Ir配合物染料调节有机发光二极管发光特性

周思成; 高景宣; 马舒杨; 赵思萌; 吕京繁; 田苗; 张东东; 赵欣如

doi:10.3788/fgxb20163705.0548

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Ir配合物染料调节有机发光二极管发光特性

器件制备及器件物理 | 更新时间：2020-08-12

- Ir配合物染料调节有机发光二极管发光特性
- Properties Adjustment for Organic Light-emitting Diodes by Doping Ir-complex Dyes
- 发光学报 2016年37卷第5期页码：548-555
- 作者机构：
  
  1. 清华大学附属中学北京,100084
  2. 清华大学化学系有机光电子与分子工程教育部重点实验室北京,100084
- 作者简介：
- 基金信息：
  
  国家自然科学基金面上项目(60877026)资助()
- DOI：10.3788/fgxb20163705.0548
  中图分类号： TN383+.1
- 纸质出版日期：2016-5-5，
  
  收稿日期：2016-1-3，
  
  修回日期：2016-2-25，
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周思成, 高景宣, 马舒杨等. Ir配合物染料调节有机发光二极管发光特性[J]. 发光学报, 2016,37(5): 548-555

ZHOU Si-cheng, GAO Jing-xuan, MA Su-yang etc. Properties Adjustment for Organic Light-emitting Diodes by Doping Ir-complex Dyes[J]. Chinese Journal of Luminescence, 2016,37(5): 548-555
周思成, 高景宣, 马舒杨等. Ir配合物染料调节有机发光二极管发光特性[J]. 发光学报, 2016,37(5): 548-555 DOI： 10.3788/fgxb20163705.0548.

ZHOU Si-cheng, GAO Jing-xuan, MA Su-yang etc. Properties Adjustment for Organic Light-emitting Diodes by Doping Ir-complex Dyes[J]. Chinese Journal of Luminescence, 2016,37(5): 548-555 DOI： 10.3788/fgxb20163705.0548.

摘要

为了研究有机发光二极管(OLED)中发光特性与材料能带结构的关系

把不同的Ir配合物染料掺杂到结构相同的OLED器件中。OLED结构为ITO/NPB/CBP:染料/TPBi/Mg:Ag/Ag

染料分别为Ir(MDQ)

(acac)、Ir(ppy)

和Firpic。实验表明

这3种染料对应的掺杂器件分别发红光、绿光和蓝光。3个器件的阈值电压基本一致((60.1) V)

但是

在100 cd/m

亮度下

绿光器件外量子效率最高(7.64%)

蓝光器件外量子效率(5.65%)与绿光相近

红光器件外量子效率最低(2.75%)。分析认为

由于染料的掺杂浓度低

器件结构和载流子传输特性变化小

因而掺杂对阈值电压影响小;CBP与掺杂染料间存在能量转移

红色染料能级差小

非辐射跃迁几率大

发光效率最低;相比于绿光

蓝色染料能级差大

跃迁几率小

因此发光效率比绿光低。实验还发现

染料的发光波长与其能级差相比有红移现象

分析认为

这是由激发态能量振动弛豫和系间窜越过程形成的。

Abstract

Through doping different organic dyes in organic light-emitting diodes (OLEDs) with the same structures

we hope to investigate the relationship between the energy gaps of the doped dyes and the emission wavelength of the devices

as well as to analyze the energy transfer mechanism in the system. The structure of the OLED is ITO/NPB/CBP:dyes/TPBi/Mg:Ag/Ag

and the doped organic dyes include Ir(MDQ)

(acac)

Ir(ppy)

and Firpic. The three doped devices have almost the same threshold voltages and emit red

green and blue light

respectively. At an luminance of 100 cd/m

the green-light device doped Ir(ppy)

achieves the highest external quantum efficiency of 7.64%. Meanwhile

the red-light device doped Ir(MDQ)

(acac) has the external quantum efficiency of 2.75%

which is the lowest one among the three devices

while the blue-light one doped Firpic achieves an external efficiency of 5.65%. The differences of the emission wavelength and the external quantum efficiency of those devices are assigned to the difference of the energy gaps of the dyes. Further analysis also shows that energy transfer between the CBP and the dyes exists.

关键词

有机染料有机发光二极管掺杂能量转移

Keywords

organic dyesorganic light-emitting diodedopingenergy transfer

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