生物质焦油制备的碳量子点

邓祥意; 冯雅丽; 李浩然; 杜竹玮; 滕青; 康金星

doi:10.3788/fgxb20173808.1015

您当前的位置：

首页 >

文章列表页 >

生物质焦油制备的碳量子点

材料合成及性能 | 更新时间：2020-08-12

- 生物质焦油制备的碳量子点
- Synthesis of Carbon Quantum Dots by Biomass Tar
- 发光学报 2017年38卷第8期页码：1015-1020
- 作者机构：
  
  1. 北京科技大学土木与资源工程学院北京,100083
  2. 中国科学院过程工程研究所生化工程国家重点实验室北京,100190
- 作者简介：
- 基金信息：
  
  水体污染与治理科技重大专项（2015ZX07205-003）();中国大洋矿产资源研究计划（DY125-15-T-08）();国家自然科学基金（21176026，211
- DOI：10.3788/fgxb20173808.1015
  中图分类号： O613.71
- 纸质出版日期：2017-8-5，
  
  收稿日期：2016-12-24，
  
  修回日期：2017-2-11，
扫描看全文
邓祥意, 冯雅丽, 李浩然等. 生物质焦油制备的碳量子点[J]. 发光学报, 2017,38(8): 1015-1020

DENG Xiang-yi, FENG Ya-li, LI Hao-ran etc. Synthesis of Carbon Quantum Dots by Biomass Tar[J]. Chinese Journal of Luminescence, 2017,38(8): 1015-1020
邓祥意, 冯雅丽, 李浩然等. 生物质焦油制备的碳量子点[J]. 发光学报, 2017,38(8): 1015-1020 DOI： 10.3788/fgxb20173808.1015.

DENG Xiang-yi, FENG Ya-li, LI Hao-ran etc. Synthesis of Carbon Quantum Dots by Biomass Tar[J]. Chinese Journal of Luminescence, 2017,38(8): 1015-1020 DOI： 10.3788/fgxb20173808.1015.

摘要

利用生物质热解副产物焦油为碳前驱体，采用反相微乳液法和P

碳化法制备了荧光碳量子点。反相微乳液法制备的碳量子点为规则球状结构，粒径均一，平均粒度为4.3 nm，晶面间距为0.25 nm，对应于石墨碳的（100）晶面；P

碳化法制备的碳量子点为蜂窝状结构，平均粒径为6.8 nm，晶面间距为0.33 nm，对应于石墨碳的（002）晶面。两种方法制备的碳量子点均具备石墨结构特征，碳量子点荧光产率分别为85.3%和24.3%。

Abstract

By using the reverse microemulsion method and P

carbonization method

the fluorescent carbon quantum dots were prepared using pyrolysis by-products tar as carbon precursor. The carbon dots prepared by reverse microemulsion method are regular spherical structures with uniform particle size of 4.3 nm and the crystal lattice spacing is 0.25 nm

corresponding to the (100) plane of graphite carbon. The carbon quantum dots prepared by P

carbonization method are honeycomb-like with particle size of 6.8 nm and the crystal lattice spacing is 0.33 nm

corresponding to the (002) plane of graphite carbon. The yield of carbon quantum dots is 85.3% and 24.3%

respectively.

关键词

生物质焦油反相微乳液法P2O5碳化法碳量子点

Keywords

biomass tarreverse microemulsion methodP2O5 carbonization methodcarbon quantum dots

references

王莉, 吕婷, 阮枫萍, 等. 水热法制备的荧光碳量子点[J]. 发光学报, 2014, 35(6):706-709. WANG L, LYU T, RUAN F P, et al.. Synthesis of photoluminescent carbon nanoparticles by hydrothermal method[J]. Chin. J. Lumin., 2014, 35(6):706-709. (in Chinese)

YANG S T, WANG X, WANG H F, et al.. Carbon dots as nontoxic and high-performance fluorescence imaging agents[J]. J. Phys. Chem. C, 2009, 113(42):18110-18114.

LUO P G, SAHU S, YANG S T, et al.. Carbon "quantum" dots for optical bioimaging[J]. J. Mater. Chem. B, 2013, 1(16):2116-2127.

DA SILVA J C G E, GONALVES H M R. Analytical and bioanalytical applications of carbon dots[J]. TrAC Trends. Anal. Chem., 2011, 30(8):1327-1336.

WANG F, XIE Z, ZHANG H, et al.. Highly luminescent organosilane-functionalized carbon dots[J]. Adv. Funct. Mater., 2011, 21(6):1027-1031.

