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1. 安阳市质量技术监督检验测试中心,河南 安阳,455000
2. 广西师范大学化学与药学学院 教育部药用资源化学与药物分子工程重点实验室,广西 桂林,541004
纸质出版日期:2017-1-5,
收稿日期:2016-6-23,
修回日期:2016-9-23,
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赵丽敏, 陈丽妮, 赵书林. 基于石墨烯量子点的荧光探针应用于抗坏血酸检测的研究[J]. 发光学报, 2017,38(1): 124-131
ZHAO Li-min, CHEN Li-ni, ZHAO Shu-lin. Detection of Ascorbic Acid by Fluorescence Probe Based on Graphene Quantum Dots[J]. Chinese Journal of Luminescence, 2017,38(1): 124-131
赵丽敏, 陈丽妮, 赵书林. 基于石墨烯量子点的荧光探针应用于抗坏血酸检测的研究[J]. 发光学报, 2017,38(1): 124-131 DOI: 10.3788/fgxb20173801.0124.
ZHAO Li-min, CHEN Li-ni, ZHAO Shu-lin. Detection of Ascorbic Acid by Fluorescence Probe Based on Graphene Quantum Dots[J]. Chinese Journal of Luminescence, 2017,38(1): 124-131 DOI: 10.3788/fgxb20173801.0124.
基于石墨烯量子点(GQDs)的荧光性能建立了一种非标记荧光方法,用于灵敏和选择性测定抗坏血酸(AA)。GQDs溶液在紫外光激发下发出很强的蓝色荧光,当向溶液中加入AA后,GQDs溶液的荧光被猝灭。猝灭机理可能为在弱酸性介质中,AA与GQDs发生氧化还原反应,AA转移电子给GQDs。荧光猝灭强度与AA浓度在5.010
-6
~7.510
-5
mol/L范围内呈良好的线性关系,检出限低至1.010
-6
mol/L。该体系成本低、操作简单,并且在多种可能干扰的物质存在下对AA表现出很高的选择性。本方法应用于生物样品中AA的检测,回收率在95.2%~115.3%之间。
A label-free fluorescence method based on the fluorescence property of graphene quantum dots (GQDs) was developed for sensitive and selective detection of ascorbic acid (AA). The initial strong blue fluorescence of the GQDs in aqueous solution was effectively quenched upon addition of AA. The quenching mechanism may involve transfer of electrons from AA to GQDs
via
the redox reaction of AA and GQDs in weak acid solution. The quenching efficiency was linearly proportional to the concentration of AA within the range of 5.010
-6
-7.510
-5
mol/L with a low detection limit down to 1.010
-6
mol/L. The proposed sensing system is simple and low-cost with facile experimental operations
and has a high selectivity for AA over a number of possible interfering species. Additionally
this method was successfully applied to the determination of AA in biological samples with satisfactory recoveries (95.2%-115.3%).
石墨烯量子点荧光探针非标记方法抗坏血酸
graphene quantum dotsfluorescence probelabel-free methodascorbic acid
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