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Yb3+/Tm3+共掺的硅酸盐玻璃上转换发光性能
Up-conversion Luminescence Properties of Yb3+/Tm3+ Co-doped Silicate Glasses
- 发光学报 2016年37卷第5期 页码：526-531
- 作者机构：
1. 海南省特种玻璃重点实验室海南大学,海南 海口,570228
2. 特种玻璃国家重点实验室海南中航特玻材料有限公司,海南 海口,571924
3. 海南中航特玻科技有限公司,海南 海口,571924
- 作者简介：
- 基金信息：海南省重大科技专项--特种玻璃产业关键技术的引用和集成应用资助项目()
DOI：10.3788/fgxb20163705.0526
中图分类号： TQ171;O482.31纸质出版日期：2016-5-5，
收稿日期：2016-1-9，
修回日期：2016-3-7，
扫 描 看 全 文
苏俊, 张振华, 赵会峰等. Yb<sup>3+</sup>/Tm<sup>3+</sup>共掺的硅酸盐玻璃上转换发光性能[J]. 发光学报, 2016,37(5): 526-531
SU Jun, ZHANG Zhen-hua, ZHAO Hui-feng etc. Up-conversion Luminescence Properties of Yb<sup>3+</sup>/Tm<sup>3+</sup> Co-doped Silicate Glasses[J]. Chinese Journal of Luminescence, 2016,37(5): 526-531
苏俊, 张振华, 赵会峰等. Yb<sup>3+</sup>/Tm<sup>3+</sup>共掺的硅酸盐玻璃上转换发光性能[J]. 发光学报, 2016,37(5): 526-531 DOI： 10.3788/fgxb20163705.0526.
SU Jun, ZHANG Zhen-hua, ZHAO Hui-feng etc. Up-conversion Luminescence Properties of Yb<sup>3+</sup>/Tm<sup>3+</sup> Co-doped Silicate Glasses[J]. Chinese Journal of Luminescence, 2016,37(5): 526-531 DOI： 10.3788/fgxb20163705.0526.
摘要
采用高温熔融法制备了掺杂不同比例Yb
3+
和Tm
3+
的硅酸盐玻璃。吸收光谱表明
Yb
3+
和Tm
3+
在300~1100 nm的吸收过程彼此不干扰。研究了玻璃样品在980 nm LD泵浦下的上转换发光行为
结果表明:Yb
3+
/Tm
3+
在477 nm(
1
G
4
3
H
6
)发射强烈的上转换蓝光
在654 nm(
1
G
4
3
F
4
)发射较弱的红光
在795 nm(
3
H
4
3
H
6
)发射微弱的红外光。提高Yb
3+
的比例均能够提高477 nm蓝光、654 nm红光和795 nm红外光的发射强度。研究分析了上转换发光强度与激光器泵浦功率之间的关系
结果表明上转换蓝光和红光发射均为三个光子过程
红外光发射为两个光子过程。分析了Yb
3+
、Tm
3+
在硅酸盐玻璃中上转换发光的机制。
Abstract
Silicate glasses with different ratio of Yb
3+
and Tm
3+
were prepared by high temperature melting method. Absorption spectra show that the absorption process of Tm
3+
and Yb
3+
in 300-1100 nm are not disturbed by each other. Up-conversion luminescence of the glass sample under 980 nm LD was studied. The results show that Yb
3+
Tm
3+
launches strong up-conversion blue light at 477 nm (
1
G
4
3
H
6
)
but the emission of red light 654 nm(
1
G
4
3
F
4
) and 795 nm (
3
H
4
3
H
6
) infrared light are all weak. Improving the ratio of Yb
3+
can improve the emission intensity of 477 nm blue
654 nm red and 795 nm infrared. The relationship between the intensity of up-conversion luminescence and the pump power of the laser was studied. The conversion of blue and red emission are three photon processes
and the infrared emission is two photon processes. Finally
the mechanization of Yb
3+
and Tm
3+
in the transformation of the silicate glass was analyzed.
关键词
硅酸盐玻璃Yb3+、Tm3+上转换发光机制
Keywords
references
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