基于聚芴及阳离子铱配合物的白光发光电化学池

吴家祺; 李福山; 聂晨; 曾群英; 郭太良

doi:10.3788/fgxb20163705.0573

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基于聚芴及阳离子铱配合物的白光发光电化学池

器件制备及器件物理 | 更新时间：2020-08-12

- 基于聚芴及阳离子铱配合物的白光发光电化学池
- White Light-emitting Electrochemical Cells Based on Polyfluorene and Cationic Iridium Complexes
- 发光学报 2016年37卷第5期页码：573-577
- 作者机构：
  
  福州大学物理与信息工程学院光电显示技术研究所,福建福州,350002
- 作者简介：
- 基金信息：
  
  国家自然科学基金(61377027)();福建省自然科学基金(2013J01233)资助项目()
- DOI：10.3788/fgxb20163705.0573
  中图分类号： TN383+.1
- 纸质出版日期：2016-5-5，
  
  收稿日期：2015-11-3，
  
  修回日期：2016-3-7，
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吴家祺, 李福山, 聂晨等. 基于聚芴及阳离子铱配合物的白光发光电化学池[J]. 发光学报, 2016,37(5): 573-577

WU Jia-qi, LI Fu-shan, NIE Chen etc. White Light-emitting Electrochemical Cells Based on Polyfluorene and Cationic Iridium Complexes[J]. Chinese Journal of Luminescence, 2016,37(5): 573-577
吴家祺, 李福山, 聂晨等. 基于聚芴及阳离子铱配合物的白光发光电化学池[J]. 发光学报, 2016,37(5): 573-577 DOI： 10.3788/fgxb20163705.0573.

WU Jia-qi, LI Fu-shan, NIE Chen etc. White Light-emitting Electrochemical Cells Based on Polyfluorene and Cationic Iridium Complexes[J]. Chinese Journal of Luminescence, 2016,37(5): 573-577 DOI： 10.3788/fgxb20163705.0573.

摘要

发光电化学池在柔性显示和大面积发光面板的低成本制造方面具有显著优势

但是白光发光电化学池器件的制备一直是一个难题。本文报道了基于阳离子铱离子配合物的柔性黄光发光电化学池

其在6 V时的电流效率高达11.6 cd/A。并将此铱离子配合物与蓝光聚芴材料以一定比例混合

基于此材料制备了白光发光电化学池

其色坐标为(0.31

0.33)

接近标准白光。

Abstract

Light-emitting electrochemical cells (LECs) have a crucial benefit in low cost fabrication processes in flexible and large area illumination panels

but the white light emission remains to be a problem. The fabrication of flexible yellow LECs based on a cationic iridium complex was reported in this paper

which showed yellow electroluminescence with high current efficiency of 11.6 cd/A at 6 V. White light-emitting electrochemical cells were fabricated by blending material mixing polyfluorene with cationic iridium complexes. The cells show white electroluminescence with CIE coordinates of (0.31

0.33)

which is close to standard white emission.

关键词

发光电化学池白光阳离子铱配合物聚芴

Keywords

light-emitting electrochemical cellswhite lightcationic iridium complexespolyfluorene

references

PEI Q, YU G, ZHANG C, et al.. Polymer light-emitting electrochemical cells[J]. Science, 1995, 269(5227):1086-1088.

YANG Y, PEI Q. Voltage controlled two color light-emitting electrochemical cells[J]. Appl. Phys. Lett., 1996, 68(19):2708-2710.

SLINKER J, BERNARDS D, HOUSTON P L, et al.. Solid-state electroluminescent devices based on transition metal complexes[J]. Chem. Commun., 2003(19):2392-2399.

SLINKER J D, RIVNAY J, MOSKOWITZ J S, et al.. Electroluminescent devices from ionic transition metal complexes[J]. J. Mater. Chem., 2007, 17(29):2976-2988.

HU T, HE L, DUAN L, et al.. Solid-state light-emitting electrochemical cells based on ionic iridium (Ⅲ) complexes[J]. J. Mater. Chem., 2012, 22(10):4206-4215.

MATYBA P, YAMAGUCHI H, CHHOWALLA M, et al.. Flexible and metal-free light-emitting electrochemical cells based on graphene and PEDOT-PSS as the electrode materials[J]. Acs Nano, 2010, 5(1):574-580.

