铽-芳香化合物-丁二酸发光配合物的合成及性能

谭 慧; 王丽影; 周 悦; 苟丽宁; 吴盘亮; 郭栋才

doi:null

您当前的位置：

首页 >

文章列表页 >

铽-芳香化合物-丁二酸发光配合物的合成及性能

论文 | 更新时间：2020-08-12

- 铽-芳香化合物-丁二酸发光配合物的合成及性能
- Synthesis and Optical Properties of Complexes of Terbium with Aromatic Compounds and Succinic Acid
- 发光学报 2009年30卷第1期页码：101-107
- 作者机构：
  
  湖南大学化学化工学院,湖南长沙,410082
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31;O614.33
- 纸质出版日期：2009-2-20，
  
  网络出版日期：2009-2-20，
  
  收稿日期：2008-8-25，
  
  修回日期：1900-1-2，
扫描看全文
谭慧, 王丽影, 周悦, 等. 铽-芳香化合物-丁二酸发光配合物的合成及性能[J]. 发光学报, 2009,30(1):101-107.

TAN Hui, WANG Li-ying, ZHOU Yue, et al. Synthesis and Optical Properties of Complexes of Terbium with Aromatic Compounds and Succinic Acid[J]. Chinese Journal of Luminescence, 2009,30(1):101-107.
谭慧, 王丽影, 周悦, 等. 铽-芳香化合物-丁二酸发光配合物的合成及性能[J]. 发光学报, 2009,30(1):101-107. DOI：

TAN Hui, WANG Li-ying, ZHOU Yue, et al. Synthesis and Optical Properties of Complexes of Terbium with Aromatic Compounds and Succinic Acid[J]. Chinese Journal of Luminescence, 2009,30(1):101-107. DOI：

摘要

以苯甲酸及其衍生物为第一配体、丁二酸为第二配体

在非水性溶剂条件下合成了6种新的铽三元荧光配合物。利用元素分析、EDTA配位滴定分析、红外光谱和紫外吸收光谱分析对目标物的组成与结构进行了表征

并研究了其发光性能和热稳定性。结果表明:丁二酸的引入显著地加强了各第一配体向中心铽离子传递能量的能力

其传递能量的顺序为:对氯苯甲酸＞间氯苯甲酸＞大茴香酸＞对甲基苯甲酸＞苯甲酸＞对羟基苯甲酸。目标配合物与其相对应的二元配合物比较荧光强度有了显著的提高。

Abstract

Six new ternary complexes of terbium were synthesized with benzoic acid or its derivatives as the first ligand and succinic acid as the second ligand under the condition of non-aqueous solution. The structure and composition of the title complexes were characterized by means of elemental analysis

EDTA titrimetric method

UV spectra and IR spectra. The fluorescence properties and thermal stability of the title complexes were also studied. The results show that the induction of succinic acid can greatly increase the ability of the first lignd transfering light energy to the central terbium ion. The sequence of energy transmission is as follows:p-chlorobenzoic acid >m-chlorobenzoic acid> anisic acid＞p-toluic acid＞benzoic acid＞p-hydroxylbenzoic acid. The title complexes have much higher luminescence intensity than their corresponding binary complexes.

关键词

铽配合物光致发光

Keywords

terbiumcomplexphotoluminescence

references

. Zhuo Zhongcheng, Ruan Jianming, Zou Jianpeng, et al. Syntheses and fluorescence properties of terbium with benzoic acid and its derivatives [J]. Chin. J. Lumin. (发光学报), 2006, 27 (4):571-575 (in Chinese).

. Li X, Zheng X, Jin L, et al. Crystal structure and luminescence of a europium coordination polymer { 1/2(4,4'-bpy)}∞ [J]. J. Molecular Structure, 2000, 519 (1-3):85-91.

. Hu Bin, Chen Da, Su Qingde. Photoacoustic and luminescence spectra study on the effects of chlorine substituent on the energy transfer of Eu(Ⅲ)-chlorobenzoic acid [J]. Spectrochimica Acta, Part A, 2007, 66 (2):273-277.

. Yuan Jibing, Li Jiahang, Leung Louis, et al. Synthesis and photoluminescence of three Eu(Ⅲ) ternary complexes with new secondary ligands with different structure [J]. J. Chin. Rare Earth Soc. (中国稀土学报), 2004, 22 (5):600-604 (in Chinese).

. An B L, Gongm L, Cheah K W, et al. Synthesis and bright luminescence of lanthanide complexes sensitized with a novel organic ligand [J]. Chem. Phys. Lett., 2004, 385 (5-6):345-350.

