酚类物质在鲁米诺-硝酸银-纳米金体系中化学发光行为研究

毛丽惠; 李晓严; 李保新

doi:10.3788/fgxb20173806.0814

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酚类物质在鲁米诺-硝酸银-纳米金体系中化学发光行为研究

发光学应用及交叉前沿 | 更新时间：2020-08-12

- 酚类物质在鲁米诺-硝酸银-纳米金体系中化学发光行为研究
- Effect of Polyphenol Compounds on Luminol-AgNO₃-gold Nanoparticles Chemical Luminescence System
- 发光学报 2017年38卷第6期页码：814-819
- 作者机构：
  
  1. 河南省信阳学院理工学院,河南信阳,464000
  2. 陕西师范大学化学化工学院,陕西西安,710062
- 作者简介：
- 基金信息：
  
  河南省教育厅高等学校重点科研项目（17B150010，15B150015）资助()
- DOI：10.3788/fgxb20173806.0814
  中图分类号： O657.3
- 纸质出版日期：2017-6-5，
  
  收稿日期：2016-11-24，
  
  修回日期：2017-3-15，
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毛丽惠, 李晓严, 李保新. 酚类物质在鲁米诺-硝酸银-纳米金体系中化学发光行为研究[J]. 发光学报, 2017,38(6): 814-819

MAO Li-hui, LI Xiao-yan, LI Bao-xin. Effect of Polyphenol Compounds on Luminol-AgNO<sub>3</sub>-gold Nanoparticles Chemical Luminescence System[J]. Chinese Journal of Luminescence, 2017,38(6): 814-819
毛丽惠, 李晓严, 李保新. 酚类物质在鲁米诺-硝酸银-纳米金体系中化学发光行为研究[J]. 发光学报, 2017,38(6): 814-819 DOI： 10.3788/fgxb20173806.0814.

MAO Li-hui, LI Xiao-yan, LI Bao-xin. Effect of Polyphenol Compounds on Luminol-AgNO<sub>3</sub>-gold Nanoparticles Chemical Luminescence System[J]. Chinese Journal of Luminescence, 2017,38(6): 814-819 DOI： 10.3788/fgxb20173806.0814.

摘要

鲁米诺-硝酸银-纳米金体系有很强的化学发光现象。当向该体系中加入酚类物质，化学发光信号有不同程度的变化。研究发现，酚类物质的-OH可以与纳米金产生相互作用，相互作用的大小与酚类物质所含的-OH数目、位置有关。结合流动注射化学发光法对对苯二酚、邻苯二酚、邻苯三酚进行了测定，检出限分别为4.010

-11

，8.010

-10

，2.610

-9

g/mL。用加标回收法测定了自来水中的邻苯二酚，回收率在97.5%~105%，相对标准偏差在1.4%~2.5%，结果满意。初步讨论了酚类物质对此体系化学发光强度影响的机理，建立了测定多酚类物质的化学发光分析新方法。

Abstract

Luminol-AgNO

-gold nanoparticles system has a strong chemical luminescence(CL) phenomena. When polyphenol compounds are added in the system

the cheminescence signals have different degrees of change. OH in the phenolics can interact with the nanometer gold

and the interaction is related to the number and location of OH in the phenolic compounds. Combined with the flow injection chemiluminescence method

hydeoquinone

catechol and phthalate were determined. The detection limits are 4.010

-11

8.010

-10

2.610

-9

g/mL

respectively. The method was successfully used to determine catechol in water. The recovery is 97.5%－105%

and the relative standard derivations (RSD) is 1.4%－2.5%. The possible mechanism of the CL reaction was discussed

and the CL method for determination of the polyphenol compounds was proposed.

关键词

酚类物质化学发光纳米金

Keywords

polyphenol compoundschemiluminescencegold nanoparticls

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