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1. 大连工业大学 新材料与材料改性省高校重点实验室,辽宁 大连,116034
2. 北京生态岛科技有限责任公司 研发中心 北京,102402
3. 大连工业大学 食品学院,辽宁 大连,116034
纸质出版日期:2017-4-5,
收稿日期:2016-8-31,
修回日期:2016-10-18,
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郭伟华, 郝洪顺, 靳闪闪等. ZnO:(Al,Sm)阻挡层薄膜的制备及其光电性能[J]. 发光学报, 2017,38(4): 442-449
GUO Wei-hua, HAO Hong-shun, JIN Shan-shan etc. Preparation and Photoelectric Property of ZnO: (Al, Sm) Block Films[J]. Chinese Journal of Luminescence, 2017,38(4): 442-449
郭伟华, 郝洪顺, 靳闪闪等. ZnO:(Al,Sm)阻挡层薄膜的制备及其光电性能[J]. 发光学报, 2017,38(4): 442-449 DOI: 10.3788/fgxb20173804.0442.
GUO Wei-hua, HAO Hong-shun, JIN Shan-shan etc. Preparation and Photoelectric Property of ZnO: (Al, Sm) Block Films[J]. Chinese Journal of Luminescence, 2017,38(4): 442-449 DOI: 10.3788/fgxb20173804.0442.
采用溶胶凝胶法制备ZnO:Al'Sm阻挡层薄膜'并用X射线衍射仪(XRD)、能谱仪(EDS)、红外光谱(FTIR)、荧光光谱(PL)、紫外可见光谱(UV-Vis)和扫描电子显微镜(SEM)等对阻挡层薄膜进行了表征'探讨了Al、Sm掺杂量对阻挡层薄膜性能的影响。结果表明:当Al的掺杂摩尔分数为1%、Sm的掺杂摩尔分数为3%时'所制备的阻挡层荧光强度最高'可将部分紫外光下转换为588 nm的可见光'拓宽了光谱响应范围;基于ZnO:1% Al'3% Sm阻挡层的海胆棘壳色素敏化的纳米TiO
2
太阳能电池的开路电压为0.73 V'短路电流密度为0.68 mA/cm
2
'转换效率达0.33%'效率比基于ZnO阻挡层的电池提高了约136%。
Al and/or Sm doped ZnO block films were prepared by sol-gel method
and characterized by XRD
EDS
FTIR
PL
UV-Vis and SEM to investigate the effects of Al and Sm doping content on the performance. When the doping mole fraction of Al is 1%
and that of Sm is 3%
the photoluminescence intensity of the block film is the highest. The film can down-convert part of ultraviolet light to visible light of 588 nm
which widens the spectra response range. By using ZnO:Al
Sm down-conversion film and TiO
2
(P25) porous absorbing layer
after sensitized by the pigment ethanol solution of spines of sea urchin
the short-circuit current density and open-circuit voltage of the dye sensitized solar cell (DSSC) are 0.68 mA/cm
2
and 0.73 V
respectively. And the DSSC achieves the power conversion efficiency of 0.33%
which is increased by 136% compared to the DSSC based on ZnO block layer.
溶胶凝胶法ZnO:AlSm阻挡层染料敏化太阳能电池
sol-gelZnO:AlSmblock layerdye sensitized solar cell(DSSC)
O'REGAN B, GRTZEL M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J]. Nature, 1991, 353(6346):737-740.
KAKIAGE K, AOYAMA Y, YANO T, et al.. Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes[J]. Chem. Commun., 2015, 51(88):15894-15897.
孙琼, 孙先淼, 李阳, 等. 具有阵列-簇双层结构的TiO2纳米棒的光电性能[J]. 发光学报, 2013, 34(1):61-65. SUN Q, SUN X M, LI Y, et al.. Photoelectrical properties of TiO2 nanorods with an array-cluster double-layered structure[J]. Chin. J. Lumin., 2013, 34(1):61-65. (in Chinese)
陶勇, 廖志君, 伍登学, 等. 染料敏化太阳能电池阻挡层的制备及其性能研究[J]. 功能材料, 2011, 42(7):1177-1179. TAO Y, LIAO Z J, WU D X, et al.. Fabrication and investigation of blocking layer in dye-sensitized solar cells[J]. J. Funct. Mater., 2011, 42(7):1177-1179. (in Chinese)
秦艺颖, 胡志强, 张普涛, 等. 染料敏化太阳能电池Sm3+掺杂TiO2下转换光阳极的制备及性能[J]. 发光学报, 2015, 36(8):868-874. QIN Y Y, HU Z Q, ZHANG P T, et al.. Synthesis and properties of Sm3+-doped TiO2 down-conversion photoanode for dye-sensitized solar cells[J]. Chin. J. Lumin., 2015, 36(8):868-874. (in Chinese)
陈东坡, 张晓丹, 魏长春, 等. TiCl4水解法制备的阻挡层对染料敏化太阳能电池光电性能的影响[J]. 物理化学学报, 2011, 27(2):425-431. CHEN D P, ZHANG X D, WEI C C, et al.. Effect of blocking layers prepared by the hydrolysis of TiCl4 solution on the photovoltaic performance of a dye-Sensitized solar cell[J]. Acta Phys. Chim. Sinica, 2011, 27(2):425-431. (in Chinese)
CAMERON P J, PETER L M. Characterization of titanium dioxide blocking layers in dye-sensitized nanocrystalline solar cells[J]. J. Phys. Chem. B, 2003, 107(51):14394-14400.
