浏览全部资源
扫码关注微信
1. 西南科技大学 信息工程学院,四川 绵阳,621010
2. 西南科技大学极端物质特性实验室,四川 绵阳,621010
3. 特殊环境机器人四川省重点实验室,四川 绵阳,621010
纸质出版日期:2016-5-5,
收稿日期:2016-1-25,
修回日期:2016-3-11,
扫 描 看 全 文
刘泉澄, 邓琥, 尚丽平. 太赫兹时域光谱的α/β型HMX定量研究[J]. 发光学报, 2016,37(5): 631-636
LIU Quan-cheng, DENG Hu, SHANG Li-ping. Quantitative Investigation of α/β HMX Based on Terahertz Time Domain Spectroscopy System[J]. Chinese Journal of Luminescence, 2016,37(5): 631-636
刘泉澄, 邓琥, 尚丽平. 太赫兹时域光谱的α/β型HMX定量研究[J]. 发光学报, 2016,37(5): 631-636 DOI: 10.3788/fgxb20163705.0631.
LIU Quan-cheng, DENG Hu, SHANG Li-ping. Quantitative Investigation of α/β HMX Based on Terahertz Time Domain Spectroscopy System[J]. Chinese Journal of Luminescence, 2016,37(5): 631-636 DOI: 10.3788/fgxb20163705.0631.
/型HMX为同分异构体
物理化学特性有较大差异。为了对/型HMX混合物进行定量研究
利用太赫兹时域光谱技术
对/型HMX单质与一定比例混合物进行了检测与分析。获得单质/型HMX在0.2~2 THz频段标准太赫兹吸收谱
采用线性拟合对/型HMX混合的太赫兹吸收谱进行分析建立预测方程
并预测未知样品。结果表明:/型HMX混合物在0.82 THz处的吸收强度与型HMX的含量有较好的线性关系。/型HMX混合物在0.82 THz处的吸收特性可以用来进行/型HMX的定量检测。
The physicochemical characteristics of alpha and beta HMX which are isomers are quite different. In order to make a quantitative analysis of alpha and beta HMX mixtures
both pure and mixed alpha/beta HMX were detected and analyzed using of terahertz time-domain spectroscopy (THz-TDS) and THz absorption spectra were obtained. The THz absorption spectra of alpha/beta HMX mixtures were analyzed using linear fitting technique
and the forecast equations were set up to predict unknown samples. The results show that the absorption intensity of alpha/beta mixtures at 0.82 THz range has a good linear relationship with the content of alpha HMX. The absorption characteristics of alpha/beta HMX mixtures at 0.82 THz can be used for quantitative detection.
&alpha/&betaHMX太赫兹时域光谱吸收光谱定量检测
&alpha/&betaHMXTHz-TDSabsorption spectrumquantitative detection
欧育湘. 炸药学[M]. 北京:北京理工大学出版社, 2006. OU Y X. Deep Fried Pharmacy[M]. Beijing:Beijing Institute of Technology Press, 2006. (in Chinese)
KONEK C T, MASON B P, HOOPER J P, et al.. Terahertz absorption spectra of 1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocane (HMX) polymorphs[J]. Chem. Phys. Lett., 2010, 489(1-3):48-53.
SAW C K. Kinetics of HMX and phase transitions:effects of grain size at elevated temperature[C]. Proceedings of The 12th International Detonation Symposium, San Diego, USA, 2002.
CZERSKI H, GREENAWAY M W, PROUD W G, et al.. - phase transition during dropweight impact on cyclotetramethylene-tetranitroamine[J]. J. Appl. Phys., 2004, 96(8):4131-4134.
