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Tm3+/Er3+/Yb3+掺杂的镓锗酸盐玻璃光谱性能及能量传递
Spectroscopic Properties and Energy Transfer of Tm3+/Er3+/Yb3+-doped Ga2O3-GeO2 Glass
- 发光学报 2017年38卷第1期 页码：50-56
- 作者机构：
洛阳理工学院 材料科学与工程学院,河南 洛阳,471023
- 作者简介：
- 基金信息：国家自然科学基金（51002070）();河南省教育厅科学技术研究重点项目（16A430040，14A430034）资助()
DOI：10.3788/fgxb20173801.0050
中图分类号： TQ171;O482.31纸质出版日期：2017-1-5，
收稿日期：2016-7-10，
修回日期：2016-8-26，
扫 描 看 全 文
石冬梅, 赵营刚,. Tm<sup>3+</sup>/Er<sup>3+</sup>/Yb<sup>3+</sup>掺杂的镓锗酸盐玻璃光谱性能及能量传递[J]. 发光学报, 2017,38(1): 50-56
SHI Dong-mei, ZHAO Ying-gang,. Spectroscopic Properties and Energy Transfer of Tm<sup>3+</sup>/Er<sup>3+</sup>/Yb<sup>3+</sup>-doped Ga<sub>2</sub>O<sub>3</sub>-GeO<sub>2</sub> Glass[J]. Chinese Journal of Luminescence, 2017,38(1): 50-56
石冬梅, 赵营刚,. Tm<sup>3+</sup>/Er<sup>3+</sup>/Yb<sup>3+</sup>掺杂的镓锗酸盐玻璃光谱性能及能量传递[J]. 发光学报, 2017,38(1): 50-56 DOI： 10.3788/fgxb20173801.0050.
SHI Dong-mei, ZHAO Ying-gang,. Spectroscopic Properties and Energy Transfer of Tm<sup>3+</sup>/Er<sup>3+</sup>/Yb<sup>3+</sup>-doped Ga<sub>2</sub>O<sub>3</sub>-GeO<sub>2</sub> Glass[J]. Chinese Journal of Luminescence, 2017,38(1): 50-56 DOI： 10.3788/fgxb20173801.0050.
摘要
采用熔融淬冷法制备得到透明的Tm
3+
/Er
3+
/Yb
3+
掺杂镓锗钠玻璃。对比研究了808 nm和980 nm激发下Tm
2
O
3
含量对样品可见-红外光学光谱特性的影响。结合稀土离子能级结构，分析了Tm
3+
、Er
3+
和Yb
3+
离子之间的能量传递机制。结果表明：在808 nm和980 nm的激发下，Tm
3+
/Er
3+
/Yb
3+
掺杂样品中均观察到了473，655，521，544 nm的蓝、红和绿光。在808 nm激发下，随着Tm
3+
浓度的增加，Tm
3+
：1 800 nm和Er
3+
：1 530 nm发射强度的比率I
1.8
/I
1.53
逐渐增大。由于在Tm
3+
和Er
3+
间的能量传递有效地改变了红光和绿光的发射强度，473，521，655 nm的发光强度呈现先升高再降低的趋势，在Tm
2
O
3
掺杂摩尔分数为0.3%时达到最大值。而在980 nm激发下，由于Yb
3+
对Er
3+
和Tm
3+
的能量传递起主要作用，使得其上转换红光（655 nm）、绿光（521 nm和544 nm）和蓝光（473 nm）的发光强度高于808 nm激发下的上转换发光。
Abstract
The transparent Ga
2
O
3
-GeO
2
-Na
2
O glasses doped with Tm
3+
/Er
3+
/Yb
3+
were prepared by melting quenching method. The effects of Tm
2
O
3
contents on the visible and infrared spectra of the samples under 808 and 980 nm excitation were compared. The mechanisms of energy transfer between Tm
3+
Er
3+
and Yb
3+
ions were analyzed combining with the energy level of rare earth ions. The results show that the obvious blue (473 nm)
red (655 nm)
green (521 and 544 nm) emission can be observed in Tm
3+
/Er
3+
/Yb
3+
-codoped sample. I
1.8
/I
1.53
(intensity ratio of Tm
3+
:1 800 nm and Er
3+
:1 530 nm) are enhanced and the red and green upconversion emission intensities under the excitation of 808 nm are adjusted due to the efficient energy transfer between Er
3+
and Tm
3+
with the increase of Tm
3+
concentration. Correspondently
the emission intensity of 473
521 and 655 nm show a trend of firstly increasing and then decreasing
and achieve the maximum value when the mole fraction of Tm
2
O
3
is up to 0.3%. The upconversion red
green and blue emission intensity under 980 nm excitation is higher than that of 808 nm because of the sensitizing effect of Yb
3+
to Er
3+
and Tm
3+
.
