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北京信息科技大学仪器科学与光电工程学院 北京,100192
纸质出版日期:2016-5-5,
收稿日期:2015-12-26,
修回日期:2016-3-10,
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牛春晖, 任宣玮, 李晓英等. YNbO<sub>4</sub>粉末材料中Er<sup>3+</sup>发光研究及其光谱性质J-O计算[J]. 发光学报, 2016,37(5): 519-525
NIU Chun-hui, REN Xuan-wei, LI Xiao-ying etc. Luminescence Characteristics of Er<sup>3+</sup> in YNbO<sub>4</sub> Powder Materials and J-O Calculation of Its Spectrum[J]. Chinese Journal of Luminescence, 2016,37(5): 519-525
牛春晖, 任宣玮, 李晓英等. YNbO<sub>4</sub>粉末材料中Er<sup>3+</sup>发光研究及其光谱性质J-O计算[J]. 发光学报, 2016,37(5): 519-525 DOI: 10.3788/fgxb20163705.0519.
NIU Chun-hui, REN Xuan-wei, LI Xiao-ying etc. Luminescence Characteristics of Er<sup>3+</sup> in YNbO<sub>4</sub> Powder Materials and J-O Calculation of Its Spectrum[J]. Chinese Journal of Luminescence, 2016,37(5): 519-525 DOI: 10.3788/fgxb20163705.0519.
为了研究Er
3+
/Yb
3+
共掺杂YNbO
4
粉末材料上转换发光特性
采用J-O理论计算了该材料的光谱性质。根据吸收谱各吸收峰面积拟合出谱线强度参数
并根据谱线强度参数计算出理论振子强度和实验振子强度
得到两者均方差为
rms
=3.91610
-7
。计算了YNbO
4
粉末材料中Er
3+
粒子的跃迁几率、跃迁分支比及能级寿命等参数
并计算得到了Er
3+
离子从能级
2
H
11/2
、
4
S
3/2
和
4
F
9/2
到基态辐射跃迁的受激发射截面。研究结果表明YNbO
4
材料是一种优良的上转换基质材料。
In order to study up-conversion luminescence characteristics of Er
3+
/Yb
3+
co-doped YNbO
4
powder materials
the spectrum property was calculated by using J-O theory in this paper. The spectrum intensity parameters were obtained by the fitting method based on the absorption peak's area of the absorption spectrum
and the theoretical oscillator intensity and the experimental oscillator intensity were figured out according to the spectrum intensity parameters
and the mean square deviation of them(
rms
) was 3.91610
-7
. The parameters such as the transition probability
transition branching ratio and energy level life
etc
. of Er
3+
particles in YNbO
4
powder materials were calculated
and the stimulated emission cross section of Er
3+
radiative transition from the energy level
2
H
11/2
4
S
3/2
and
4
F
9/2
to the ground state was also figured out. The experimental results show that YNbO
4
is one kind of superior up-conversion matrix materials.
YNbO4J-O理论上转换发光
YNbO4J-O theoryup-conversion luminescence
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