周婷婷,黄风雷. HMX不同晶型热膨胀特性及相变的ReaxFF分子动力学模拟[J]. 物理学报, 2012, 61(24):246501-1-11. ZHOU T T, HUANG F L. Thermal expansion behaviors and phase transitions of HMX polymorphs via ReaxFF molecular dynamics simulations[J]. Acta Phys. Sinica, 2012, 61(24):246501-1-11. (in Chinese)
SAW C K, ZAUG J M, FARBER D L, et al.. Using simultaneous time-resolved SHG and XRD diagnostics to examine phase transitions of HMX and TATB[C]. Proceedings of Shock Compression of Condensed Matter, Atlanta, USA, 2001, 620:856-859.
MATTOS E C, MOREIRA E D, DUTRA R C L, et al.. Determination of the HMX and RDX content in synthesized energetic material by HPLC, FT-MIR, and FT-NIR spectroscopies[J]. Qum. Nova, 2004, 27(4):540-544.
刘学涌,王晓川,黄奕刚,等. 原位红外光谱法研究HMX炸药的热分解过程[J]. 光谱学与光谱分析, 2006, 26(2):251-254. LIU X Y, WANG X C, HUANG Y G, et al.. Study on thermal decomposition of HMX energetic materials by in-situ FTIR spectroscopy[J]. Spectrosc. Spect. Anal., 2006, 26(2):251-254. (in Chinese)
GHOSH M, WANG L L, ASHER S A. Deep-ultraviolet resonance Raman excitation profiles of NH4NO3, PETN, TNT, HMX, and RDX[J]. Appl. Spectrosc., 2012, 66(9):1013-1021.
YE S J, TONOKURA K, KOSHI M. A Raman study of energy transfer processes between phonon and vibron in RDX and -HMX at low temperatures[J]. J. Japan Explos. Soc., 2002, 63(2):49-57.
杜宇,李敬明,宗和厚,等. -HMX的太赫兹波吸收特性及理论计算[J]. 含能材料, 2015, 23(5):454-458. DU Y, LI J M, ZONG H H, et al.. Absorption characteristics and theoretical calculation of terahertz wave for -HMX[J]. Energy Mater., 2015, 23(5):454-458. (in Chinese)
WEN Q, ZHANG W B, ZONG H H, et al.. Vibrational properties, phonon spectrum and related thermal parameters of -octahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine:a theoretical study[J]. J. Mol. Model., 2016, 22(1):9.
ALLIS D G, PROKHOROVA D A, KORTER T M. Solid-state modeling of the terahertz spectrum of the high explosive HMX[J]. J. Phys. Chem. A, 2006, 110(5):1951-1959.
HOOPER J, MITCHELL E, KONEK C, et al.. Terahertz optical properties of the high explosive -HMX[J]. Chem. Phys. Lett., 2009, 467(4-6):309-312.
姚宝岱,王高. 钝感RDX及HMX炸药的太赫兹光谱分析[J]. 光电技术应用, 2010, 25(6):11-13. YAO B D, WANG G. Analysis of terahertz spectrum of explosives RDX and HMX[J]. Electro-Opt. Technol. Appl., 2010, 25(6):11-13. (in Chinese)
李小霞,邓琥,廖和涛,等. 室温下中药附子的太赫兹波谱分析[J]. 激光与红外, 2013, 43(11):1282-1285. LI X X, DENG H, LIAO H T, et al.. Analysis of the terahertz spectrum of Chinese herbal medicine aconite at room temperature[J]. Laser Infrared, 2013, 43(11):1282-1285. (in Chinese)
DORNEY T D, BARANIUK R G, MITTLEMAN D M. Material parameter estimation with terahertz time-domain spectroscopy[J]. J. Opt. Soc. Am. A, 2001, 18(7):1562-1571.
邓琥,尚丽平,张泽林,等. 不同行程下水蒸汽太赫兹传输特性[J]. 红外与激光工程, 2015, 44(3):979-984. DENG H, SHANG L P, ZHANG Z L, et al.. Transmission characteristics of water vapor based on different transmission distance[J]. Infrared Laser Eng., 2015, 44(3):979-984. (in Chinese)
0
浏览量
23
下载量
3
CSCD
关联资源
相关文章
相关作者
相关机构