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1. 海南省特种玻璃重点实验室海南大学,海南 海口,570228
2. 特种玻璃国家重点实验室海南中航特玻材料有限公司,海南 海口,571924
3. 海南中航特玻科技有限公司,海南 海口,571924
纸质出版日期:2016-5-5,
收稿日期:2016-1-9,
修回日期:2016-3-7,
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苏俊, 张振华, 赵会峰等. Yb<sup>3+</sup>/Tm<sup>3+</sup>共掺的硅酸盐玻璃上转换发光性能[J]. 发光学报, 2016,37(5): 526-531
SU Jun, ZHANG Zhen-hua, ZHAO Hui-feng etc. Up-conversion Luminescence Properties of Yb<sup>3+</sup>/Tm<sup>3+</sup> Co-doped Silicate Glasses[J]. Chinese Journal of Luminescence, 2016,37(5): 526-531
苏俊, 张振华, 赵会峰等. Yb<sup>3+</sup>/Tm<sup>3+</sup>共掺的硅酸盐玻璃上转换发光性能[J]. 发光学报, 2016,37(5): 526-531 DOI: 10.3788/fgxb20163705.0526.
SU Jun, ZHANG Zhen-hua, ZHAO Hui-feng etc. Up-conversion Luminescence Properties of Yb<sup>3+</sup>/Tm<sup>3+</sup> Co-doped Silicate Glasses[J]. Chinese Journal of Luminescence, 2016,37(5): 526-531 DOI: 10.3788/fgxb20163705.0526.
采用高温熔融法制备了掺杂不同比例Yb
3+
和Tm
3+
的硅酸盐玻璃。吸收光谱表明
Yb
3+
和Tm
3+
在300~1100 nm的吸收过程彼此不干扰。研究了玻璃样品在980 nm LD泵浦下的上转换发光行为
结果表明:Yb
3+
/Tm
3+
在477 nm(
1
G
4
3
H
6
)发射强烈的上转换蓝光
在654 nm(
1
G
4
3
F
4
)发射较弱的红光
在795 nm(
3
H
4
3
H
6
)发射微弱的红外光。提高Yb
3+
的比例均能够提高477 nm蓝光、654 nm红光和795 nm红外光的发射强度。研究分析了上转换发光强度与激光器泵浦功率之间的关系
结果表明上转换蓝光和红光发射均为三个光子过程
红外光发射为两个光子过程。分析了Yb
3+
、Tm
3+
在硅酸盐玻璃中上转换发光的机制。
Silicate glasses with different ratio of Yb
3+
and Tm
3+
were prepared by high temperature melting method. Absorption spectra show that the absorption process of Tm
3+
and Yb
3+
in 300-1100 nm are not disturbed by each other. Up-conversion luminescence of the glass sample under 980 nm LD was studied. The results show that Yb
3+
Tm
3+
launches strong up-conversion blue light at 477 nm (
1
G
4
3
H
6
)
but the emission of red light 654 nm(
1
G
4
3
F
4
) and 795 nm (
3
H
4
3
H
6
) infrared light are all weak. Improving the ratio of Yb
3+
can improve the emission intensity of 477 nm blue
654 nm red and 795 nm infrared. The relationship between the intensity of up-conversion luminescence and the pump power of the laser was studied. The conversion of blue and red emission are three photon processes
and the infrared emission is two photon processes. Finally
the mechanization of Yb
3+
and Tm
3+
in the transformation of the silicate glass was analyzed.
硅酸盐玻璃Yb3+、Tm3+上转换发光机制
聂秋华,金哲,徐铁峰,等. 蓝绿光上转换荧光输出的稀土掺杂玻璃研究进展[J]. 硅酸盐通报, 2006, 25(5):108-117. NIE Q H, JIN Z, XU T F, et al.. Research progress of rare earth doped glasses with the blue and green upconversion fluorescence[J]. Bull. Chin. Ceram. Soc., 2006, 25(5):108-117. (in Chinese)
RYBA-ROMANOWSKI W, GO?VAB S, SOKLSKA I, et al.. Spectroscopic characterization of a Tm3+:SrGdGa3O7 crystal[J]. Appl. Phys. B, 1999, 68(2):199-205.
KIMANI M M, CHEN H Y, MCMILLEN C D, et al.. Synthetic and spectroscopic studies of vanadate glaserites I:upconversion studies of doubly co-doped (Er, Tm, or Ho):Yb:K3Y(VO4)2[J]. J. Solid State Chem., 2015, 226:312-319.
傅恒毅,钱江云,潘毓,等. 稀土掺杂上转换发光玻璃陶瓷的制备及性能[J]. 材料科学与工程学报, 2012, 30(1):29-36. FU H Y, QIAN J Y, PAN Y, et al.. Preparation and properties of rare earth doped glass ceramics with upconversion luminescence behaviors[J]. J. Mater. Sci. Eng., 2012, 30(1):29-36. (in Chinese)
LI D G, QIN W P, LIU S H, et al.. Synthesis and luminescence properties of RE3+ (RE=Yb, Er, Tm, Eu, Tb)-doped Sc2O3 microcrystals[J]. J. Alloys Compd., 2015, 653:304-309.
