烧结温度和掺杂浓度对Y4Zr3O12∶Eu3+荧光粉发光性质的影响

赖凤琴; 李嘉鹏; 吴有福生; 胡美兰; 肖青辉; 姚庆林; 夏李斌; 叶信宇; 游维雄

doi:10.3788/fgxb20173811.1436

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烧结温度和掺杂浓度对Y₄Zr₃O₁₂∶Eu³⁺荧光粉发光性质的影响

材料合成及性能 | 更新时间：2020-08-12

- 烧结温度和掺杂浓度对Y₄Zr₃O₁₂∶Eu³⁺荧光粉发光性质的影响
- Effects of Calcination Temperature and Dopant Concentration on The Luminescence Properties of Eu³⁺ Doped Y₄Zr₃O₁₂ Phosphors
- 发光学报 2017年38卷第11期页码：1436-1442
- 作者机构：
  
  1. 江西理工大学冶金与化学工程学院,江西赣州,341000
  2. 江西理工大学材料科学与工程学院,江西赣州,341000
  3. 江西理工大学机电工程学院,江西赣州,341000
- 作者简介：
- 基金信息：
  
  国家自然科学基金（51304086，11464017）资助项目()
- DOI：10.3788/fgxb20173811.1436
  中图分类号： O482.31
- 纸质出版日期：2017-11-5，
  
  网络出版日期：2017-7-13，
  
  收稿日期：2017-4-11，
  
  修回日期：2017-6-7，
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赖凤琴, 李嘉鹏, 吴有福生等. 烧结温度和掺杂浓度对Y4Zr3O12∶Eu3+荧光粉发光性质的影响[J]. 发光学报, 2017,38(11): 1436-1442

LAI Feng-qin, LI Jia-peng, WU You-fu-sheng etc. Effects of Calcination Temperature and Dopant Concentration on The Luminescence Properties of Eu3+ Doped Y4Zr3O12 Phosphors[J]. Chinese Journal of Luminescence, 2017,38(11): 1436-1442
赖凤琴, 李嘉鹏, 吴有福生等. 烧结温度和掺杂浓度对Y4Zr3O12∶Eu3+荧光粉发光性质的影响[J]. 发光学报, 2017,38(11): 1436-1442 DOI： 10.3788/fgxb20173811.1436.

LAI Feng-qin, LI Jia-peng, WU You-fu-sheng etc. Effects of Calcination Temperature and Dopant Concentration on The Luminescence Properties of Eu3+ Doped Y4Zr3O12 Phosphors[J]. Chinese Journal of Luminescence, 2017,38(11): 1436-1442 DOI： 10.3788/fgxb20173811.1436.

摘要

采用溶胶凝胶法制备了Y

∶Eu

纳米荧光粉，分别采用XRD、TEM和荧光光谱仪对样品的结构、形貌和发光性能进行了表征，探讨了烧结温度和Eu

掺杂浓度对荧光粉发光性能的影响。结果表明，样品可以被394 nm和467 nm的激发光有效激发。样品的最佳烧结温度和Eu

离子的最佳掺杂摩尔分数分别为1 400℃和18%。浓度猝灭主要归因于电偶极-电偶极相互作用。

Abstract

:Eu

phosphors were synthesized by the sol-gel method. The crystal structure

morphology and luminescence properties were investigated by XRD

TEM and luminescence spectroscopy. The effects of calcination temperature and Eu

concentration on the luminescence properties were also studied. These phosphors can be efficiently excited by 394 and 467 nm. The optimal calcination temperature and optimal Eu

mole fraction are 1 400℃ and 18%

respectively. The mechanism of concentration quenching is attributed to the electric dipole-dipole interaction.

关键词

Y4Zr3O12:Eu3+荧光粉sol-gel浓度猝灭

Keywords

Y4Zr3O12:Eu3+ phosphorsol-gelconcentration quenching

references

WANG J, ZHANG W Q, QI S Y, et al.. Preparation and luminescence characteristics of Eu-doped calcium chloride silicate Ca7Si2O8Cl6[J]. J. Alloys Compd., 2014, 589:120-124.

WANG T, XU X H, ZHOU D C, et al.. Red phosphor Ca2Ge7O16:Eu3+ for potential application in field emission displays and white light-emitting diodes[J]. Mate. Res. Bull., 2014, 60:876-881.

王迪, 孟祥雨, 赵嘉伟, 等. Ca9Al(PO4)7:Eu2+的发光、浓度猝灭及温度稳定性[J]. 光子学报, 2015, 44(5):0516002. WANG D, MENG X Y, ZHAO J W, et al.. Luminescence, concentration quenching and thermal stability of Ca9Al-(PO4)7:Eu2+[J]. Acta Photon. Sinica, 2015, 44(5):0516002. (in Chinese)

徐嘉林, 金维召, 刘旺, 等. Ho,Yb:Tb3Ga5O12纳米粉体制备及发光性能研究[J]. 中国光学, 2015, 8(4):608-614. XU J L, JIN W Z, LIU W, et al.. Preparation and luminescent properties of Ho,Yb:Tb3Ga5O12 nano-powder[J]. Chin. Opt., 2015, 8(4):608-614. (in Chinese)

LI L, LIU X G, NOH H M, et al.. Key chemical parameters related to the width of the charge transfer band and the emission intensity of 5D07F2 in Eu3+ doped Ln2O3[J]. J. Alloys Compd., 2015, 620:324-328.

