基质中非4f组态的电子态对Pr3+离子发光的影响

刘峰; 王笑军

doi:10.3788/fgxb20173801.0001

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基质中非4f组态的电子态对Pr³⁺离子发光的影响

特邀报告 | 更新时间：2020-08-12

- 基质中非4f组态的电子态对Pr³⁺离子发光的影响
- Effects of Non-4f States on Pr³⁺ Luminescence in Phosphors
- 发光学报 2017年38卷第1期页码：1-6
- 作者机构：
  
  1. Department of Physics, Georgia Southern University, Statesboro GA,USA,30460
  2. College of Engineering, Department of Physics and Astronomy, University of Georgia,GA Athens,USA,30602
- 作者简介：
  
  [ "刘峰(1978-),男,吉林长春人,2007年于中科院长春光机所获凝聚态物理专业博士学位,2007年开始在美国佐治亚大学工作至今,现作为学术研究员任职于工学院。主要从事发光物理和发光材料的研究,尤其是对新颖荧光材料的谱学表征和光存储材料的物理功能调控,成果发表于Physical Review Letters和Nature Materials等学术刊物。E-mail:fliu@uga.edu" ]
  [ "王笑军(1958-),男,吉林舒兰人,美国南佐治亚大学物理系教授,1992年于美国佐治亚大学获物理博士学位,1992-1995年在俄克拉荷马州立大学及加州大学尔湾分校做博士后研究,1995年在美国南佐治亚大学物理系工作至今。主要从事发光物理和发光材料的研究。发表学术论文及著作章节200余篇(章)。现为国际发光大会IPC委员,LSA、MRB杂志编辑,发光学报、中国稀土学报编委等。E-mail:xwang@georgiasouthern.edu" ]
- 基金信息：
- DOI：10.3788/fgxb20173801.0001
  中图分类号： O482.31
- 纸质出版日期：2017-1-5，
  
  收稿日期：2016-10-24，
  
  修回日期：2016-11-27，
扫描看全文
刘峰, 王笑军,. 基质中非4f组态的电子态对Pr3+离子发光的影响[J]. 发光学报, 2017,38(1): 1-6

LIU Feng, WANG Xiao-jun,. Effects of Non-4f States on Pr3+ Luminescence in Phosphors[J]. Chinese Journal of Luminescence, 2017,38(1): 1-6
刘峰, 王笑军,. 基质中非4f组态的电子态对Pr3+离子发光的影响[J]. 发光学报, 2017,38(1): 1-6 DOI： 10.3788/fgxb20173801.0001.

LIU Feng, WANG Xiao-jun,. Effects of Non-4f States on Pr3+ Luminescence in Phosphors[J]. Chinese Journal of Luminescence, 2017,38(1): 1-6 DOI： 10.3788/fgxb20173801.0001.

摘要

三价镨离子（Pr

）是一种备受关注的稀土发光离子。学者们在过去几十年里对其发光性质进行了大量的理论和实验研究。在不同的基质材料中，由于非4f组态的电子态与Pr

离子发光能级相互作用，Pr

离子可以展现从紫外到红外波段的不同特征的光发射。影响Pr

离子发光的这些电子态可能源于4f5d激发组态、电荷迁移态或类激子态。本文中，我们以几种具有代表性的发光材料为例，简短地总结和评述了Pr

离子发光的不同谱形；也尝试解释了几个新颖的实验现象，例如：杂质束缚激子态和电荷迁移态对发光的猝灭影响。我们希望这些相关概念和谱学结果的整理有助于读者更好地理解一些实验上的发光现象，并为设计发光材料提供新的思路。

Abstract

Different emission wavelengths of Pr

ion

from the ultraviolet to the infrared

may result from the effects of non-4f states in phosphors. Such non-4f states generally refer to the Pr

4f5d state

exciton-like state or charge-transfer state. Here

we present a brief review on Pr

luminescence by the means of emission spectral measurement in several representative phosphors. Several interesting spectral phenomena are reported and reviewed

including the effects of impurity-trapped exciton state and charge-transfer state on the luminescence quenching in the Pr

-activated phosphors. We expect this review is beneficial to the readers to better understand their experimental findings

and to inspire them to design new and improved phosphor systems.

关键词

Pr3+1S0发射1D2发射杂质束缚激子态电荷迁移态红外发光

Keywords

Pr3+1S0 emission1D2 emissionimpurity-trapped excitoncharge-transfer stateinfrared

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