掺杂金属离子对(Eu,Tb)稀土配合物发光性质的影响

王 鹏; 魏长平; 任晓明

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掺杂金属离子对(Eu,Tb)稀土配合物发光性质的影响

论文 | 更新时间：2020-08-12

- 掺杂金属离子对(Eu,Tb)稀土配合物发光性质的影响
- Influences of Co-doping Metal Ions on Luminescent Properties of (Eu,Tb) Rare Earth Complexes
- 发光学报 2009年30卷第1期页码：97-100
- 作者机构：
  
  长春理工大学材料科学与工程学院,吉林长春,130022
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O614.3;O482.31
- 纸质出版日期：2009-2-20，
  
  网络出版日期：2009-2-20，
  
  收稿日期：2008-9-30，
  
  修回日期：1900-1-2，
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王鹏, 魏长平, 任晓明. 掺杂金属离子对(Eu,Tb)稀土配合物发光性质的影响[J]. 发光学报, 2009,30(1):97-100.

WANG Peng, WEI Chang-ping, REN Xiao-ming. Influences of Co-doping Metal Ions on Luminescent Properties of (Eu,Tb) Rare Earth Complexes[J]. Chinese Journal of Luminescence, 2009,30(1):97-100.
王鹏, 魏长平, 任晓明. 掺杂金属离子对(Eu,Tb)稀土配合物发光性质的影响[J]. 发光学报, 2009,30(1):97-100. DOI：

WANG Peng, WEI Chang-ping, REN Xiao-ming. Influences of Co-doping Metal Ions on Luminescent Properties of (Eu,Tb) Rare Earth Complexes[J]. Chinese Journal of Luminescence, 2009,30(1):97-100. DOI：

摘要

合成了以柠檬酸为第一配体、1

10-菲咯啉为第二配体的单核稀土(Eu、Tb)配合物和Tb/Y、Eu/Y按不同比例混合的掺杂稀土配合物。采用红外光谱、紫外光谱、激发和发射光谱等对合成的配合物结构和荧光性能进行了表征。红外光谱表明稀土离子与第一、第二配体进行了配位

配合物的紫外吸收主要是配体的吸收

保持了π→π

电子跃迁的特征。激发和发射光谱表明

不发光稀土离子Y

的掺入能显著增强发光稀土离子的光发射强度。

Abstract

In my paper

the rare earth (Eu

Tb) complexes were synthesized with citric acid as the first ligand and 1

10-phenanthroline (phen) as the secondary ligand

ternary rare earth complexes with a series of different ratios of Eu/Y and Tb/Y were synthesized. The complexes synthesized were characterized by IR spectra

UV spectra and emission-excitation spectra. IR spectra and elemental analysis show that composition and structure of the complexes synthesized is the same as the data in accordance with a chemical formula

the rare earth ions coordinated with the ligands

and the complexes is the target product. From the IR spectrum it can be seen

the C—O bond(1 729 cm-1) of citric acid symmetric stretching vibration

C—O bond (1 217 cm-1) symmetric stretching and O—H hydrogenous bond formation of hydroxyl plane bending vibration (945 cm-1) disappeared after the formation of complexes. The absorption of the ligand (phen) resulted in the complexe’s absorption which holded the character of π→π* transition with the formation of the ligand (phen) having little effect on the transition. Y3+ does not produce fluorescence itself

but the fluorescence intensity of the europium(Ⅲ) complexes increased with yttrium(Ⅲ) doped. The energy of ligand triplet state was transfered to yttrium(Ⅲ) difficultly because of the high excitation energy and f0 structure of yttrium(Ⅲ)

so that europium(Ⅲ) can get more energy

and its fluorescence intensity increased

which is so-called the co-luminescence.

关键词

稀土配合物掺杂柠檬酸苯甲酸110-菲咯啉

Keywords

rare earth complexesdopingcitric acidbenzoic acid110-phenanthroline

references

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. Zhang Mei, Zhao Yongliang, Zhao Yanfang, et al. Studies on fluorescence properties of Eu3+ dinuclear complexes with 2-thiopheneacetic acid and o-phenanthroline [J]. Chin. J. Lumin.(发光学报), 2008, 29 (5):827-832 (in Chinese).

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. Chen Ye, Cai Weimin, Yu Yingning, et al. Preparation and luminescence properties of rare earth( Eu3+,Tb3+ )comp-lexes with citric acid and 1,10phenanthroline [J]. Chin. J. Lumin. (发光学报), 2002, 23 (6):579-584 (in Chinese).

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. Duan Ning, Zhang Xiqing, Gao Xin, et al. Green electroluminescence generated from a new rare earth complex: Tb(asprin)3phen [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2001, 21 (3):267-270 (in Chinese).

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