LIANG Z J, MO F W, ZHANG X G, et al.. Luminescence of the LiMgBO3:Eu3+, Bi3+ phosphor[J]. J. Lumin., 2014, 151:47-51.

DU Q Q, ZHOU G J, ZHOU J, et al.. Enhanced luminescence of novel Y2Zr2O7:Dy3+ phosphors by Li+co-doping[J]. J. Alloys Compd., 2013, 552:152-156.

SINGH V, SIVARAMAIAH G, RAOJ L, et al.. Investigation of new UV-emitting, Gd-activated Y4Zr3O12 phosphors prepared via combustion method[J]. J. Lumin., 2015, 157:82-87.

GALLARDO-LOPEZ A, MARTINEZ-FERNANDEZ J, DOMINGUEZ-RODERIGUEZA. Contribution to the study of the transition to a superstructure in high yttria content YCSZ[J]. J. Eur. Ceram. Soc., 2002, 22:2821-2825.

SHLYAKHTINA A V, BELOV D A, STEFANOVICHS Y. -phase to defect fluorite (order-disorder) transition in the R2O3-MO2 (R=Sc, Tm, Lu; M=Zr, Hf) systems[J]. Mate. Res. Bull., 2011, 46:512-517.

CLARKE D R, PHILLPOT S R, Thermal barrier coating materials[J]. Mater. Today, 2005, 8:22-29.

PUCHALSKA M, ZYCH E, SOBCZYK M, et al.. Effect of charge compensation on up-conversion and UV excited luminescence of Eu3+ in Yb3+-Eu3+ doped calcium aluminate CaAl4O7[J]. Mater. Chem. Phys., 2014, 147:304-310.

YANG H J, PENG F, ZHANGQ L, et al.. Strong upconversion luminescence in LiYMo2O8:Er, Yb towards efficiency enhancement of dye-sensitized solar cells[J]. Opt. Mater., 2013, 35:2338-2342.

YOU W X, LAI F Q, JIANG H H, et al.. The up-conversion properties of Yb3+ and Er3+ doped Y4Al2O9 phosphors[J]. Phys. B, 2012, 407:1094-1098.

SURESH KUMAR A, ARUN KUMAR R, BALASUNDARAPRABHU R, et al.. Influence of calcination temperature on the luminescent properties of Eu3+ doped CaAl4O7 phosphor prepared by Pechini method[J]. Spectrochim. Acta:Part A, 2015, 134:283-287.

KOLESNIKOV I E, TOLSTIKOVA D V, KUROCHKINA V, et al.. Eu3+ concentration effect on luminescence properties of YAG:Eu3+ nanoparticles[J]. Opt. Mater., 2014, 37:306-310.

关荣锋, 孙倩, 李勤勤, 等. CaMoO4:Eu3+,Bi3+,Li+红色荧光粉的共沉淀制备与表征[J]. 发光学报, 2013, 34(8):1000-1005. GUANG R F, SUN Q, LI Q Q, et al.. Co-precipitation synthesis and characterization of CaMoO4:Eu3+, Bi3+, Li+ red phosphor[J]. Chin. J. Lumin., 2013, 34(8):1000-1005. (in Chinese)

BANDI V R, JAYASIMHADRI M, JEONGJ, et al.. Host sensitized novel red phosphor CaZrSi2O7:Eu3+ for near UV and blue LED-based white LEDs[J]. J. Phys. D:Appl. Phys., 2010, 43(39):395103-1-7.

YOU W X, XIAO Z L, LAIF Q, et al.. Synthesis and photoluminescence properties of Ba3Al2O6:Eu3+red phosphor[J]. J. Mater. Sci., 2016, 51:5403-5411.

JIANG W N, FU R L, GU X G, et al.. A red-emitting phosphor LaSr2AlO5:Eu3+/Eu2+ prepared under oxidative and reductive atmospheres[J]. J. Lumin., 2015, 157:46-52.

黄世华, 楼立人. 能量传递中敏化剂发光强度与浓度的关系[J]. 发光学报, 1990, 11(1):1-7. HUANG S H, LOU L R. Concentration dependence of sensitizer fluorescence intensity in energy transfer[J]. Chin. J. Lumin., 1990, 11(1):1-7. (in Chinese)

HUANG J, YI S P, DENGY M, et al.. A novel red emitting phosphor of Eu3+ doped Sr2La2MgW2O12 for white light emitting diodes[J]. Spectrochim. Acta:Part A, 2015, 148:324-327.

TANIGUCHI K, HONDA T, KATOA. Eu concentration dependence of luminescence properties of Sr1-xEuxGa2S4 phosphors synthesized by polymerized complex sulfurization method[J]. Opt. Mater., 2013, 35:1993-1996.

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