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1. 江西理工大学 材料科学与工程学院,江西 赣州,341000
2. 江西理工大学 冶金与化学工程学院, 江西 赣州 341000
3. 江西钨业集团 稀土新材料有限公司, 江西 赣州 341000
4. 宁波出入境检验检疫局,浙江 宁波,315800
纸质出版日期:2017-4-5,
收稿日期:2016-10-12,
修回日期:2016-11-13,
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夏李斌, 王林生, 杨东彪等. 白光LED用B<sub>2</sub>O<sub>3</sub>-Bi<sub>2</sub>O<sub>3</sub>-Eu<sub>2</sub>O<sub>3</sub>-<em>M</em>O(<em>M</em>=Mg,Ca,Sr,Ba)红光发射荧光玻璃的结构与发光性能[J]. 发光学报, 2017,38(4): 415-422
XIA Li-bin, WANG Lin-sheng, YANG Dong-biao etc. Structure Analysis and Optical Properties of B<sub>2</sub>O<sub>3</sub>-Bi<sub>2</sub>O<sub>3</sub>-Eu<sub>2</sub>O<sub>3</sub>-<em>M</em>O (<em>M</em>=Mg, Ca, Sr, Ba) Red Light Glasses for White LED[J]. Chinese Journal of Luminescence, 2017,38(4): 415-422
夏李斌, 王林生, 杨东彪等. 白光LED用B<sub>2</sub>O<sub>3</sub>-Bi<sub>2</sub>O<sub>3</sub>-Eu<sub>2</sub>O<sub>3</sub>-<em>M</em>O(<em>M</em>=Mg,Ca,Sr,Ba)红光发射荧光玻璃的结构与发光性能[J]. 发光学报, 2017,38(4): 415-422 DOI: 10.3788/fgxb20173804.0415.
XIA Li-bin, WANG Lin-sheng, YANG Dong-biao etc. Structure Analysis and Optical Properties of B<sub>2</sub>O<sub>3</sub>-Bi<sub>2</sub>O<sub>3</sub>-Eu<sub>2</sub>O<sub>3</sub>-<em>M</em>O (<em>M</em>=Mg, Ca, Sr, Ba) Red Light Glasses for White LED[J]. Chinese Journal of Luminescence, 2017,38(4): 415-422 DOI: 10.3788/fgxb20173804.0415.
采用熔融冷却法制备了铕掺杂碱土金属硼铋酸盐玻璃(BBME'BBCE'BBSE'BBBE)。研究了玻璃的密度、摩尔体积、光学碱度等物理性质'分析了玻璃的结构、光学性质和热稳定性。结果表明'从BBME到BBBE'玻璃结构致密程度不断下降。Eu
3+
能较好地熔融到玻璃中'成为良好的发光中心'在465 nm和613 nm处分别有强烈的蓝光激发和橙红光发射'激发和发射强度从BBME到BBBE不断增强。玻璃均呈现非晶态'其结构对称性相对较低'从BBME到BBBE呈下降趋势。玻璃结构主要组成为非对称的[BO
3
]三角体、松散的[BO
4
]四面体、[BiO
3
]三角体以及含[BO
4
]四面体的三硼环、四硼环和五硼环'结构中均不存在硼六圆环'也不存在含[BO
3
]三角体的五硼环、焦硼环和正硼环。研究结果表明'所研制的低温铕掺杂碱土金属硼铋酸盐玻璃具有热稳定好、折射率相对适宜的优点'有望成为未来白光LED(荧光粉)玻璃陶瓷的良好基质。
Eu
3+
doped alkaline earth bismuth borate glasses(BBME
BBCE
BBSE
BBBE)were prepared by the rapid melt quenching technique. The general physical properties including density
molar volume
optical basicity and so on were studied
the structure
optical properties as well as thermal stability of the glasses were investigated. The tightness of the glass decreases from BBME to BBBE. Eu
3+
melts homogeneously in the glasses and acts as a well activator. The intense emission peaked at 613 nm is observed in the emission spectra under 465 nm excitation. the intensity increases gradually from BBME to BBBE. All the glass samples present amorphous states and have low symmetric structure
and the symmetries decrease from BBME to BBBE. The asymmetric[BO
3
] units
loose[BO
4
] units
[BiO
3
] units and tri-
tetra-
penta-borate groups including[BO
3
] units are identified in the glass samples
however
six member rings and penta-borate
pyro-borate
ortho-borate groups consisting of[BO
3
] are not observed. The glass samples with well thermal stability
low melting temperature and appropriate refractive index are expected to be good candidates applied for WLED glass ceramic in the future.
