Pb2+掺杂导致的CaF2中Yb3+离子三聚体合作发光猝灭

吐尔逊·艾迪力比克; 杨育; 赵丹; 秦伟平

doi:10.3788/fgxb20173810.1280

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Pb²⁺掺杂导致的CaF₂中Yb³⁺离子三聚体合作发光猝灭

材料合成及性能 | 更新时间：2020-08-12

- Pb²⁺掺杂导致的CaF₂中Yb³⁺离子三聚体合作发光猝灭
- Pb²⁺ Ions Doping Induced Cooperative Luminescence Quenching of Yb³⁺-trimers in CaF₂
- 发光学报 2017年38卷第10期页码：1280-1286
- 作者机构：
  
  1. 吉林大学电子科学与工程学院,吉林长春,130012
  2. 伊犁师范学院电子与信息工程学院, 新疆伊宁,835000
- 作者简介：
- 基金信息：
  
  国家自然科学基金（11274139，11474132）;新疆科技厅自然科学基金（2015211C295）;伊犁师范学院微纳电传感技术与仿生器械实验室开放项目（2016wnzd004）资助
- DOI：10.3788/fgxb20173810.1280
  中图分类号： O482.31
- 纸质出版日期：2017-10-5，
  
  网络出版日期：2017-7-13，
  
  收稿日期：2017-4-6，
  
  修回日期：2017-5-8，
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吐尔逊·艾迪力比克, 杨育等. Pb²⁺掺杂导致的CaF₂中Yb³⁺离子三聚体合作发光猝灭[J]. 发光学报, 2017,38(10): 1280-1286

TUERXUN Aidilibike, YANG Yu, ZHAO Dan etc. Pb²⁺ Ions Doping Induced Cooperative Luminescence Quenching of Yb³⁺-trimers in CaF₂[J]. Chinese Journal of Luminescence, 2017,38(10): 1280-1286
吐尔逊·艾迪力比克, 杨育等. Pb²⁺掺杂导致的CaF₂中Yb³⁺离子三聚体合作发光猝灭[J]. 发光学报, 2017,38(10): 1280-1286 DOI： 10.3788/fgxb20173810.1280.

TUERXUN Aidilibike, YANG Yu, ZHAO Dan etc. Pb²⁺ Ions Doping Induced Cooperative Luminescence Quenching of Yb³⁺-trimers in CaF₂[J]. Chinese Journal of Luminescence, 2017,38(10): 1280-1286 DOI： 10.3788/fgxb20173810.1280.

摘要

利用978 nm近红外光激发样品CaF

：Pb

，Yb

，在室温下观察到二价Pb

离子在383 nm附近的紫外上转换发光。该发射峰对应于Pb

离子的

（

）跃迁。瞬态光谱测量结果表明：在这个材料体系中，Pb

离子的激发来自于Yb

离子三聚体的合作敏化。但是随着Pb

离子掺杂浓度的提高，Yb

离子三聚体遭到结构性破坏，导致其合作发光减弱。本文首次利用Pb

离子掺杂造成Yb

离子三聚体的结构性破坏，从而引起合作荧光猝灭，并对在CaF

基质中因其他二价离子的掺入而造成的Yb

三聚体合作发光猝灭给予了合理的解释。

Abstract

At room temperature

the ultraviolet (UV) upconversion emissions from CaF

:Pb

were observed under the excitation of 978 nm near infrared (NIR) laser. The upconversion emission peak is centered at 383 nm

which is ascribed to the

(

) transition of Pb

ions. Through the results of transient measurements

the upconversion process of Pb

ions is confirmed. The energy transfer process is that three excited Yb

ions simultaneously transfer their energy to one Pb

ion. With the increasing of Pb

concentration

the cooperative luminescence from Yb

clusters decreases gradually. In order to explain this phenomenon

we propose a new cooperative luminescence quenching mechanism in this paper

which is originated from Pb

induced structure destruction of Yb

-trimers. The fluorescence quenching in Pb

and Yb

codoped CaF

is given a reasonable explanation.

