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1. 河南省信阳学院 理工学院,河南 信阳,464000
2. 陕西师范大学 化学化工学院,陕西 西安,710062
纸质出版日期:2017-6-5,
收稿日期:2016-11-24,
修回日期:2017-3-15,
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毛丽惠, 李晓严, 李保新. 酚类物质在鲁米诺-硝酸银-纳米金体系中化学发光行为研究[J]. 发光学报, 2017,38(6): 814-819
MAO Li-hui, LI Xiao-yan, LI Bao-xin. Effect of Polyphenol Compounds on Luminol-AgNO<sub>3</sub>-gold Nanoparticles Chemical Luminescence System[J]. Chinese Journal of Luminescence, 2017,38(6): 814-819
毛丽惠, 李晓严, 李保新. 酚类物质在鲁米诺-硝酸银-纳米金体系中化学发光行为研究[J]. 发光学报, 2017,38(6): 814-819 DOI: 10.3788/fgxb20173806.0814.
MAO Li-hui, LI Xiao-yan, LI Bao-xin. Effect of Polyphenol Compounds on Luminol-AgNO<sub>3</sub>-gold Nanoparticles Chemical Luminescence System[J]. Chinese Journal of Luminescence, 2017,38(6): 814-819 DOI: 10.3788/fgxb20173806.0814.
鲁米诺-硝酸银-纳米金体系有很强的化学发光现象。当向该体系中加入酚类物质,化学发光信号有不同程度的变化。研究发现,酚类物质的-OH可以与纳米金产生相互作用,相互作用的大小与酚类物质所含的-OH数目、位置有关。结合流动注射化学发光法对对苯二酚、邻苯二酚、邻苯三酚进行了测定,检出限分别为4.010
-11
,8.010
-10
,2.610
-9
g/mL。用加标回收法测定了自来水中的邻苯二酚,回收率在97.5%~105%,相对标准偏差在1.4%~2.5%,结果满意。初步讨论了酚类物质对此体系化学发光强度影响的机理,建立了测定多酚类物质的化学发光分析新方法。
Luminol-AgNO
3
-gold nanoparticles system has a strong chemical luminescence(CL) phenomena. When polyphenol compounds are added in the system
the cheminescence signals have different degrees of change. OH in the phenolics can interact with the nanometer gold
and the interaction is related to the number and location of OH in the phenolic compounds. Combined with the flow injection chemiluminescence method
hydeoquinone
catechol and phthalate were determined. The detection limits are 4.010
-11
8.010
-10
2.610
-9
g/mL
respectively. The method was successfully used to determine catechol in water. The recovery is 97.5%-105%
and the relative standard derivations (RSD) is 1.4%-2.5%. The possible mechanism of the CL reaction was discussed
and the CL method for determination of the polyphenol compounds was proposed.
酚类物质化学发光纳米金
polyphenol compoundschemiluminescencegold nanoparticls
HUANG X, REN J. Nanomaterial-based chemiluminescence resonance energy transfer:a strategy to develop new analytical methods[J]. Trac. Trends Anal. Chem., 2012, 40:77-89.
LIN J M, LIU M L. Chemiluminescence from the decomposition of peroxymonocarbonate catalyzed by gold nanoparticles[J]. J. Phys. Chem. B, 2008, 112:7850-7855.
LI Q, ZHANG L, LI J, et al.. Nanomaterial-amplified chemiluminescenc systems and their appellations in bioassays[J]. Trac. Trends Anal. Chem., 2011, 30:401-403.
周艳玲. 酚类化合物检测方法研究进展[J]. 环境检测管理与技术,2011, 23(s1):70-77. ZHOU Y L. Progress in research on detection of phenolic compounds[J].Admin. Tech. Environ. Monitor., 2011, 23(s1):70-77. (in Chinese)
ZHAO D M, ZHANG X H, FENG L J, et al.. Simultaneous determination of hydroquinone and catechol at PASA/MWNTs composite film modified glassy carbon electrode[J]. Colloids Surf. B, 2009, 74:317-321.