发光材料红光发射硼铋酸盐玻璃碱土
luminescence materialred emissionbismuth borate glassalkali earth
CHONG M K, PITA K, KAM C H. Photoluminescence of Y2O3:Eu3+ thin film phosphors by sol-gel deposition and rapid thermal annealing[J]. J. Phys. Chem. of Solids, 2005, 66(1):213-217.
肖华, 吕毅军, 朱丽虹, 等. 远程荧光体白光发光二极管的发光性能[J]. 光子学报, 2014, 43(5):0523003. XIAO H, LV Y J, ZHU L H, et al.. Luminous performance of remote phosphor white LED[J]. Acta Photon. Sinica, 2014, 43(5):0523003. (in Chinese)
DA SILVA C M JR, BUENO L A, GOUVEIA-NETO A S. Er3+/Sm3+-and Tb3+/Sm3+-doped glass phosphors for application in warm white light-emitting diode[J]. J. Non-Cryst. Solids, 2015, 410:151-154.
REN L J, LEI X H, DU X Q, et al.. Effect of Eu2O3 concentration on luminescent properties of Ce/Tb/Eu co-doped calcium borosilicate glass for white LED[J]. J. Lumin., 2013, 142:150-154.
KARIMI H, LI G, WANG Q N, et al.. Preparation and luminescence properties of europium doped oxynitride glass ceramics[J]. J. Mater. Sci. Eng., 2014, 32(6):821-825.
张志敏, 向卫东, 钟家松, 等. 白光LED用Ce:YAG微晶玻璃的研究进展[J]. 材料导报, 2013, 27(9):28-33. ZHANG Z M, XIANG W D, ZHONG J S, et al.. Research progress of Ce:YAG glass-ceramic phosphor for white LED[J]. Mater. Rev., 2013, 27(9):28-33. (in Chinese)
杨志平, 梁晓双, 赵引红, 等. 橙红色荧光粉Ca3Y2(Si3O9)2:Sm3+的制备及发光性能的表征[J]. 光子学报, 2014, 43(3):0316002. YANG Z P, LIANG X S, ZHAO Y H, et al.. Preparation and luminescence properties of reddish-orange phosphors Ca3Y2-(Si3O9)2:Sm3+[J]. Acta Photon. Sinica, 2014, 43(3):0316002. (in Chinese)
HE G, LI Y Y, BU C H, et al.. Preparation of Ce-doped (Y, Gd)3Al5O12 nanoceramics by sintering and crystallization of glass microspheres[J]. Mater. Res. Bull., 2015, 66:45-50.
ZHOU Y, CHEN D Q, TIAN W D, et al.. Impact of Eu3+ dopants on optical spectroscopy of Ce3+:Y3Al5O12-embedded transparent glass-ceramics[J]. J. Am. Ceram. Soc., 2015, 98(8):2445-2450.
金怀东, 向卫东, 黄海宇, 等. Ce, Pr掺杂的YAG微晶玻璃的制备及光谱性能[J]. 无机化学学报, 2011, 27(7):1285-1290. JIN H D, XIANG W D, HUANG H Y, et al.. Preparation and luminescence properties of Ce, Pr doped YAG glass ceramics[J]. Chin. J. Inorg. Chem., 2011, 27(7):1285-1290. (in Chinese)
PAL I, AGARWAL A, SANGHI S, et al.. Structural, absorption and fluorescence spectral analysis of Pr3+ ions doped zinc bismuth borate glasses[J]. J. Alloys Compd., 2011, 509(28):7625-7631.
