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Dy3+和Tb3+掺杂镓硼锗硅酸盐玻璃发光性能
Luminescence Properties of Ga2O3-B2O3-GeO2-SiO2 Glass Doped with Dy3+ and Tb3+
- 发光学报 2016年37卷第9期 页码：1043-1049
- 作者机构：
陕西科技大学 材料科学与工程学院,陕西 西安,710021
- 作者简介：
- 基金信息：国家自然科学基金（51472151）();国际科技合作计划（2009DFR50520）();陕西科技大学博士科研启动基金（BJ15-16）资助项目()
DOI：10.3788/fgxb20163709.1043
中图分类号： O482.31纸质出版日期：2016-9-5，
收稿日期：2016-4-20，
修回日期：2016-5-17，
扫 描 看 全 文
殷海荣, 唐元元, 郭宏伟, 莫祖学, 王宇飞, 宋建波. Dy<sup>3+</sup>和Tb<sup>3+</sup>掺杂镓硼锗硅酸盐玻璃发光性能[J]. 发光学报, 2016,37(9): 1043-1049
YIN Hai-rong, TANG Yuan-yuan, GUO Hong-wei, MO Zu-xue, WANG Yu-fei, SONG Jian-bo. Luminescence Properties of Ga<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-GeO<sub>2</sub>-SiO<sub>2</sub> Glass Doped with Dy<sup>3+</sup> and Tb<sup>3+</sup>[J]. 发光学报, 2016,37(9): 1043-1049
殷海荣, 唐元元, 郭宏伟, 莫祖学, 王宇飞, 宋建波. Dy<sup>3+</sup>和Tb<sup>3+</sup>掺杂镓硼锗硅酸盐玻璃发光性能[J]. 发光学报, 2016,37(9): 1043-1049 DOI： 10.3788/fgxb20163709.1043.
YIN Hai-rong, TANG Yuan-yuan, GUO Hong-wei, MO Zu-xue, WANG Yu-fei, SONG Jian-bo. Luminescence Properties of Ga<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-GeO<sub>2</sub>-SiO<sub>2</sub> Glass Doped with Dy<sup>3+</sup> and Tb<sup>3+</sup>[J]. 发光学报, 2016,37(9): 1043-1049 DOI： 10.3788/fgxb20163709.1043.
摘要
采用高温熔融法分别制备了高含量Tb
3+
单掺和Dy
3+
/Tb
3+
共掺的镓硼锗硅酸盐（GBSG）发光玻璃，并分析了其光谱性能。根据Dy
3+
和Tb
3+
掺杂的镓硼锗硅酸盐（GBSG）玻璃的激发和发射光谱、荧光寿命衰减曲线等特性，探讨了Dy
3+
与Tb
3+
之间的能量传递关系。结果表明：玻璃的发光强度和荧光寿命随着Tb
3+
、Dy
3+
含量的增加而减少。与相同摩尔浓度的单掺玻璃相比，共掺玻璃发光强度的衰减速率先减慢而后加快。Tb
3+
、Dy
3+
离子之间的能量传递方式为无辐射共振能量传递和
4
F
9/2
+
7
F
6
6
H
15/2
+
5
D
4
交叉弛豫效应。
Abstract
Ga
2
O
3
-B
2
O
3
-GeO
2
-SiO
2
glasses doped with high Tb
3+
concentration and co-doped with Tb
3+
and Dy
3+
were synthesized by high temperature melting method. The energy transfer between Tb
3+
and Dy
3+
was studied according to the excitation and emission spectra and decay time. The results show that the emission intensity and fluorescence lifetime decrease with the increasing of Tb
3+
and Dy
3+
content. Compared with the same content of Tb
3+
single doped glass
the luminous intensity of Dy
3+
/Tb
3+
co-doped glass first decreases slowly
and then decreases rapidly. It can be concluded that the energy transfer mechanism between Tb
3+
and Dy
3+
includes nonradiative energy resonance transfer and
4
F
9/2
+
7
F
6
6
H
15/2
+
5
D
4
cross relaxation effect.
关键词
能量传递Dy3+/Tb3+共掺发光性能镝离子铽离子
Keywords
energy transferDy3+/Tb3+ co-dopedluminescencedysprosium ionterbium ion
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