Effect of B2O3 Content on the Spectroscopic Properties and Thermal Stability of Er3+-doped Niobic Tellurite Glasses

TU Ming-liang; HUANG Wei; ZHANG Xu-dong; DAI Shi-xun; SHENG Xiang; WANG Xun-si; XU Tie-feng

doi:null

您当前的位置：

首页 >

文章列表页 >

Effect of B₂O₃ Content on the Spectroscopic Properties and Thermal Stability of Er³⁺-doped Niobic Tellurite Glasses

更新时间：2020-08-11

- Effect of B₂O₃ Content on the Spectroscopic Properties and Thermal Stability of Er³⁺-doped Niobic Tellurite Glasses
- Chinese Journal of Luminescence Vol. 28, Issue 3, Pages: 361-366(2007)
- 作者机构：
  
  1. 宁波大学, 信息科学与工程学院,浙江宁波,315211
  2. 绍兴托普信息职业技术学院, 基础学部,浙江绍兴,312000
  3. 杭州师范学院理学院, 物理系,浙江杭州,310036
- 作者简介：
- 基金信息：
- DOI：
  CLC： TQ171.112;O482.31
- Published：20 May 2007，
  
  Received：14 October 2006，
  
  Revised：10 March 2007，
扫描看全文
屠明亮, 黄炜, 张旭东, 戴世勋, 沈祥, 王训四, 徐铁峰. B2O3含量对掺铒碲铌酸盐玻璃光谱性质及热稳定性影响[J]. 发光学报, 2007,28(3): 361-366

TU Ming-liang, HUANG Wei, ZHANG Xu-dong, DAI Shi-xun, SHENG Xiang, WANG Xun-si, XU Tie-feng. Effect of B2O3 Content on the Spectroscopic Properties and Thermal Stability of Er3+-doped Niobic Tellurite Glasses[J]. Chinese Journal of Luminescence, 2007,28(3): 361-366
屠明亮, 黄炜, 张旭东, 戴世勋, 沈祥, 王训四, 徐铁峰. B2O3含量对掺铒碲铌酸盐玻璃光谱性质及热稳定性影响[J]. 发光学报, 2007,28(3): 361-366 DOI：

TU Ming-liang, HUANG Wei, ZHANG Xu-dong, DAI Shi-xun, SHENG Xiang, WANG Xun-si, XU Tie-feng. Effect of B2O3 Content on the Spectroscopic Properties and Thermal Stability of Er3+-doped Niobic Tellurite Glasses[J]. Chinese Journal of Luminescence, 2007,28(3): 361-366 DOI：

摘要

制备了一系列碲铌酸盐玻璃85TeO

-(15-x)Nb

-xB

-1%Er

(TNB

15).根据Judd-Ofelt(J-O)和McCumber理论

讨论和分析了B

含量对掺铒碲铌酸盐玻璃热稳定性及光谱性质影响.研究发现

玻璃开始析晶温度和玻璃转变温度差值Δ

(

)

J-O强度参数

FWHM和峰值受激发射截面的乘积在B

引入摩尔分数为9%时达到最大值.同时

13/2

能级寿命也随着B

含量的增加而单调增加.结果表明

在掺铒碲铌玻璃中

适量的B

能较好地提高玻璃的热稳定性能和Er

离子的光谱性质.

Abstract

A series of niobic tellurite glasses of 85TeO

-(15-x) Nb

-xB

-1%Er

(TNB

molar fraction) glasses were prepared. The effect of B

content on the spectroscopic properties and thermal stability of Er

-doped niobic tellurite glasses were investigated and discussed based on Judd-Ofelt(J-O) and McCumber theory. For the glasses with different B

content

it is found that the transition temperature (

)

crystallization onset temperature (

)Δ

J-O intensity parameters Ω

(

the product of fluorescence full width at half maximum (FWHM) and the peak of stimulated emission cross-section (σ

peake

) reach the maximum values when B

is 9%(molar fraction). The measured lifetime of Er

13/2

level (τ

) increases monotonically with increasing B

.The results indicate that in Er

-doped niobic tellurite glasses

proper amount of B

can be used as a mo-difier to improve thermal stability and spectroscopic properties of Er

ions.

关键词

碲铌酸盐玻璃热稳定性Judd-Ofelt理论光谱特性

Keywords

niobic tellurite glassesthermal stabilityJudd-Ofelt theoryspectroscopic properties

references

YANG J H,Dai S X,Dai N L,et al.Effect of Bi2O3 on the spectroscopic of erbium-doped bismuth silicate glasses[J].J.Opt.Soc.Am.B,2003,20(5):810-815.

