Ag纳米晶和辅助电场的引入对TeO2-ZnO-Bi2O3玻璃发光性能的影响

陈淑文; 林健; 杨晓宇

doi:10.3788/fgxb20183903.0266

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Ag纳米晶和辅助电场的引入对TeO₂-ZnO-Bi₂O₃玻璃发光性能的影响

材料合成及性能 | 更新时间：2020-08-12

- Ag纳米晶和辅助电场的引入对TeO₂-ZnO-Bi₂O₃玻璃发光性能的影响
- Influence of Ag Nanocrystals and Auxiliary Electric Field on The Luminescence Properties of TeO₂-ZnO-Bi₂O₃ Glasses
- 发光学报 2018年39卷第3期页码：266-272
- 作者机构：
  
  同济大学材料科学与工程学院上海,201804
- 作者简介：
- 基金信息：
  
  上海市科学技术委员会项目（12nm0504700）资助()
- DOI：10.3788/fgxb20183903.0266
  中图分类号： O482.31
- 纸质出版日期：2018-3-5，
  
  收稿日期：2017-9-27，
  
  修回日期：2017-12-11，
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陈淑文, 林健, 杨晓宇. Ag纳米晶和辅助电场的引入对TeO2-ZnO-Bi2O3玻璃发光性能的影响[J]. 发光学报, 2018,39(3): 266-272

CHEN Shu-wen, LIN Jian, YANG Xiao-yu. Influence of Ag Nanocrystals and Auxiliary Electric Field on The Luminescence Properties of TeO2-ZnO-Bi2O3 Glasses[J]. Chinese Journal of Luminescence, 2018,39(3): 266-272
陈淑文, 林健, 杨晓宇. Ag纳米晶和辅助电场的引入对TeO2-ZnO-Bi2O3玻璃发光性能的影响[J]. 发光学报, 2018,39(3): 266-272 DOI： 10.3788/fgxb20183903.0266.

CHEN Shu-wen, LIN Jian, YANG Xiao-yu. Influence of Ag Nanocrystals and Auxiliary Electric Field on The Luminescence Properties of TeO2-ZnO-Bi2O3 Glasses[J]. Chinese Journal of Luminescence, 2018,39(3): 266-272 DOI： 10.3788/fgxb20183903.0266.

摘要

采用熔融退火法制备得到Er

/Yb

共掺的TeO

-ZnO-Bi

玻璃。通过热处理微晶化析出Zn

等微晶和引入Ag纳米晶这两种方式，玻璃的发光性能均有所提升。然而，对含Ag纳米晶玻璃进一步热处理后，玻璃的发光性能下降。针对银纳米晶的引入易导致热处理过程中玻璃基体过度析晶的问题，进一步采用电场辅助热处理方法来控制Ag纳米晶与微晶的析出。对含Ag纳米晶玻璃进行电场辅助热处理后，Ag纳米晶析出量增多且微晶没有过度生长，玻璃的发光性能得到进一步提升。

Abstract

/Yb

co-doped TeO

-ZnO-Bi

tellurite glasses were first prepared by melt-quenching method. Through precipitation of Zn

micro-crystals by heat treatment and introduction of Ag nanocrystals respectively

the luminescence properties of glasses are improved. However

after further heat treatment

the luminescence properties of glasses with Ag nanocrystals decrease. As Ag nanocrystals can lead to excessive crystallization of glasses during heat treatment process

the auxiliary electric field heat treatment method is applied to control the precipitation of Ag nanocrystals and micro-crystals. After auxiliary electric field heat treatment

more Ag nanocrystals are produced and the growth of micro-crystals is controlled

which lead to the improved luminescence properties of glasses.

关键词

碲酸盐玻璃微晶化Ag纳米晶辅助电场

Keywords

tellurite glassesmicro crystallizationAg nanocrystalsauxiliary electric field

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