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1. 厦门大学物理系,福建 厦门,361005
2. 厦门大学固体表面物理化学国家重点实验室, 福建厦门361005
纸质出版日期:1999-11-30,
收稿日期:1998-12-15,
修回日期:1999-6-8,
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林秀华. Au对GaP接触界面形成及其特性[J]. 发光学报, 1999,20(4): 336-341
LIN Xiuhua. INTERFACE FORMATION AND PROPERTIESIN An CONTACT TO GaP[J]. Chinese Journal of Luminescence, 1999,20(4): 336-341
借助X射线衍射和扫描电子显微镜研究了An和GaP接触体系界面特性的温度依赖性。测量表明
既使在低于400℃温度下界面反应也会生成少量的An-GaP金属间化合物
它的主要成份是(GaAu)H
Ga
2
Au.在较高温度550℃合金条件下
GaP化合物表面发生分解
界面反应增强并伴随着快速的原子间互扩散。大量Ga原子向外迁移进人An膜复盖层。同时
An原子也内扩散进入GaP表面
An-Ga之间界面反应生成(GaAu)H
Ga
2
An和(GaAu)8O.实验结果指出
An和GaP接触界面是一个金属一半导体界面反应层和合金再生长层。它含有An、Ga、P原子。An-Ga金属间化合物的形成有助改善An膜机械强度和粘附性。扫描电子显微镜观察发现
当合金温度超过AuGa共熔温度470℃
表面形貌变得粗糙和不均匀。随着温度上升
M-S接触界面层微结晶颗粒变大。在600℃下
微结晶效应显着。事实上
这种合金条件无助于欧姆接触制备。
The temperature dependence of interface characteristics in An/GaP contact system has been studied by X-ray diffraction (XRD) and scanning electron microscope (SEM).The measurements show that even at temperature below 400C the interface reaction will form a little amount of An-Ga inter-metallic compound. Its main constituents are (GaAu)H
Ga
2
Au. In the case of alloying at a higher temperature 550C the surface of GaP compound has decomposed. The interface reaction is enhanced accompanying by rapid atomic inter-diffusion. Extensive out-migration of gallium atoms into gold film overlay and penetration of gold atoms into the GaP layer have been observed. The chemical reaction between An-Ga occurs and form (GaAu)H
Ga
2
Au and (GaAu)8O etc.These experimental results suggest that the interface between the An layer and GaP is a metal-semiconductor interfacial reaction and alloying re-growth layer
which contains An
Ga and P atoms. The An-Ga inter-metallic compounds can contribute to the improvement of mechanical strength and the adhesion of An film. The SEM observation indicafes that as alloying temperature exceeds the An-Ga eutectic temperature 470C
the surface morphology of M-S contact becomes rougher and more inhomogeneous.With rising the temperapture
the microcrystal grains of interface layer become larger.At 600℃
the micro-crystallization effect is obvious. In fact
the alloying condition is not favorable to the of ohmic contact fabrication.
An-GaP接触界面反应X射线衍射谱表面性质
An contact to GaPinterface reactionsXRD spectralsurface property
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