RAMTEKE D D, SWART H C, GEDAM R S. Spectroscopic properties of Pr3+ ions embedded in lithium borate glasses[J]. Physica B:Condens. Matter, 2016, 480:111-115.
SWAPNA K, MAHAMUDA S, RAO A S, et al.. Optical studies of Sm3+ ions doped zinc alumino bismuth borate glasses[J]. Spectrochim. Acta Part A:Mol. Biomol. Spectrosc., 2014, 125:53-60.
KESAVULU C R, KUMAR K K, VIJAYA N, et al.. Thermal, vibrational and optical properties of Eu3+-doped lead fluorophosphate glasses for red laser applications[J]. Mater. Chem. Phys., 2013, 141(2-3):903-911.
ANJAIAH J, LAXMIKANTH C, VEERAIAH N. Spectroscopic properties and luminescence behaviour of europium doped lithium borate glasses[J]. Physica B:Condens. Matter, 2014, 454:148-156.
KAEWKHAO J, BOONIN K, YASAKA P, et al.. Optical and luminescence characteristics of Eu3+ doped zinc bismuth borate (ZBB) glasses for red emitting device[J]. Mater. Res. Bull., 2015, 71:37-41.
SWAPNA K, MAHAMUDA S, RAO A S, et al.. Luminescence characterization of Eu3+ doped zinc alumino bismuth borate glasses for visible red emission applications[J]. J. Lumin., 2014, 156:80-86.
NAIDU M D, RAJESH D, BALAKRISHNA A, et al.. Kinetics of fluorescence properties of Eu3+ ion in strontium-aluminium-bismuth-borate glasses[J]. J. Rare Earths, 2014, 32(12):1140-1147.
YAO L Q, CHEN G H, CUI S C, et al.. Fluorescence and optical properties of Eu3+-doped borate glasses[J]. J. Non-Cryst. Solids, 2016, 444:38-42.
BALAJI S, AZEEM P A, REDDY R R. Absorption and emission properties of Eu3+ ions in sodium fluoroborate glasses[J]. Physica B:Condens. Matter, 2007, 394(1):62-68.
?UR L, JANEK J, SO?TYS M, et al.. Structural and optical investigations of rare earth doped lead-free germanate glasses modified by MO and MF2 (M=Ca, Sr, Ba)[J]. J. Non-Cryst. Solids, 2016, 431:145-149.
KUMAR K U, BABU S S, RAO C S, et al.. Optical and fluorescence spectroscopy of Eu2O3-doped P2O5-K2O-KF-MO-Al2O3 (M=Mg, Sr and Ba) glasses[J]. Opt. Commun., 2011, 284(12):2909-2914.
JANEK J, SO?TYS M, ?UR L, et al.. Luminescence investigations of rare earth doped lead-free borate glasses modified by MO (M=Ca, Sr, Ba)[J]. Mater. Chem. Phys., 2016, 180:237-243.
YUSUB S, RAJYASREE C, BABU A R, et al.. Influence of alkaline earth oxides (R=Ca, Sr and Ba) on spectroscopic and dielectric studies of iron doped RO-Na2O-B2O3 glasses[J]. J. Non-Cryst. Solids, 2013, 364:62-68.
SUNG Y M. Crystallization kinetics of fluoride nanocrystals in oxyfluoride glasses[J]. J. Non-Cryst. Solids, 2012, 358(1):36-39.
HOVHANNISYAN M R, HOVHANNISYAN R M, GRIGORYAN B V, et al.. A study of the phase and glass forming diagrams of the BaO-Bi2O3-B2O3 system[J]. Glass Technol. Eur. J. Glass Sci. Technol. A, 2009, 50(6):323-328.