Gao Yuan,Nie Qiuhua,Xu Tiefeng,et al.Spectroscpic properties and Judd-Ofelt theory analysis of a new Er3+/Yb3+-codoped germanotellurite glass[J].Chin.J.Lumin.(发光学报),2006,27(1):47-52 (in Chinese).

Jiang S B,Luo T,Hwang B C,et al.Er3+-doped phosphate glasses for fiber amplifers with high gain per unit length[J].J.Non-Cryst.Solids,2000,263-264:364-368.

Wang J S,Vogel E M,Snitzer E,et al.Tellurite glass:A new candidate for fiber devices[J].Opt.Mater.,1994,3(4):187-203.

Tanabe S,Sugimoto N,Ito S,et al.Broadband 1.5μm emission of Er3+ ions in bismuth-based oxide glasses for potential WDM amplifier[J].J.Lumin.,2000,87-89:670-672.

Lin H,Meredith G,Jiang S B,et al.Optical transitions and visible upconversion in Er3+ doped niobic tellurite glass[J].J.Appl.Phys.,2003,93(1):186-191.

Dai S X,Wu J L,Zhang J J,et al.The spectroscopic properties of Er3+-doped TeO2-Nb2O5 glasses with high mechanical strength performance[J].Spectrochimica Acta Part A,2005,62(1-3):431-437.

Cho D H,Choi Y G,Kim K H.Improvement of 4I11/2→4I13/2 transition rate and thermal stabilities in Er3+ doped TeO2-B2O3(GeO2)-ZnO-K2O glass[J].ETRI,2001,23(4):151-157.

Judd B R.Optical absorption intensities of rare-earth ions[J].Phys.Rev.,1962,127(3):750-761.

Ofelt G S.Intensities of crystal spectra of rare earth ions[J].J.Chem.Phys.,1962,37(3):511-520.

Tanabe S,Ohyagi T,Soga N,et al.Compositional dependence of Judd-Ofelt parameters of Er3+ ions in alkali-metal borate glasses[J].Phys.Rev.B,1992,46(6):3305-3310.

Tanabe S.Optical transitions of rare earth ions for amplifiers:how the local structure works in glass[J].J.Non-Cryst.Solids,1999,259(1-3):1-9.

Tanabe S,Ohyagi T,Todoroki S,et al.Relation between the Ω6 intensity parameters of Er3+ ions and the 151Eu isomer shift in oxide glasses[J].J.Appl.Phys.,1993,73(12):8451-8454.

Pauling L.The Nature of the Chemical Bond[M].Third Edition,Ithaca:Cornell University Press,N.Y.,1960.

McCumber D E.Einstein relations connecting broadband emission and absorption spectra[J].Phy.Rev.,1964,136(4A):A954-A957.

MinacaloO W J,Quimby R S.General procedure for the anslysis of Er3+ cross sections[J].Opt.Lett.,1991,16(4):258-260.

Yang J,Dai S,et al.Spectroscopic properties & thermal stability of Er3+ doped bismuth based glasses for optical amplifier[J].J.Appl.Phys.,2003,93(3):977-983.

Shen Xiang,Nie Qiuhua,Xu Tiefeng,et al.Er3+/Yb3+ codoped tungsten-tellurite glasses:the thermal stability and spectral properties at 1.5μm band[J].Chin.J.Lumin.(发光学报),2006,27(1):36-40 (in Chinese).

Feng X,Tanabe S,Hanada T.Spectroscopic properties and thermal stability of Er3+ doped germanotellurite glasses for broadband fiber amplifiers[J].J.Am.Ceram.Soc.,2001,84(1):165-171.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Spectroscopic Properties and Judd-Ofelt Theory Analysis of a New Er³⁺/Yb³⁺-codoped Germanotellurite Glass

Up-conversion Luminescence Properties of Nd³⁺/Yb³⁺ Doped YNbO₄ Powder

Near-infrared Phosphor BaY₂Al₂Ga₂SiO₁₂∶Cr³⁺ with Excellent Thermal Stability and Considerable Quantum Efficiency

Quantitative Calculation and Prediction of Spectroscopic Properties of Thulium-doped Germanate Laser Glass

Optical Properties of Visible Laser Crystal Sm³⁺∶CaDyAlO₄

Related Author

GAO Yuan

NIE Qiu-hua

XU Tie-feng

HOU Shuai

SHEN Xiang

REN Xuan-wei

LYU Yong

NIU Chun-hui

Related Institution

Department of Logistic and Management, Public Security Marine Police Academy

College of Information Science and Engineering, Ningbo University

北京信息科技大学仪器科学与光电工程学院

School of Applied Chemistry and Engineering， University of Science and Technology of China

State Key Laboratory of Rare Earth Resource Utilization，Changchun Institute of Applied Chemistry， Chinese Academy of Sciences

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