Eu/Tm/Tb掺杂硼硅酸盐玻璃的发光性能

石冬梅; 赵营刚

doi:10.3788/fgxb20163704.0392

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Eu/Tm/Tb掺杂硼硅酸盐玻璃的发光性能

材料合成及性能 | 更新时间：2020-08-12

- Eu/Tm/Tb掺杂硼硅酸盐玻璃的发光性能
- Luminescence Properties of Eu/Tm/Tb-doped Borosilicate Glass
- 发光学报 2016年37卷第4期页码：392-398
- 作者机构：
  
  洛阳理工学院材料科学与工程学院,河南洛阳,471023
- 作者简介：
- 基金信息：
  
  国家自然科学基金(51002070)();洛阳市科技发展计划(1401051A)资助项目()
- DOI：10.3788/fgxb20163704.0392
  中图分类号： TQ171;O482.31
- 纸质出版日期：2016-4-5，
  
  收稿日期：2015-12-18，
  
  修回日期：2016-1-18，
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石冬梅, 赵营刚,. Eu/Tm/Tb掺杂硼硅酸盐玻璃的发光性能[J]. 发光学报, 2016,37(4): 392-398

SHI Dong-mei, ZHAO Ying-gang,. Luminescence Properties of Eu/Tm/Tb-doped Borosilicate Glass[J]. Chinese Journal of Luminescence, 2016,37(4): 392-398
石冬梅, 赵营刚,. Eu/Tm/Tb掺杂硼硅酸盐玻璃的发光性能[J]. 发光学报, 2016,37(4): 392-398 DOI： 10.3788/fgxb20163704.0392.

SHI Dong-mei, ZHAO Ying-gang,. Luminescence Properties of Eu/Tm/Tb-doped Borosilicate Glass[J]. Chinese Journal of Luminescence, 2016,37(4): 392-398 DOI： 10.3788/fgxb20163704.0392.

摘要

采用熔融淬冷法制备了性能优越的Eu/Tm/Tb单掺、双掺和三掺的硼硅酸盐玻璃。测试了样品的激发和发射光谱

计算了CIE色坐标

研究了紫外激发下Eu/Tm/Tb掺杂的硼硅酸盐玻璃的发光性能。结果表明:在361 nm激发下

随着Tm

加入到Eu

掺杂的硼硅酸盐样品中

观察到Tm

的459 nm(

)锐线特征发射峰

同时由于Eu

的能量传递的存在降低了Eu

的437 nm宽带峰及Eu

的589 nm(

)和612 nm(

)的特征发射峰强度。在377 nm激发下

Eu/Tm/Tb三掺样品能够同时出现红、绿和蓝光。调节Eu

的含量能有效改变发光玻璃的发光强度和颜色

最终得到色坐标为(0.33

0.386 7)的发光玻璃。

Abstract

Eu/Tm/Tb-doped singly

doubly and triply borosilicate glasses were prepared using a conventional melting-quenching method. The luminescent properties of Eu/Tm/Tb-doped samples under the UV excitation were investigated in detail by measuring the excitation and emission spectra and calculating CIE chromaticity coordinates. The results show that the sharp emission peak centered at 459 nm originating from

of Tm

is observed

and the characteristic emission intensity centered at 437 nm ascribing to the broad peak of Eu

589 nm(

)and 612 nm(

)of Eu

is reduced due to the energy transfer from Eu

to Tm

ion. Red

green and blue light can be observed in Eu/Tm/Tb -doped triply samples simultaneously under the excitation of 377 nm. The luminescent intensity and color of borosilicate glasses might be changed by adjusting Eu

content

and the sample with CIE chromaticity coordinates(0.33

0.386 7)are obtained.

关键词

硼硅酸盐玻璃Eu/Tb/Tm光谱性能能量传递

Keywords

borosilicate glassesEu/Tb/Tmspectroscopic propertyenergy transfer

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