KOVASH JR C S, HOEFELMEYER J D, LOGUE B A. TiO2 compact layers prepared by low temperature colloidal synthesis and deposition for high performance dye-sensitized solar cells[J]. Electrochim. Acta, 2012, 67:18-23.
聂铭岐, 胡志强, 秦艺颖, 等. TiO2/Sm3+下转换薄膜的制备及其在染料敏化太阳能电池中的应用[J]. 发光学报, 2014, 35(8):974-979. NIE M Q, HU Z Q, QIN Y Y, et al.. Preparation of TiO2/Sm3+ down-conversion film and its application in dye-sensitized solar cell[J]. Chin. J. Lumin., 2014, 35(8):974-979. (in Chinese)
马振辉, 谷景华, 张跃. 溶剂热法制备Al掺杂ZnO薄膜的机理研究[J]. 人工晶体学报, 2012, 41(1):74-78. MA Z H, GU J H, ZHANG Y. Study on growth mechanism of Al doped ZnO films prepared by solvothermal method[J]. J. Synth. Cryst., 2012, 41(1):74-78. (in Chinese)
MEREU R A, MESAROS A, VASILESCU M, et al.. Synthesis and characterization of undoped, Al and/or Ho doped ZnO thin Films doped ZnO thin films[J]. Ceram. Int., 2013, 39(5):5535-5543.
RANI A A, ERNEST S. Structural, morphological, optical and compositional characterization of spray deposited Ga doped ZnO thin film for dye-sensitized solar cell application[J]. Superlatt. Microstruct., 2014, 75:398-408.
HUANG N, LIU Y M, PENG T, et al.. Synergistic effects of ZnO compact layer and TiCl4 post-treatment for dye-sensitized solar cells[J]. J. Power Sources, 2012, 204:257-264.
PHURUANGRAT A, YAYAPAO O, THONGTEM T, et al.. Preparation, characterization and photocatalytic properties of Ho doped ZnO nanostructures synthesized by sonochemical method[J]. Superlatt. Microstruct., 2014, 67:118-126.
KLEINWECHTER H, JANZEN C, KNIPPING J, et al.. Formation and properties of ZnO nano-particles from gas phase synthesis processes[J]. J. Mater. Sci., 2002, 37(20):4349-4360.
CHANG M, CAO X L, ZENG H B, et al.. Enhancement of the ultraviolet emission of ZnO nanostructures by polyaniline modification[J]. Chem. Phys. Lett., 2007, 446(4-6):370-373.
KIISK V, AVEL M, REEDO V, et al.. Anatase-to-rutile phase transition of samarium-doped TiO2 powder detected via the luminescence of Sm3+[J]. Phys. Proc., 2009, 2(2):527-538.
秦艺颖, 胡志强, 张普涛, 等. 染料敏化太阳能电池Eu3+, Sm3+掺杂TiO2下转换光阳极的制备及性能[J]. 光子学报, 2016, 45(6):0616002-1-7. QIN Y Y, HU Z Q, ZHANG P T, et al.. Synthesis and properties of Eu3+, Sm3+-doped TiO2 down-conversion photoanode for dye-sensitized solar cells[J]. Acta Photon. Sinica, 2016, 45(6):0616002-1-7. (in Chinese)
PAL P P, MANAM J. Structural and photoluminescence studies of Eu3+ doped zinc oxide nanorods prepared by precipitation method[J]. J. Rare Earths, 2013, 31(1):37-43.
曾凡强, 战可涛. sol-gel法制备的ZnO:(Al, La)透明导电膜光电性能[J]. 电子元件与材料, 2008, 27(7):47-49. ZENG F Q, ZHAN K T. Photoelectric properties of ZnO:(Al, La) transparant conductive thin film prepared by sol-gel method[J]. Electron. Compon. Mater., 2008, 27(7):47-49. (in Chinese)
XUE S W, ZU X T, ZHENG W G, et al.. Effects of annealing and dopant concentration on the optical characteristics of ZnO:Al thin films by sol-gel technique[J]. Phys. B, 2006, 382(1-2):201-204.
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