丁二炔衍生物的制备及其光学特性

崔丽影; 宋志洋; 赵欣宇; 于存龙

doi:10.3788/fgxb20163712.1491

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丁二炔衍生物的制备及其光学特性

材料合成及性能 | 更新时间：2020-08-12

- 丁二炔衍生物的制备及其光学特性
- Fabrication and Optical Property of Diacetylene Derivative
- 发光学报 2016年37卷第12期页码：1491-1495
- 作者机构：
  
  吉林农业大学资源与环境学院, 吉林长春 130118
- 作者简介：
- 基金信息：
  
  国家自然科学基金青年基金（51403076）资助项目()
- DOI：10.3788/fgxb20163712.1491
  中图分类号： TP394.1;O63
- 纸质出版日期：2016-12-10，
  
  收稿日期：2016-7-25，
  
  修回日期：2016-9-13，
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崔丽影, 宋志洋, 赵欣宇等. 丁二炔衍生物的制备及其光学特性[J]. 发光学报, 2016,37(12): 1491-1495

CUI Li-ying, SONG Zhi-yang, ZHAO Xin-yu etc. Fabrication and Optical Property of Diacetylene Derivative[J]. Chinese Journal of Luminescence, 2016,37(12): 1491-1495
崔丽影, 宋志洋, 赵欣宇等. 丁二炔衍生物的制备及其光学特性[J]. 发光学报, 2016,37(12): 1491-1495 DOI： 10.3788/fgxb20163712.1491.

CUI Li-ying, SONG Zhi-yang, ZHAO Xin-yu etc. Fabrication and Optical Property of Diacetylene Derivative[J]. Chinese Journal of Luminescence, 2016,37(12): 1491-1495 DOI： 10.3788/fgxb20163712.1491.

摘要

利用一步酯化法并进一步通过重结晶纯化法成功地合成了含螺吡喃基团的丁二炔衍生物，并对其进行了

H NMR、质谱、元素分析、DSC、TGA和红外表征。测试结果表明，样品的熔点为55℃，具有较好的热稳定性，直到282℃才开始分解。接着对样品进行了光学测试，紫外光谱表明，经254 nm紫外光照射后，其最大吸收峰大约位于564 nm。荧光光谱表明，其最大荧光发射波长位于大约650 nm。化合物膜的耐疲劳测试表明，样品具有很好的耐疲劳性。

Abstract

The spiropyran functionalized diacetylene derivative was prepared by esterification reaction between 10

12-pentacosadiynoic acid and 3'

3'-Dimethyl-6-nitro-spiro[2H-1-benzopyran-2

2'-indoline]-1'-ethanol. Then

it was purified

via

recrystallization and characterized through

H NMR

MALDI-TOF-MS

elemental analysis

DSC

TGA

IR. The results show that the melt point of the sample is 55℃. It has good thermal stability and begins to decompose until to 282℃. The absorption spectrum shows only one absorption peak (

max

=564 nm) irradiated by UV light (

=254 nm). The fluorescence spectra indicate the fluorescence peak position is at about 650 nm when the excitation light wavelength varying from 560 to 580 nm. The photoreaction reversibility of the target compound doped in PMMA film is detected

and the results confirm that it has good fatigue resistance.

关键词

丁二炔螺吡喃光学性能

Keywords

diacetylenespiropyranoptical property

references

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