马振华,王会才,姚晓霞,等. 氟化石墨修饰玻碳电极同时测定邻苯二酚和对苯二酚[J]. 分析化学, 2015, 43(12):1906-1912. MA ZH H, WANG H C, YAO X X, et al.. Simultaneous determination of catechol and hydroquinone based on fluorinated graphite modified glassy carbon electrode[J]. Chin. J. Anal. Chem., 2015, 43(12):1906-1912. (in Chinese)
许春萱,丁婷婷,杨媛媛,等. 聚L-半胱氨酸/乙炔黑修饰玻碳电极测定水样中对苯二酚[J]. 冶金分析, 2016, 36(9):19-24. XE CH X, DING T T, YANG Y Y,et al.. Determination of hydroquinone in water with poly (L-cysteine)/acetylene black modified glassy carbon electrode[J]. Metal. Anal., 2016, 36(9):19-24. (in Chinese)
刘小花,白海鑫,王瑾. 单壁碳纳米管-氧化石墨烯复合修饰电极测定邻苯二酚[J]. 化学研究, 2015, 26(6):629-632. LIU X H, BAI H X, WANG J. The determination of catechol at single walled carbon nanotube-graphene oxide modified electrode[J]. Chem. Res., 2015, 26(6):629-632. (in Chinese)
王春燕,由天艳,田坚. 聚谷氨酸修饰电极同时测定对苯二酚和邻苯二酚[J]. 分析化学, 2011, 39(4):528-533. WANG CH Y, YOU T Y, TIAN J. Simultaneous determination of hydroquinone andcatechol with poly(glutamic acid) modified electrode[J]. Chin. J. Anal. Chem., 2011, 39(4):528-533. (in Chinese)
薛永林,任守信,高玲. 荧光光度法同时测定邻苯二酚、间苯二酚与对苯二酚[J]. 分析测试学报, 2010, 29(12):1147-1152. XUE Y L, REN S X, GAO L. Simultaneous fluorespectrophotometric determination of catechol, resorcinol and hydroquinone by chemometric method[J]. J. Instrum. Anal., 2010, 29(12):1147-1152. (in Chinese)
占达东,叶燕. 分光光度法检测废水中的间苯二酚[J]. 光谱实验室, 2004, 21(6):1208-1210. ZHAN D D, YE Y. Determination of resorcinol in waste water by spectrophotometry[J]. Chin. J. Spectrosc. Lab., 2004, 21(6):1208-1210. (in Chinese)
翟虎,陈小全,邵辉莹. 多元校正-紫外分光光度法同时测定苯酚和间苯二酚[J]. 光谱实验室, 2008, 25(3):440-443. ZHAI H, CHEN X Q, SHAO H Y. Simultaneous determination for phenol and resorcinol by multivariatecal ibration-UV spectrophotometry[J]. Chin. J. Spectrosc. Lab., 2008, 25(3):440-443. (in Chinese)
CUI H, GUO J Z, LI N,et al.. Gold nanoparticle triggered chemiluminescence between luminol and AgNO3[J]. J. Phys. Chem. C, 2008, 112(30):11319-11323.
ZHANG F, CUI H, SHI M J. Chemiluminescence accompanied by the reaction of gold nanoparticles with potassium permanganate[J]. Phys. Chem. Chem. Phys., 2006, 8:1017-1021.
GUO J Z, CUI H. Lucigenin chemiluminescence induced by nobel metal nanoparticles in the presence of adsorbates[J].J. Phys. Chem. C, 2007, 111(33):12254-12259.
GHOSH K, NATH S, KUNDU S, et al.. Solvent and ligand effect on the localized surface plasmon resonance (LSPR) of gold colloids[J]. J. Phys. Chem. B, 2004, 108(37):13963-13971.
SARATHY V, KULLKARNI G U, RAO C N R. A novel method of preparing thiol-derivatised nanoparticles of gold, platinum, and silver forming superstructures[J].J. Chem. Soc. Chem. Commun., 1997, 6:5371.
王炳娟, 李玲霞, 邹洪. 邻苯三酚自氧化法测定SOD活性的电化学研究[J]. 现代仪器与医疗, 2008, 2:29-30. WANG B J, LI L X, ZOU H. Determination the activity of superoxide dismutase enzyme by electrochemical method based on the reaction of pyrogallol autoxidation[J]. Modern instrum. Med. Treat., 2008, 2:29-30. (in Chinese)
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