FANG Y X, GUO S J, LI D, et al.. Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles[J]. ACS Nano, 2012, 6(1):400-409.

JAISWAL J K, GOLDMAN E R, MATTOUSSI H, et al.. Use of quantum dots for live cell imaging[J]. Nat. Methods, 2004, 1(1):73-78.

RAY S C, SAHA A, JANA N R, et al.. Fluorescent carbon nanoparticles:synthesis, characterization, and bioimaging application[J]. J. Phys. Chem. C, 2009, 113(43):18546-18551.

KWON W, RHEE S W. Facile synthesis of graphitic carbon quantum dots with size tunability and uniformity using reverse micelles[J]. Chem. Commun., 2012, 48(43):5256-5258.

LIU H P, YE T, MAO C D. Fluorescent carbon nanoparticles derived from candle soot[J]. Angew. Chem. Int. Ed., 2007, 46(34):6473-6475.

TIAN L, GHOSH D, CHEN W, et al.. Nanosized carbon particles from natural gas soot[J]. Chem. Mater., 2009, 21(13):2803-2809.

娄庆, 曲松楠. 基于超级碳点的水致荧光"纳米炸弹"[J]. 中国光学, 2015, 8(1):91-98 LOU Q, QU S N. Water triggered luminescent nano-bombs based on supra-carbon-nanodots[J]. Chin. Opt., 2015,8(1):91-98. (in Chinese)

LIU R L, WU D Q, LIU S H, et al.. An aqueous route to multicolor photoluminescent carbon dots using silica spheres as carriers[J]. Angew. Chem. Int. Ed., 2009, 48(25):4598-4601.

ZHU H, WANG X L, LI Y L, et al.. Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence propertiesw[J]. Chem. Commun., 2009, (34):5118-5120.

WANG X H, QU K G, XU B L, et al.. Microwave assisted one-step green synthesis of cell-permeable multicolor photoluminescent carbon dots without surface passivation reagents[J]. J. Mater. Chem., 2011, 21(8):2445-2450.

JIANG J, HE Y, LI S Y, et al.. Amino acids as the source for producing carbon nanodots:microwave assisted one-step synthesis, intrinsic photoluminescence property and intense chemiluminescence enhancement[J]. Chem. Commun., 2012, 48(77):9634-9636.

XU X Y, RAY R, GU Y L, et al.. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J]. J. Am. Chem. Soc., 2004, 126(40):12736-12737.

李腾飞, 李昳玮, 肖璐, 等. 荧光可调控的碳量子点的电化学制备及性质研究[J]. 化学学报, 2014, 72(2):227-232. LI T F, LI Y W, XIAO L, et al.. Electrochemical preparation of color-tunable fluorescent carbon quantum dots[J]. Acta Chim. Sinica, 2014, 72(2):227-232. (in Chinese)

WANG X, CAO L, LU F S, et al.. Photoinduced electron transfers with carbon dots[J]. Chem. Commun., 2009, (25):3774-3776.

LU J, YANG J X, WANG J Z, et al.. One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids[J]. ACS Nano, 2009, 3(8):2367-2375.

张存兰. 生物质燃烧气化焦油成分分析研究[J]. 化学分析计量, 2009, 18(6):55-57. ZHANG C L. Component analysis for biomass burning gasification tar[J]. Chem. Anal. Meterage, 2009, 18(6):55-57. (in Chinese)

张朝平, 邓伟, 胡林, 等. 微乳液法制备超细Ni-Fe复合物微粒[J]. 无机材料学报, 2001, 16(3):481-485. ZHANG C P, DENG W, HU L, et al.. Preparation of ultrafine Ni-Fe composite particles by microemulsion[J]. J. Inorg. Mater., 2001, 16(3):481-485. (in Chinese)

YU H, ZHANG H C, HUANG H, et al.. ZnO/carbon quantum dots nanocomposites:one-step fabrication and superior photocatalytic ability for toxic gas degradation under visible light at room temperature[J]. New J. Chem., 2012, 36(4):1031-1035.

MING H, MA Z, LIU Y, et al.. Large scale electrochemical synthesis of high quality carbon nanodots and their photocatalytic property[J]. Dalton Trans., 2012, 41(31):9526-9531.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

煤基碳量子点制备及对环境水中Cr（Ⅵ）的测定

硫醇⁃烯交联增强碳量子点发光效率机理研究

淡竹叶碳量子点的微波法制备及在细胞成像中的应用探究

三苯甲基改性油溶性碳量子点合成及其在发光器件中的应用

荧光碳量子点在药物分析中的应用研究进展