王永明,李彩云,范英芳. LiNbO3晶体中Yb3+的配位场能级分析[J]. 无机化学学报, 2002, 18(9):953-956. WANG Y M, LI C Y, FAN Y F. Analysis of coordination-field energy levels of Yb3+ in LiNbO3 crystal[J]. Chin. J. Inorg. Chem., 2002, 18(9):953-956. (in Chinese)
段佩华,张继森,张立国,等. YAG粉末材料中Cr3+敏化的Yb3+近红外发光性质[J]. 中国光学, 2015, 8(4):603-607. DUAN P H, ZHANG J S, ZHANG L G, et al.. Near-infrared emission properties of Yb3+ ions sensitized by Cr3+ ions in YAG powder materials[J]. Chin. Opt., 2015, 8(4):603-607. (in Chinese)
朱晓,尚建力. 端泵Yb:YAG碟片激光器泵浦系统中关键光学元件性能对激光器效率影响[C]. 科技引领产业、支撑跨越发展第六届湖北科技论坛论文集萃, 武汉, 2011. ZHU X, SHANG J L. End pump Yb:effect of component performance of key optical pumping system of YAG thin disk laser on laser efficiency[C]. Industry Leading Technology Support, Leaping Development-The Sixth Hubei Forum of Science and Technology Papers, Wuhan, China, 2011. (in Chinese)
SONG S A, KIM D S, JEONG H M, et al.. Upconversion in Nd-Tm-Yb triply doped oxyfluoride glass-ceramics containing CaF2 nanocrystals[J]. J. Lumin., 2014, 152:75-78.
韩娇,满石清. 铥镱共掺镓酸盐玻璃上转换发光性能[J]. 陕西科技大学学报, 2011, 29(3):30-32. HAN J, MAN S Q. Upconversion luminescence of Tm3+/Yb3+ co-doped gallate glasses[J]. J. Shaanxi Univ. Sci. Technol., 2011, 29(3):30-32. (in Chinese)
吕景文,肖洪亮,李红玲,等. Yb3+/Tm3+共掺玻璃陶瓷上转换发光[J]. 功能材料, 2006, 37(S):31-32. LV J W, XIAO H L, LI H L, et al.. Up-conversion luminescence of Yb3+/Tm3+-codoped glass ceramics[J]. J. Funct. Mater., 2006, 37(S):31-32. (in Chinese)
苏方宁,邓再德. 声子态密度对掺稀土玻璃材料上转换发光强度的影响[J]. 玻璃与搪瓷, 2007, 35(2):1-5. SU F N, DENG Z D. Influence of phonon density on the intensity of upconversion luminescence of rare earths doped glass[J]. Glass Enamel, 2007, 35(2):1-5. (in Chinese)
冯衍,陈晓波,郝昭,等. Tm3+, Yb3+共掺ZBLAN玻璃中的能量传递与上转换[J]. 物理学报, 1997, 46(12):2454-2460. FENG Y, CHEN X B, HAO Z, et al.. Energy transfer and upconversion in Tm3+ and Yb3+ codoped ZBLAN glass[J]. Acta Phys. Sinica, 1997, 46(12):2454-2460. (in Chinese)
段忠超,张军杰,廖梅松,等. Tm3+-Yb3+共掺氧氟硅酸盐玻璃热学性能和上转换发光特性研究[J]. 武汉理工大学学报, 2007, 29(SI):29-33. DUAN Z C, ZHANG J J, LIAO M S, et al.. Research on thermal stability and upconversion properties in Tm3+-Yb3+ codoped oxyfluoride silicate glasses[J]. J. Wuhan Univ. Technol., 2007, 29(SI):29-33. (in Chinese)
LOIKO P A, SERRES J M, MATEOS X, et al.. Spectroscopic and laser characterization of Yb, Tm:KLu(WO4)2 crystal[J]. Opt. Mater., 2016, 51:223-231.
LI L, WANG X C, WEI X T, et al.. Influence of precipitant solution pH on the structural, morphological and upconversion luminescent properties of Lu2O3:2%Yb, 0.2%Tm nanopowders[J]. Phys. B, 2011, 406(3):609-613.
FUKUSHIMA S, FURUKAWA T, NIIOKA H, et al.. Y2O3:Tm,Yb nanophosphors for correlative upconversion luminescence and cathodoluminescence imaging[J]. Micron, 2014, 67:90-95.
LUPEI V, LUPEI A, GHEORGHE C, et al.. Spectroscopic characteristics of Tm3+ in Tm and Tm, Nd, Yb:Sc2O3 ceramic[J]. J. Lumin., 2008, 128(5-6):901-904.
YANG H K, OH J H, MOON B K, et al.. Photoluminescent properties of near-infrared excited blue emission in Yb, Tm co-doped LaGaO3 phosphors[J]. Ceram. Int., 2014, 40(8):13357-13361.
XING L L, XU Y L, WANG R, et al.. Controllable and white upconversion luminescence in LiNbO3:Ln3+ (Ln=Ho, Yb, Tm) single crystals[J]. Chem. Phys. Lett., 2013, 577:53-57.
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