Er3+掺杂Na5Lu9F32单晶体的红外光学特性

汤庆阳; 王成; 夏海平; 何仕楠; 江浩川; 陈宝玖

doi:10.3788/fgxb20163710.1189

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Er³⁺掺杂Na₅Lu₉F₃₂单晶体的红外光学特性

材料合成及性能 | 更新时间：2020-08-12

- Er³⁺掺杂Na₅Lu₉F₃₂单晶体的红外光学特性
- Infrared Optical Properties of Er³⁺ Doped Na₅Lu₉F₃₂ Single Crystal
- 发光学报 2016年37卷第10期页码：1189-1194
- 作者机构：
  
  1. 宁波大学光电子功能材料重点实验室,浙江宁波,315211
  2. 中国科学院宁波材料技术与工程研究所,浙江宁波,315211
  3. 大连海事大学物理系, 辽宁大连 116026
- 作者简介：
- 基金信息：
  
  国家自然科学基金（51472125，51272109）();浙江省自然科学基金（Z17E020003）();宁波大学王宽诚幸福基金资助项目()
- DOI：10.3788/fgxb20163710.1189
  中图分类号： O482.31
- 纸质出版日期：2016-10-5，
  
  收稿日期：2016-5-5，
  
  修回日期：2016-6-15，
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汤庆阳, 王成, 夏海平等. Er3+掺杂Na5Lu9F32单晶体的红外光学特性[J]. 发光学报, 2016,37(10): 1189-1194

TANG Qing-yang, WANG Cheng, XIA Hai-ping etc. Infrared Optical Properties of Er3+ Doped Na5Lu9F32 Single Crystal[J]. Chinese Journal of Luminescence, 2016,37(10): 1189-1194
汤庆阳, 王成, 夏海平等. Er3+掺杂Na5Lu9F32单晶体的红外光学特性[J]. 发光学报, 2016,37(10): 1189-1194 DOI： 10.3788/fgxb20163710.1189.

TANG Qing-yang, WANG Cheng, XIA Hai-ping etc. Infrared Optical Properties of Er3+ Doped Na5Lu9F32 Single Crystal[J]. Chinese Journal of Luminescence, 2016,37(10): 1189-1194 DOI： 10.3788/fgxb20163710.1189.

摘要

采用坩埚下降法成功地生长了Er

离子掺杂的Na

（NLF）单晶体。测定了单晶体在400~2 500 nm波段的吸收光谱与2.5~25 m红外波段的透过光谱。Na

单晶体在400~7 150 nm宽波段范围具有好的光学透过性，在该波段的透过率达到90%。在透过光谱中几乎观察不到2.7 m中红外波段的吸收，说明单晶体中OH

离子的含量极低。根据测定的吸收光谱，通过Judd-Ofelt理论计算了Er

在单晶体中的光学强度参数

（

=2.08，

=2.07，

=0.75），以及相应的辐射跃迁速率、荧光分支比和荧光寿命。根据Futchbauer-Ladenburg公式估算了样品的发射截面大约分别为1.4210

-20

（

13/2

15/2

）和1.6610

-20

（

11/2

13/2

）。在980 nm半导体激光器（LD）激发下，研究了单晶体的近红外1.5 m与中红外2.7 m的发射光谱特性。

Abstract

doped Na

single crystal was successfully grown by Bridgman method. The absorption spectra of the single crystal from 400 nm to 2 500 nm and the transmission characteristics from 2.5 m to 25 m were measured. Na

single crystal possessed high optical transmittance from 400 nm to 7 150 nm wide band

and the transmittance reached to 90%. Almost no absorption of 2.7 m band was observed. It indicated that the content of OH

ion was very low in the single crystal. The intensity parameters

(

=2.08

=2.07

=0.75) were calculated by using Judd-Ofelt theory based on the absorption spectrum. The radiative transition rates

branching ratios and radiative lifetimes were also obtained. The emission cross sections of the sample were 1.4210

-20

(

13/2

15/2

) and 1.6610

-20

(

11/2

13/2

) estimated by Futchbauer-Ladenburg formula. The emission spectra of 1.5 m and 2.7 m band were investigated under 980 nm LD.