关键词

Yb3+离子三聚体合作敏化Pb2+离子紫外上转换发光

Keywords

Yb3+-trimerscooperative sensitizationPb2+ ionsUV upconversion luminescence

references

SILVERSMITH A J, LENTH W, MACFARLANE R M. Green infrared pumped erbium upconversion laser[J]. Appl. Phys. Lett., 1987, 51:1977-1979.

MACFARLANE R M, TONG F, SILVERSMITH A J, et al.. Violet cw neodymium upconversion laser[J]. Appl. Phys. Lett., 1988, 52:1300-1302.

DANGER T, KOETKE J, BREDE R, et al.. Spectroscopy and green upconversion laser emission of Er3+-doped crystals at room temperature[J]. J. Appl. Phys., 1994, 76:1413-1422.

JOHNSON L F, GUGGENHEIM H J. Laser emission at 3 from Dy3+ in BaY2F8[J]. Appl. Phys. Lett., 1973, 23(2):96-98.

JOUBERT M F. Photon avalanche upconversion in rare earth laser materials[J]. Opt. Mater., 1999, 11:181-203.

SUYVER J F, AEBISCHER A, BINER D, et al.. Novel materials doped with trivalent lanthanides and transition metal ions showing near-infrared to visible photon upconversion[J]. Opt. Mater., 2005, 27:1111-1130.

POLLNAU M, GAMELIN D R, LUTHI S R, et al.. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems[J]. Phys. Rev. B, 2000, 61:3337-3346.

SONG E H, DING S, WU M, et al.. Anomalous NIR Luminescence in Mn2+-doped fluoride perovskite nanocrystals[J]. Adv. Opt. Mater., 2014, 2:670-678.

WANG L L, XUE X J, SHI F, et al.. Ultraviolet and violet upconversion fluorescence of europium (Ⅲ) doped in YF3 nanocrystals[J]. Opt. Lett., 2009, 34:2781-2783.

SONG E H, DING S, WU M, et al.. Temperature-tunable upconversion luminescence of perovskite nanocrystals KZnF3:Yb3+, Mn2+[J]. J. Mater. Chem. C, 2013, 1:4209-4215.

ZHANG J H, HAO Z D, LI J, et al.. Observation of efficient population of the red-emitting state from the green state by non-multiphonon relaxation in the Er3+-Yb3+ system[J]. Light:Sci. Appl., 2015, 4:e239.

HUANG F F, LIU X Q, MA Y Y, et al.. Origin of near to middle infrared luminescence and energy transfer process of Er3+/Yb3+co-doped fluorotellurite glasses under different excitations[J]. Sci. Rep.-UK, 2015, 5:8233.

WEI T, TIAN Y, CHEN F Z, et al.. Mid-infrared fluorescence, energy transfer process and rate equation analysis in Er3+ doped germanate glass[J]. Sci. Rep.-UK, 2014, 4:6060.

STREK W, CICHY B, RADOSINSKI L, et al.. Laser-induced white-light emission from graphene ceramics-opening a band gap in graphene[J]. Light:Sci. Appl., 2015, 4:e237.

AUZEL F. Upconversion and anti-stokes processes with f and d ions in solids[J]. Chem. Rev., 2004, 104:139-173.

JOSHI C P, MOHARIL S V. Luminescence of Pb2+ in some aluminates prepared by combustion synthesis[J]. Phys. Stat. Sol. B, 2000, 220:985-989.

FOLKERTS H F, ZUIDEMA J, BLASSE G. The luminescence of Pb2+ in lead compounds with one-dimensional chains[J]. Solid State Commun., 1996, 99:655-658.

FOLKERTS H F, BLASSE G. Two types of luminescence from Pb2+ in alkaline-earth carbonates with the aragonite structure[J]. Phys. Chem. Solids, 1996,57:303-306.

LESKELA M. Luminescence properties of Eu2+,Sn2+,and Pb2+ in SrB6010 and Sr1-xMnxB6O10[J]. J. Solid State Chem., 1985, 59:272-279.