关键词
Ga2O3-GeO2-Na2O玻璃Tm3+/Yb3+/Er3+光谱性能能量传递
Keywords
Ga2O3-GeO2-Na2O glassTm3+/Yb3+/Er3+spectroscopic propertiesenergy transfer
references
LI X Y, ZHOU S S, JIANG G C, et al.. Blue upconversion of Tm3+ using Yb3+ as energy transfer bridge under 1532 nm excitation in Er3+, Yb3+, Tm3+ tri-doped CaMoO4[J]. J. Rare Earths, 2015, 33(5):475-479.
吴一, 张汇锋, 冯建国, 等. Ag纳米颗粒对Er3+/Tm3+/Yb3+共掺铋锗酸盐玻璃上转换发光特性的影响[J]. 光电子激光, 2014, 25(1):96-100. WU Y, ZHANG H F, FENG J G, et al.. Effect of Ag nanoparticles on upconversion luminescence properties of Er3+/Tm3+/Yb3+ codoped bismuth germanate glasses[J]. J. Optoelectron.Laser, 2014, 25(1):96-100. (in Chinese)
王倩, 张为欢, 欧阳绍业, 等. Dy3+-Tb3+掺杂氟氧碲酸盐玻璃的光谱性能研究[J]. 光子学报, 2015, 44(1):0116004. WANG Q, ZHANG W H, OUYANG S Y, et al.. Luminescence properties of oxyfluoride tellurite glasses doped with Dy3+ ions and Tb3+ ions[J]. Acta Photon. Sinica, 2015, 44(1):0116004. (in Chinese)
韩万磊, 贾玉涛, 宋瑛林. Tm3+-Er3+-Yb3+共掺的氟氧化物玻璃陶瓷的发光特性[J]. 光学学报, 2011, 31(2):0216001-1-5. HAN W L, JIA Y T, SONG Y L. Characters of luminescence from Tm3+-Er3+-Yb3+ tri-doped oxyfluoride glass ceramics[J]. Acta Opt. Sin., 2011, 31(2):0216001-1-5. (in Chinese).
LI M, LIU X Q, GUO Y Y, et al..~2m fluorescence radiative dynamics and energy transfer between Er3+ and Tm3+ ions in silicate glass[J]. Mater. Res. Bull., 2014, 51:263-270.
FARES H, ELHOUICHET H, GELLOZ B, et al.. Surface plasmon resonance induced Er3+ photoluminescence enhancement in tellurite glass[J]. J. Appl. Phys., 2015, 117(19):193102.
ZHAO Z Y, AI B, LIU C, et al.. Er3+ ions-doped germano-gallate oxyfluoride glass-ceramics containing BaF2 Nanocrystals[J]. J. Am. Ceram. Soc., 2015, 98(7):2117-2121.
徐军. 激光材料科学与技术前沿[M]. 上海:上海交通大学出版社, 2007:238-240. XU J. Laser Materials Science and Technology Frontier [M]. Shanghai:Shanghai Jiaotong University Press, 2007:238-240. (in Chinese)
HEO J, SHIN Y B, JANG J N. Spectroscopic analysis of Tm3+ in PbO-Bi2O3-Ga2O3 glass[J]. Appl. Opt., 1995, 34(21):4284-4289.
CHOI Y G, KIM K H, HEO J. Spectroscopic properties of and energy transfer in PbO-Bi2O3-Ga2O3 glass doped with Er2O3[J]. J. Am. Ceram. Soc., 1999, 82(10):2762-2768.
BALDA R, FERNNDEZ J, SANZ M, et al.. Laser spectroscopy of Nd3+ ions in GeO2-PbO-Bi2O3 glasses[J]. Phys. Rev. B, 2000, 61(5):3384-3390.
OLIVEIRA A S, DE ARAUJO M T, GOUVEIA-NETO A S, et al.. Upconversion fluorescence spectroscopy of Er3+/Yb3+-doped heavy metal Bi2O3-Na2O-Nb2O5-GeO2 glass[J]. J. Appl. Phys., 1998, 83(1):604-606.
CAI M Z, ZHOU B E, WANG F C, et al.. Mid-infrared emission and quantitative analysis of energy transfer processes in Er3+ doped oxyfluogermanate glasses[J]. J. Appl. Phys., 2015, 117(24):243106-1-10.
