基于合作能量传递的Sm2+离子上转换发光

刘晓辉; 马世童; 郑克志; 秦伟平

doi:10.3788/fgxb20173811.1413

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基于合作能量传递的Sm²⁺离子上转换发光

材料合成及性能 | 更新时间：2020-08-12

- 基于合作能量传递的Sm²⁺离子上转换发光
- Upconversion Luminescence of Sm²⁺ Ions Based on Cooperative Energy Transfer
- 发光学报 2017年38卷第11期页码：1413-1419
- 作者机构：
  
  吉林大学电子科学与工程学院,吉林长春,130012
- 作者简介：
- 基金信息：
  
  国家自然科学基金（11274139，11474132）资助项目()
- DOI：10.3788/fgxb20173811.1413
  中图分类号： O482.31
- 纸质出版日期：2017-11-5，
  
  网络出版日期：2017-7-13，
  
  收稿日期：2017-4-26，
  
  修回日期：2017-5-3，
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刘晓辉, 马世童, 郑克志等. 基于合作能量传递的Sm2+离子上转换发光[J]. 发光学报, 2017,38(11): 1413-1419

LIU Xiao-hui, MA Shi-tong, ZHENG Ke-zhi etc. Upconversion Luminescence of Sm2+ Ions Based on Cooperative Energy Transfer[J]. Chinese Journal of Luminescence, 2017,38(11): 1413-1419
刘晓辉, 马世童, 郑克志等. 基于合作能量传递的Sm2+离子上转换发光[J]. 发光学报, 2017,38(11): 1413-1419 DOI： 10.3788/fgxb20173811.1413.

LIU Xiao-hui, MA Shi-tong, ZHENG Ke-zhi etc. Upconversion Luminescence of Sm2+ Ions Based on Cooperative Energy Transfer[J]. Chinese Journal of Luminescence, 2017,38(11): 1413-1419 DOI： 10.3788/fgxb20173811.1413.

摘要

报道了Sm

离子的上转换发光。在实验上证明了变价镧系离子同样可以作为上转换材料的发光中心。在近红外光的激发下，复合BaFCl

0.5

∶1% Sm

-CaF

∶1% Yb

化合物发出红色上转换发光。上转换发射光谱中位于631，644，665，689，704，729 nm的特征发射分别来自于样品中Sm

的

（

=0，1）

（

=0，1，2）特征跃迁。根据动力学分析及光子数拟合的结果，我们将二价Sm离子的上转换过程归因于合作能量传递，即：两个同时被激发的Yb

离子合作将能量传递给一个Sm

离子。

Abstract

We report the observation of upconversion luminescence from Sm

ions

which demonstrate that changeable valence lanthanides can served as the ions for optical frequency transformation. Upon the excitation of 980 nm diode laser

the doped Sm

ions in the hybrid material of BaFCl

0.5

:1%Sm

-CaF

:1%Yb

emit red upconversion fluorescence peaked at 631

644

665

689

704

729 nm from the

transitions

respectively. By transient dynamic analysis

we attribute the excitation of Sm

ions to the cooperation energy transfer process:two excited Yb

ions simultaneously transfer their energy to one Sm

ion.

关键词

合作能量传递Yb3+-dimerSm2+上转换发光

Keywords

cooperative energy transferYb3+-dimerSm2+upconversion luminescence

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