ELBASHAR Y H, ALI M I, ELSHAIKH H A, et al.. Influence of CuO and Al2O3 addition on the optical properties of sodium zinc phosphate glass absorption filters[J]. Optik Int. J. Light Electron Opt., 2016, 127(18):7041-7053.
WAGH A, RAVIPRAKASH Y, UPADHYAYA V, et al.. Composition dependent structural and optical properties of PbF2-TeO2-B2O3-Eu2O3 glasses[J]. Spectrochim. Acta A:Mol. Biomol. Spectrosc., 2015, 151:696-706.
ARYA S K, SINGH K. Structural and optical properties of 30Li2O-55B2O3-5ZnO-xTiO2-(10-x)V2O5, (0 x 10) glasses[J]. J. Non-Cryst. Solids, 2015, 414:51-58.
齐济, 王承遇, 宁桂玲. 光学碱度在玻璃中的应用及其与元素性质的关系[J]. 硅酸盐通报, 2009, 28(5):1018-1023. QI J, WANG C Y, NING G L. Application of optical basicity in glasses and its relationship with element properties[J]. Bull. Chin. Ceram. Soc., 2009, 28(5):1018-1023. (in Chinese)
DUFFY J A. A review of optical basicity and its applications to oxidic systems[J]. Geochim. Cosmochim. Acta, 1993, 57(16):3961-3970.
CHEN D Q, CHEN Y. Transparent Ce3+:Y3Al5O12 glass ceramic for organic-resin-free white-light-emitting diodes[J]. Ceram. Int., 2014, 40(9):15325-15329.
EGORYSHEVA A V, VOLODIN V D, CHISTYAKOV A A, et al.. Luminescence of europium-doped BaO-Bi2O3-B2O3 glasses[J]. Inorg. Mater., 2010, 46(12):1384-1390.
YAZDI A R, TOWLER M. The effect of the addition of gallium on the structure of zinc borate glass with controlled gallium ion release[J]. Mater. Des., 2016, 92:1018-1027.
刘盼, 殷海荣, 郭宏伟, 等. 光学碱度对Tb3+掺杂Bi2O3-B2O3玻璃发光性能的影响[J]. 发光学报, 2014, 35(4):413-419. LIU P, YIN H R, GUO H W, et al.. Effect of optical basicity on luminescence properties of Tb3+ doped Bi2O3-B2O3 glasses[J]. Chin. J. Lumin., 2014, 35(4):413-419. (in Chinese)
PANDARINATH M A, UPENDER G, RAO K N, et al.. Thermal, optical and spectroscopic studies of boro-tellurite glass system containing ZnO[J]. J. Non-Cryst. Solids, 2016, 433:60-67.
YAO Z Y, MNCKE D, KAMITSOS E I, et al.. Structure and mechanical properties of copper-lead and copper-zinc borate glasses[J]. J. Non-Cryst. Solids, 2016, 435:55-68.
TARAFDER A, MOLLA A R, KARMAKAR B. Processing and properties of Eu3+-doped transparent YAG (Y3Al5O12) nanoglass-ceramics[J]. J. Am. Ceram. Soc., 2010, 93(10):3244-3251.
张明熹, 李锋锋, 张林, 等. ZnO-B2O3-SiO2玻璃红外光谱的研究[J]. 硅酸盐通报, 2009, 28(5):1050-1053. ZHANG M X, LI F F, ZHANG L, et al.. Study on infrared spectra of ZnO-B2O3-SiO2 glass[J]. Bull. Chin. Ceram. Soc., 2009, 28(5):1050-1053. (in Chinese)
COLAK S C, AKYUZ I, ATAY F. On the dual role of ZnO in zinc-borate glasses[J]. J. Non-Cryst. Solids, 2016, 432:406-412.
MOHSEN M, GOMAA E, AL-KOTB M S, et al.. Positron annihilation lifetime and Fourier transform infrared spectroscopic studies on Bi2O3-B2O3 glasses[J]. J. Non-Cryst. Solids, 2016, 436:1-8.
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