YANG Y, PEI Q. Efficient blue-green and white light-emitting electrochemical cells based on poly[9, 9-bis (3, 6-dioxaheptyl)-fluorene-2, 7-diyl] [J]. J. Appl. Phys., 1997, 81(7):3294-3298.

SLINKER J D, GORODETSKY A A, LOWRY M S, et al.. Efficient yellow electroluminescence from a single layer of a cyclometalated iridium complex[J]. J. Am. Chem. Soc., 2004, 126(9):2763-2767.

LOWRY M S, BERNHARD S. Synthetically tailored excited states:phosphorescent, cyclometalated iridium (Ⅲ) complexes and their applications[J]. Chem.-A Eur. J., 2006, 12(31):7970-7977.

HE L, DUAN L, QIAO J, et al.. Highly efficient blue-green and white light-emitting electrochemical cells based on a cationic Iridium complex with a bulky side group[J]. Chem. Mater., 2010, 22(11):3535-3542.

SU H C, CHEN H F, FANG F C, et al.. Solid-state white light-emitting electrochemical cells using iridium-based cationic transition metal complexes[J]. J. Am. Chem. Soc., 2008, 130(11):3413-3419.

SU H C, CHEN H F, SHEN Y C, et al.. Highly efficient double-doped solid-state white light-emitting electrochemical cells[J]. J. Mater. Chem., 2011, 21(26):9653-9660.

AKATSUKA T, ROLDN-CARMONA C, ORT E, et al.. Dynamically doped white light emitting tandem devices[J]. Adv. Mater., 2014, 26(5):770-774.

SU H C, CHENG C Y. Recent advances in solid-state white light-emitting electrochemical cells[J]. Israel J. Chem., 2014, 54(7):855-866.

TAMAYO A B, GARON S, SAJOTO T, et al.. Cationic bis-cyclometalated iridium (Ⅲ) diimine complexes and their use in efficient blue, green, and red electroluminescent devices[J]. Inorg. Chem., 2005, 44(24):8723-8732.

HE L, QIAO J, DUAN L, et al.. Toward highly efficient solid-state white light-emitting electrochemical cells:blue-green to red emitting cationic iridium complexes with imidazole-type ancillary ligands[J]. Adv. Funct. Mater., 2009, 19(18):2950-2960.

PARKER S T, SLINKER J D, LOWRY M S, et al.. Improved turn-on times of iridium electroluminescent devices by use of ionic liquids[J]. Chem. Mater., 2005, 17(12):3187-3190.

WANG Y M, TENG F, HOU Y B, et al.. Copper (Ⅰ) complex employed in organic light-emitting electrochemical cells:device and spectra shift[J]. Appl. Phys. Lett., 2005, 87(23):233512.

BOLINK H J, CAPPELLI L, CHEYLAN S, et al.. Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium (Ⅲ) complex[J]. J. Mater. Chem., 2007, 17(48):5032-5041.

COSTA R D, ORTI E, BOLINK H J, et al.. Intramolecular -stacking in a phenylpyrazole-based iridium complex and its use in light-emitting electrochemical cells[J]. J. Am. Chem. Soc., 2010, 132(17):5978-5980.

HABRARD F, OUISSE T, STEPHAN O, et al.. Conjugated polymer/molten salt blends:the relationship between morphology and electrical aging[J]. J. Appl. Phys., 2004, 96(12):7219-7224.

KOSILKIN I V, MARTENS M S, MURPHY M P, et al.. Polymerizable ionic liquids for fixed-junction polymer light-emitting electrochemical cells[J]. Chem. Mater., 2010, 22(17):4838-4840.

NORELL BADER A J, ILKEVICH A A, KOSILKIN I V, et al.. Precise color tuning via hybrid light-emitting electrochemical cells[J]. Nano Lett., 2010, 11(2):461-465.

LEE C, KIM J J. Enhanced light out-coupling of OLEDs with low haze by inserting randomly dispersed nanopillar arrays formed by lateral phase separation of polymer blends[J]. Small, 2013, 9(22):3858-3863.

SHAO Y, BAZAN G C, HEEGER A J. Long-lifetime polymer light-emitting electrochemical cells[J]. Adv. Mater., 2007, 19(3):365-370.

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