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1. 发光学及应用国家重点实验室 中国科学院长春光学精密机械与物理研究所,吉林 长春,130033
2. 中国科学院大学 北京,100049
3. 长春轨道客车股份有限公司,吉林 长春,130062
4. 内蒙古民族大学 化学化工学院,内蒙古 通辽,028000
纸质出版日期:2017-4-5,
收稿日期:2016-10-5,
修回日期:2016-11-10,
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吕晨曦, 张镭, 杨杨等. 芳香烃中位取代氟硼二吡咯的薄膜放大自发辐射稳定性研究[J]. 发光学报, 2017,38(4): 499-506
LYU Chen-xi, ZHANG Lei, YANG Yang etc. Stability of Amplified Spontaneous Emission of Meso Aromatic Substituted BODIPY Derivatives Films[J]. Chinese Journal of Luminescence, 2017,38(4): 499-506
吕晨曦, 张镭, 杨杨等. 芳香烃中位取代氟硼二吡咯的薄膜放大自发辐射稳定性研究[J]. 发光学报, 2017,38(4): 499-506 DOI: 10.3788/fgxb20173804.0499.
LYU Chen-xi, ZHANG Lei, YANG Yang etc. Stability of Amplified Spontaneous Emission of Meso Aromatic Substituted BODIPY Derivatives Films[J]. Chinese Journal of Luminescence, 2017,38(4): 499-506 DOI: 10.3788/fgxb20173804.0499.
对苯基、萘基和蒽基在中位取代的氟硼二吡咯(BODIPY)衍生物薄膜的放大自发辐射(ASE)性能进行了研究'探讨了影响材料ASE稳定性的因素。首先'将3种BODIPY衍生物材料PhBOD、NaBOD和EnBOD掺入聚苯乙烯经溶液旋涂法制备成薄膜'接下来测试了吸收光谱和荧光光谱'然后在光泵浦条件下测量了3种样品的ASE性能'获得了材料的ASE阈值。进一步通过长时间泵浦、环境中长时间放置和高温环境下泵浦等方法研究了材料的光稳定性、ASE环境稳定性和热稳定性。最后使用Gaussian 09计算了分子基态性质。实验结果表明'PhBOD、NaBOD和EnBOD薄膜的初始阈值分别为12.4'4.55'3.4 kW/cm
2
'其中PhBOD有较强的ASE稳定性。ASE稳定性差异可能与分子结构的共轭程度和化学稳定性相关。分子中各个基团的共轭程度较大、Mulliken电荷分布对称性较好的材料具有较好的ASE稳定性。
The amplified spontaneous emission (ASE) properties of phenyl
naphthyl and anthracene substituted boron dipyrromethene (BODIPY) derivative films were studied
and the factors that influence the ASE stability of BODIPY derivatives were discussed. First
three BODIPY derivatives (PhBOD
NaBOD and EnBOD) materials were doped into polystyrene
from which the films were prepared by spin-coating. The absorption and fluorescence spectra were recorded. The ASE performance of the three samples was measured under the optical pumping
and the ASE thresholds of the materials were obtained. The optical stability
ASE environmental stability and thermal stability of the materials were studied by means of long time pumping
long time placement in the environment and pumping under high temperature environment. Finally
Gaussian 09 was used to calculate the molecular ground state properties. Experimental results show that the initial thresholds of PhBOD
NaBOD and EnBOD films are about 12.4
4.55
3.4 kW/cm
2
respectively. Among them
PhBOD film shows better ASE stability. The difference of ASE stability may be related to the conjugation degree and chemical stability of molecular structure. The ASE stability of the material would be better when the conjugation degree of each group in the molecule is larger
and the Mulliken charge distribution is more symmetrical.
氟硼二吡咯衍生物放大自发辐射稳定性分子结构
BODIPY derivativesamplified spontaneous emission (ASE)stabilitymolecular structure
HIDE F, SCHWARTZ B J, DAZ-GARCA M A, et al.. Laser emission from solutions and films containing semiconducting polymer and titanium dioxide nanocrystals[J]. Chem. Phys. Lett., 1996, 256(4-5):424-430.
TESSLER N, DENTON G J, FRIEND R H. Lasing from conjugated-polymer microcavities[J]. Nature, 1996, 382(6593):695-697.
HIDE F, DAZ-GARCA M A, SCHWARTZ B J, et al.. Semiconducting polymers:a new class of solid-state laser materials[J]. Science, 1996, 273(5283):1833-1836.
MCGEHEE M D, GUPTA R, VEENSTRA S, et al.. Amplified spontaneous emission from photopumped films of a conjugated polymer[J]. Phys. Rev. B, 1998, 58(11):7035-7039.
TURNBULL G A, KRAUSS T F, BARNES W L, et al.. Tuneable distributed feedback lasing in MEH-PPV films[J]. Synth. Met., 2001, 121(1-3):1757-1758.