NIE Q H, JIANG C, WANG X S, et al.. Upconversion and fluorescence spectral studies of Er3+/Yb3+-codoped Bi2Q3-GeO2-Ga2Q3-Na2O glasses[J]. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 2007, 66(2):278-281.
郭琳娜, 王育华. 共沉淀制备Y2SiO5:Er3+,Yb3+,Tm3+及其上转换发光性能研究[J]. 物理学报, 2011, 60(2):027803-1-6. GUO L N, WANG Y H. Upconversion luminescence properties of Y2SiO5:Er3+,Yb3+,Tm3+ synthesized by co-precipitation method[J]. Acta Phys. Sinica, 2011, 60(2):027803-1-6. (in Chinese)
PENG S X, YANG F J, WU L B, et al.. Tm3+/Ho3+/Yb3+ codoped tellurite glass for multicolor emission-structure, thermal stability and spectroscopic properties[J]. J. Alloys Compd., 2014, 609:14-20.
FANG Y Z, ZHAO G Y, XU J Y, et al.. Energy transfer and 1.8m emission in Yb3+/Tm3+ co-doped bismuth germanate glass[J]. Ceram. Int., 2014, 40(4):6037-6043.
DE SOUZA A B, DE ARAUJO M T, VERMELHO M V D, et al.. Energy transfer between Tm3+ and Er3+ ions in a TeO2-based glass pumped at diode laser wavelength[J]. J. Non-Cryst. Solids, 2007, 353(1):94-101.
HUANG L H, JHA A, SHEN S X, et al.. Broadband emission in Er3+-Tm3+ codoped tellurite fibre[J]. Opt. Express, 2004, 12(11):2429-2434.
MAHALINGAM V, MANGIARINI F, VETRONE F, et al.. Bright white upconversion emission from Tm3+/Yb3+/Er3+-doped Lu3Ga5O12 nanocrystals[J]. J. Phys. Chem. C, 2008, 112(46):17745-17749.
BAI Y F, WANG Y X, PENG G Y, et al.. Enhanced white light emission in Er/Tm/Yb/Li codoped Y2O3 nanocrystals[J]. Opt. Commun., 2009, 282(9):1922-1924.
HU H, BAI Y. Upconversion white luminescence of TeO2:Tm3+/Er3+/Yb3+ nanoparticles[J]. J. Alloys Compd., 2012, 527:25-29.
ZOU X L, SHIKIDA A, YANAGITA H, et al.. Mechanisms of upconversion fluorescences in Er3+, Tm3+ codoped fluorozircoaluminate glasses[J]. J. Non-Cryst. Solids, 1995, 181(1-2):100-109.
XING L L, WANG R, XU W, et al.. Upconversion white-light emission in Ho3+/Yb3+/Tm3+ codoped LiNbO3 polycrystals[J]. J. Lumin., 2012, 132(6):1568-1574.
CHEN D Q, WANG Y S, ZHENG K L, et al.. Bright upconversion white light emission in transparent glass ceramic embedding Tm3+/Er3+/Yb3+:-YF3 nanocrystals[J]. Appl. Phys. Lett., 2007, 91(25):251903-1-3.
LOZANO B W, DE ARAU'JO C B, MESSADDEQ Y. Enhanced frequency upconversion in Er3+ doped fluoroindate glass due to energy transfer from Tm3+[J]. J. Non-Cryst. Solids, 2002, 311(3):318-322.
MARTIN I R, MNDEZ-RAMOS J, RODRIGUEZ V D, et al.. Increase of the 800 nm excited Tm3+ blue upconversion emission in fluoroindate glasses by codoping with Yb3+ ions[J]. Opt. Mater., 2003, 22(4):327-333.
TANABE S, HAYASHI H, HANADA T. Improved fluorescence from Tm-Ho- and Tm-Ho-Eu-codoped transparent PbF2 glass-ceramics for S+-band amplifiers[J]. J. Am. Ceram. Soc., 2002, 85(4):839-843.
戴世勋, 杨建虎, 柳祝平, 等. 970 nm抽运下Er3+/Yb3+/Tm3+共掺碲酸盐玻璃的发光特性[J]. 物理学报, 2003, 52(3):729-735. DAI S X, YANG J H, LIU Z P, et al.. The luminescence of Er3+, Yb3+, Tm3+-codoped tellurite glass pumped at 970 nm[J]. Acta Phys. Sinica, 2003, 52(3):729-735. (in Chinese)
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