ANDERSON D F, KIERSTEAD J A, PAUL LECOQ, et al.. A search for scintillation in doped and orthorhombic lead fluoride[J]. Nucl. Instrum. Methods Phys. Res. A, 1994, 342:473-476.

JACOBS P W M. Alkali halide crystals containing impurity ions with the ns2 ground-state electronic[J]. J. Phys. Chem. Solids. 1991, 52:35-67.

PEJCHAL J, MIHOKOVA E, NIKL M, et al.. Luminescence and decay kinetics of Pb2+ center in LiCaAlF6 single crystal host[J]. Opt. Mater., 2009, 31:1673-1677.

KAZANSKⅡ S A, RYSKINA I, NIKIFOROVA E, et al.. EPR spectra and crystal field of hexamer rare-earth clusters in fluorites[J]. Phys. Rev. B, 2005, 72:014127-1-11.

CHERNYSHEV V A, NIKIFOROV A E, NAZEMNIKH A D. Hexamer clusters in MeF2:Yb3+ (Me=Ca, Sr, Ba)[J]. J. Phys. Conf. Ser., 2011, 324:012025-9.

VARSANYI F, DIEKE G H. Ion-pair resonance mechanism of energy transfer in rare earth crystal fluorescence[J]. Phys. Rev. Lett., 1961, 7:442-443.

NAKAZAWA E. Cooperative luminescence in YbPO4[J]. Phys. Rev. Lett., 1970, 25:1710-1712.

WANG J, DENG R R, MAC DONALD M A, et al.. Enhancing multiphoton upconversion through energy clustering at sublattice level[J]. Nat. Mater., 2014, 13:157-162.

WEI X T, ZHAO J B, ZHANG W P, et al.. Cooperative energy transfer in Eu3+, Yb3+ codoped Y2O3 phosphor[J]. J. Rare Earth, 2010, 28:166-170.

JIANLI H, ZHIGUANG Z, HUAN Z, et al.. Intense red fiuorescence from Ho/Yb codoped tellurite glasses[J]. J. Non-Cryst. Solids, 2014, 383:157-160.

ZHANG W J, CHEN Q J, QIAN Q, et al.. Cooperative energy transfer in Tb3+/Yb3+-and Nd3+/Yb3+/Tb3+-codoped oxyfiuoride glasses[J]. Physica B, 2010, 405:1062-1066.

QIN W P. Cooperative Luminescence of Yb3+ Ions[C]. 18th International Conference on Dynamical Processes in Excited States of Solids, Fuzhou, China, 2013.

QIN W P, LIU Z Y, SIN C N, et al.. Multi-ion cooperative processes in Yb3+ clusters[J]. Light:Sci. Appl., 2014, 3:e193.

QIN W P, CHOLNAM S, LIU Z Y, et al.. Theory on cooperative quantum transitions of three identical lanthanide ions[J]. J. Opt. Soc. Am. B, 2015, 32:303-308.

STEF M, NICOARA I, STEF F. Dielectric relaxation in ytterbium- and lead-doped calcium fluoride crystals[J]. Eur. Phys. J. B, 2013, 86:152-1-8.

NICOARA I, MUNTEANU M, PECINGINA-GARJOABA N, et al.. Dielectric relaxation in PbF2-doped and X-ray irradiated CaF2 crystals[J]. ECS Transactions, 2006, 3:51-58.

ANDEENI C G, FONTANELLA J J, WINTERSGILLT M C, et al.. Clustering in rare-earth-doped alkaline earth fluorides[J]. J. Phys. C:Solid State Phys., 1981, 14:3557-3574.

CORISH J. Defect aggregation in anion-excess fluorites dopant monomers and dimers[J]. Phys. Rev. B, 1982, 25:6425-6438.

DRYDEN J S, HEYDON R G. Ultraviolet A-band absorption in NaCl:Pb2+ and clustering of lattice defects[J]. J. Phys. C:Solid State Phys., 1983, 16:5363-5373.

PARASCHIVA M, NICOARA I, STEF M, et al.. Distribution of Pb2+ ions in PbF2-doped CaF2 crystals[J]. Acta Phys. Pol. A, 2010, 117:466-470.

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