XIA R D, LAI W Y, LEVERMORE P A, et al.. Low-threshold distributed-feedback lasers based on pyrene-cored starburst molecules with 1,3,6,8-attached Oligo(9,9-Dialkylfluorene) arms[J]. Adv. Funct. Mater., 2009, 19(17):2844-2850.
XIA R, HELIOTIS G, CAMPOY-QUILES M, et al.. Characterization of a high-thermal-stability spiroanthracenefluorene-based blue-light-emitting polymer optical gain medium[J]. J. Appl. Phys., 2005, 98(8):083101-1-7.
GUO K P, ZHANG Q, WANG F F, et al.. Deep-blue, low-threshold amplified spontaneous emitting and high thermal stability binaphthyl derivates[J]. Phys. Status Solidi A, 2014, 211(10):2372-2377.
BERGMANN A, HOLZER W, STARK R, et al.. Photophysical characterization of pyrromethene dyes in solid matrices of acrylic copolymers[J]. Chem. Phys., 2001, 271(1-2):201-213.
AMAT-GUERRI F, LIRAS M, CARRASCOSO M L, et al.. Methacrylate-tethered analogs of the laser dye PM567-synthesis, copolymerization with methyl methacrylate and photostability of the copolymers[J]. Photochem. Photobiol., 2003, 77(6):577-584.
COSTELA A, GARCA-MORENO I, SASTRE R. Polymeric solid-state dye lasers:recent developments[J]. Phys. Chem. Chem. Phys., 2003, 5(21):4745-4763.
王尉谦, 秦亮, 林涛, 等. F8BT:P3HT共混薄膜放大自发辐射的温度效应[J]. 发光学报, 2016, 37(8):973-978. WANG W Q, QIN L, LIN T, et al.. Temperature dependence of amplified spontaneous emission from blend film of F8BT and P3HT[J]. Chin. J. Lumin., 2016, 37(8):973-978. (in Chinese)
DUARTE F G. Tunable Laser Applications[M]. 2nd ed. England:Taylor & Francis Group, 2008.
ULRICH G, ZIESSEL R, HARRIMAN A. The chemistry of fluorescent bodipy dyes:versatility unsurpassed[J]. Angew. Chem. Int. Ed., 2008, 47(7):1184-1201.
GUGGENHEIMER S C, BOYER G H, THANGARAJ K, et al.. Efficient laser action from two cw laser-pumped pyrromethene-BF2 complexes[J]. Appl. Opt., 1993, 32(21):3942-3943.
SUNAHARA H, URANO Y, KOJIMA H, et al.. Design and synthesis of a library of BODIPY-based environmental polarity sensors utilizing photoinduced electron-transfer-controlled fluorescence ON/OFF switching[J]. J. Am. Chem. Soc., 2007, 129(17):5597-5604.
LOUDET A, BURGESS K. BODIPY dyes and their derivatives:syntheses and spectroscopic properties[J]. Chem. Rev., 2007, 107(11):4891-4932.
张镭, 杨杨, 高劼超, 等. 有机材料EnBOD的放大自发发射性能研究[J]. 发光学报, 2015, 36(6):661-665. ZHANG L, YANG Y, GAO J C, et al.. Study on amplified spontaneous emission properties of EnBOD material[J]. Chin. J. Lumin., 2015, 36(6):661-665. (in Chinese)
BARTHOLOMEW J L, DEBARBER P A, HEEG B, et al.. Development of an organic dye solution for laser cooling by anti-Stokes fluorescence[J]. Mater. Res. Soc. Symp. Proc., 2001, 667:G1.7-1-6.
CLARK J L, RUMBLES G. Laser cooling in the condensed phase by frequency up-conversion[J]. Phys. Rev. Lett., 1996, 76(12):2037-2040.
COSTELA A, GARCA-MORENO I, AGUA D D, et al.. Highly photostable solid-state dye lasers based on silicon-modified organic matrices[J]. J. Appl. Phys., 2007, 101(7):073110-1-11.
YANG W T, PARR R G, LEE C. Various functionals for the kinetic energy density of an atom or molecule[J]. Phys. Rev. A, 1986, 34(6):4586-4590.
HAY P J. Gaussian basis sets for molecular calculations. The representation of 3d orbitals in transition-metal atoms[J]. J. Chem. Phys., 1977, 66(10):4377-4384.
WIDANY J, FRAUENHEIM T, KHLER T, et al.. Density-functional-based construction of transferable nonorthogonal tight-binding potentials for B, N, BN, BH, and NH[J]. Phys. Rev. B, 1996, 53(8):4443-4452.
OXGAARD J, TENN W J, NIELSEN R J, et al.. Mechanistic analysis of iridium heteroatom C-H activation:evidence for an internal electrophilic substitution mechanism[J]. Organometallics, 2007, 26(7):1565-1567.
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