. Cui Haixia, Chen Jianmin, Zhou Huidi. Influence of La3+, Gd3+ and Y3+ on fluorescence of Eu and Tb complexes with 1,6-bis hexane [J]. Chin. J. Lumin. (发光学报), 2007, 28 (5):776-780 (in Chinese).

. Xu Lijuan, Wang Ruifen, Zhao Na, et al. Synthesis and properties of ternary terbium complexes with halogen-bengoic acid and 1,10-phenanthroline [J]. Chin. J. Lumin. (发光学报), 2007, 28 (5):781-787 (in Chinese).

. Zhang Mei, Zhao Yongliang, Zhao Yanfang, et al. Studies on fluorescence property of Eu3+ dinuclear complexes with 2-thiopheneacetic acid and o-phenanthroline [J]. Chin. J. Lumin. (发光学报), 2008, 29 (5):827-832 (in Chinese).

. Zhao Na, Wang Shuping, Ma Ruixia, et al. Synthesis, crystal structure and properties of two ternary rare earth complexes with aromatic acid and 1,10-phenanthroline [J]. J. Alloys and Compounds, 2008, 463 (1-2):338-342.

. Wang Shaoting, Yang Yongli, Zhu Huiju, et al. Synthesis and spectral characterization of rare-earth-ortho-amino phenylbenzoate-2,2'-bipyridine complexes [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2006, 26 (5):933-955 (in Chinese).

. Guo Dongcai, Shu Wangen, Zhou Yue, et al. Synthesis and luminescence properties of reactive ternary terbium complexes [J]. J. Chin. Rare Earth Soc. (中国稀土学报), 2004, 22 (2):196-200 (in Chinese).

. Guo Dongcai, Zhang Wei, Shu Wangen, et al. Synthesis and luminescent properties of ternary complexes of terbium with aromatic carboxylic acid and acrylamide [J]. Chin. Rare Earths (稀土), 2006, 27 (2):23-25, 28-29 (in Chinese).

. Tao Dongliang, Zhang Ting, Xu Yizhuang, et al. Study of energy transfer in luminescent materials containing lanthanide elements [J]. Chin. J. Rare Earth Soc.(中国稀土学报), 2001, 19 (6):543-547 (in Chinese).

. Laura C D, Jorge P, Oscar F, et al. Two- and three-dimensional networks of gadolinium(iii) with dicarboxylate ligands: synthesis, crystal structure and magnetic properties [J]. Inorg. Chem., 2006, 45 (26):10585-10594.

. Subal C M, Ennio Z, Joan R, et al. Carboxylato-bridged 3D polymeric networks of Gd(III): Synthesis, crystal structure, magnetic property and thermal behavior [J]. Polyhedron, 2006, 25 (8):1779-1786.

. Zheng Xiangjun, Jin Linpei, Wang Zheming, et al. Structure and photophysical properties of europium complexes of succinamic acid and 1,10-phenanthroline [J]. Polyhedron, 2003, 22 (2):323-330.

. Cui Guanghua, Li Jianrong, Zhang Ruohua, et al. Hydrothermal synthesis, crystal structures and luminescent properties of two new Ln(Ⅲ)-succinate (Ln=Eu, Tb) complexes exhibiting three dimensional networks [J]. J. Molecular Structure, 2005, 740 (1-3):187-191.

. Si Hang. Organic Chemical Materials [M]. Beijing: Chemical Industry Press, 1999, 101-105 ( in Chinese).

. Li Xiaojun, Hu Keliang, Huang Yunlan, et al. IR spectra of dicarboxylate of alkali-earth metal [J]. Spectroscopy and Spectral Analysis (光谱与光谱分析), 2002, 22 (3):392-395 (in Chinese).

. Nakanshi K J, Solomon P H. 100 Cases of Infrared Spectroscopic Analysis [M]. Beijing: Science Press, 1984, 18 (in Chinese).

. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds [M]`. Beijing: Chemical Industry Press, 1986, 237 (in Chinese).

. Lu Guowei, Li Yong, LiWeihua, et al. The luminescence character of Eu complexes with derivatives of benzoic acid and different second ligands [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2003, 23 (2): 307-310 (in Chinese).

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

1D配合物[Tb(3,5-pdc)(3,5-Hpdc)(H₂O)(phen)]_n的合成、晶体结构及发光性质

深紫外AlGaN基多量子阱结构中载流子辐射复合的局域特征

Sr₆Lu₂Al₄O₁₅∶Tb³⁺荧光粉的发光特性

一维光子晶体带边态模式调控的胶体量子点发光性能

颜色可调CsLa（WO₄）₂∶Pr³⁺荧光粉的光致发光和温度传感特性