关键词

Er3+Na5Lu9F32单晶体近红外中红外

Keywords

Er3+Na5Lu9F32 single crystalnear-infraredmid-infrared

references

ZHU D J, XUE L, LI G P, et al.. A highly sensitive near-infrared ratiometric fluorescent probe for detecting nitroreductase and cellular imaging [J]. Sens. Actuators B: Chem., 2016, 222:419-424.

STOEPPLER G, PARISI D, TONELLI M, et al.. High-efficiency 1.9 m Tm3+:LiLuF4 thin-disk laser [J]. Opt. Lett., 2012, 37(7):1163-1165.

WANG C, XIA H P, FENG Z G, et al.. Infrared spectral properties for -NaYF4 single crystal of various Er3+ doping concentrations [J]. Opt. Laser Technol., 2016, 82:157-162.

姜永章,夏海平,张加忠,等. 单晶体-NaYF4:DY3+的制备及光谱特性 [J]. 光子学报, 2015, 44(8):0816001. JIANG Y Z, XIA H P, ZHANG J Z, et al.. Growth and optical spectra of DY3+ doped -NaYF4 single crystal [J]. Acta Photon. Sinica, 2015, 44(8):0816001. (in Chinese)

LI X B, GAI S L, LI C X, et al.. Monodisperse lanthanide fluoride nanocrystals: synthesis and luminescent properties [J]. Inorg. Chem., 2012, 51(7):3963-3971.

於杏燕,陈红兵,王苏静,等. Er3+:LiYF4单晶生长与光谱特性 [J]. 无机材料学报, 2011, 26(9):923-928. YU X Y, CHEN H B, WANG S J, et al.. Growth and spectral properties of Er3+:LiYF4 single crystal [J]. J. Inorg. Mater., 2011, 26(9):923-928. (in Chinese)

THOMA R E, INSLEY H, HEBERT G M. The sodium fluoride-lanthanide trifluoride systems [J]. Inorg. Chem., 1966, 5(7):1222-1229.

SHMYT'KO I M, STRUKOVA G K. Fine sructure of Na5Lu9F32 nanocrystallites formed at the initial stages of crystallization [J]. Phys. Solid State, 2009, 51(9):1907-1911.

YANG S, XIA H P, ZHANG J Z, et al.. Growth and spectral properties of Ho3+ doped -NaYF4 single crystal [J]. Opt. Mater., 2015, 45:209-214.

秦忠雪,袁孝,熊宝星,等. 掺钕TeO2-Al2O3-Cs2O玻璃的Judd-Ofelt理论分析与光谱特性 [J]. 光子学报, 2014, 43(6):616002-1-6. QIN Z X, YUAN X, XIONG B X, et al.. Judd-Ofelt theory analysis and spectroscopic properties of Nd3+-doped TeO2-Al2O3-Cs2O tellurite glasses [J]. Acta Photon. Sinica, 2014, 43(6):616002-1-6. (in Chinese)

YUAN F F, ZHAO W, SUN S J, et al.. Polarized spectroscopic properties of Er3+:Ca9Y(VO4)7 crystal [J]. J. Lumin., 2014, 154:241-245.

QIAN Y N, XIE Z X, WANG R, et al.. Efficient 1.54 m laser property in near-stoichiometric Er:LiNbO3 crystal [J]. Opt. Laser Technol., 2015, 74:173-177.

GEORGESCU ?,?TEFAN A, TOMA O. Judd-Ofelt and energy-transfer analysis of Er3+ doped in CaSc2O4 ceramic samples [J]. J. Lumin., 2015, 167:186-192.

GHEORGHE C, GEORGESCU S, LUPEI V, et al.. Absorption intensities and emission cross section of Er3+ in Sc2O3 transparent ceramics [J]. J. Appl. Phys., 2008, 103(8):083116-1-5.

HUANG L H, YAMASHITA T, JOSE R, et al.. Intense ultraviolet emission from Tb3+ and Yb3+ codoped glass ceramic containing CaF2 nanocrystals [J]. Appl. Phys. Lett., 2007, 90(13):131116-1-3.

ZHANG F, BI Z F, CHEN J Y, et al.. Spectroscopic investigation of Er3+ in fluorotellurite glasses for 2.7 m luminescence [J]. J. Alloys Compd., 2015, 649:1191-1196.

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