浏览全部资源
扫码关注微信
洛阳理工学院 材料科学与工程学院,河南 洛阳,471023
纸质出版日期:2016-4-5,
收稿日期:2015-12-18,
修回日期:2016-1-18,
扫 描 看 全 文
石冬梅, 赵营刚,. Eu/Tm/Tb掺杂硼硅酸盐玻璃的发光性能[J]. 发光学报, 2016,37(4): 392-398
SHI Dong-mei, ZHAO Ying-gang,. Luminescence Properties of Eu/Tm/Tb-doped Borosilicate Glass[J]. Chinese Journal of Luminescence, 2016,37(4): 392-398
石冬梅, 赵营刚,. Eu/Tm/Tb掺杂硼硅酸盐玻璃的发光性能[J]. 发光学报, 2016,37(4): 392-398 DOI: 10.3788/fgxb20163704.0392.
SHI Dong-mei, ZHAO Ying-gang,. Luminescence Properties of Eu/Tm/Tb-doped Borosilicate Glass[J]. Chinese Journal of Luminescence, 2016,37(4): 392-398 DOI: 10.3788/fgxb20163704.0392.
采用熔融淬冷法制备了性能优越的Eu/Tm/Tb单掺、双掺和三掺的硼硅酸盐玻璃。测试了样品的激发和发射光谱
计算了CIE色坐标
研究了紫外激发下Eu/Tm/Tb掺杂的硼硅酸盐玻璃的发光性能。结果表明:在361 nm激发下
随着Tm
3+
加入到Eu
2
O
3
掺杂的硼硅酸盐样品中
观察到Tm
3+
的459 nm(
1
D
2
3
F
4
)锐线特征发射峰
同时由于Eu
3+
Eu
2+
Tm
3+
的能量传递的存在降低了Eu
2+
的437 nm宽带峰及Eu
3+
的589 nm(
5
D
0
7
F
1
)和612 nm(
5
D
0
7
F
2
)的特征发射峰强度。在377 nm激发下
Eu/Tm/Tb三掺样品能够同时出现红、绿和蓝光。调节Eu
2
O
3
的含量能有效改变发光玻璃的发光强度和颜色
最终得到色坐标为(0.33
0.386 7)的发光玻璃。
Eu/Tm/Tb-doped singly
doubly and triply borosilicate glasses were prepared using a conventional melting-quenching method. The luminescent properties of Eu/Tm/Tb-doped samples under the UV excitation were investigated in detail by measuring the excitation and emission spectra and calculating CIE chromaticity coordinates. The results show that the sharp emission peak centered at 459 nm originating from
1
D
2
3
F
4
of Tm
3+
is observed
and the characteristic emission intensity centered at 437 nm ascribing to the broad peak of Eu
2+
589 nm(
5
D
0
7
F
1
)and 612 nm(
5
D
0
7
F
2
)of Eu
3+
is reduced due to the energy transfer from Eu
3+
Eu
2+
to Tm
3+
ion. Red
green and blue light can be observed in Eu/Tm/Tb -doped triply samples simultaneously under the excitation of 377 nm. The luminescent intensity and color of borosilicate glasses might be changed by adjusting Eu
2
O
3
content
and the sample with CIE chromaticity coordinates(0.33
0.386 7)are obtained.
硼硅酸盐玻璃Eu/Tb/Tm光谱性能能量传递
borosilicate glassesEu/Tb/Tmspectroscopic propertyenergy transfer
ZHU C F, WANG X, ZHANG M M, et al.. Eu-, Tb-, and Dy-doped oxyfluoride silicate glasses for LED applications [J]. J. Am. Ceram. Soc., 2014, 97(3):854-861.
GUO Q F, LIAO L B, XIA Z G. Luminescence properties and energy transfer in La6Ba4(SiO4)6F2:Ce3+,Tb3+ phosphors [J]. J. Lumin., 2014, 145:65-70.
CHEN D Q, XIANG W D, LIANG X J, et al.. Advances in transparent glass-ceramic phosphors for white light-emitting diodesA review [J]. J. Eur. Ceram. Soc., 2015, 35(3):859-869.
CHEN Q Q, DAI N L, LIU Z J, et al.. White light luminous properties and energy transfer mechanism of rare earth ions in Ce3+/Tb3+/Sm3+ co-doped glasses [J]. Appl. Phys. A, 2014, 115(4):1159-1166.
周青超,柏泽龙,鲁路,等. 白光LED远程荧光粉技术研究进展与展望 [J]. 中国光学, 2015, 8(3):313-328. ZHOU Q C, BAI Z L, LU L, et al.. Remote phosphor technology for white LED applications: advances and prospects [J]. Chin. Opt., 2015, 8(3): 313-328. (in Chinese)
DENG S Z, QIU Z X, ZHANG M M, et al.. Tricolor emitting and energy transfer in the phosphor Ba2ZnSi2O7:Ce3+,Eu3+, Eu2+ for white-LED based near-UV chips [J]. J. Rare Earth., 2015, 33(5):463-468.
张岚,王喜贵. Eu3+:ZnO1-xSx-SiO2发光材料的制备与发光性质 [J]. 稀土, 2014, 35(2):24-29. ZHANG L, WANG X G. Preparation and luminescent properties of Eu3+: ZnO1-xSx-SiO2 [J]. Chin. Rare Earth., 2014, 35(2):24-29. (in Chinese)
高当丽,郑海荣,田宇,等. Tm3+和Ln3+(Ln3+=Yb3+, Er3+, Pr3+, Ho3+, Eu3+)共掺氟化物纳米晶体的光谱学性质 [J]. 中国科学: 物理学 力学 天文学, 2010, 40(3):287-295. GAO D L, ZHENG H R, TIAN Y, et al.. Spectroscopic properties of Tm3+ and Ln3+(Ln3+=Yb3+, Er3+, Pr3+, Ho3+, Eu3+) co-doped fluoride nanocrystals [J]. Scientia Sinica Phys., Mech. & Astron., 2010, 40(3):287-295. (in Chinese)
刘艳,姜营营,刘桂霞,等. NaY(WO4)2:Eu3+/Tb3+/Tm3+白色荧光粉的制备与发光性能 [J]. 无机化学学报, 2013, 29(2):277-282. LIU Y, JIANG Y Y, LIU G X, et al.. Preparation and luminescence properties of NaY(WO4)2:Eu3+/Tb3+/Tm3+ white light phosphors [J]. Chin. J. Inorg. Chem., 2013, 29(2):277-282.(in Chinese)
CHEN D Q, CHEN Y. Transparent Ce3+:Y3Al5O12 glass ceramic for organic-resin-free white-light-emitting diodes [J]. Ceram. Int., 2014, 40(9):15325-15329.
黄建兵,张金朝,宋鹂. 稀土离子掺杂硼铝酸盐玻璃的发光性能 [J]. 华东理工大学学报(自然科学版), 2009, 35(4):582-586. HUANG J B, ZHANG J C, SONG L. Luminescence properties of rare earth ion-doped aluminoborate glass [J]. J. East China Univ. Sci. Technol. (Nat. Sci. Ed.), 2009, 35(4):582-586. (in Chinese)
顾路顺,施楠,张乐,等. Tb/Eu共掺锌硼磷酸盐白光发光玻璃的制备及其发光性能 [J]. 发光学报, 2014, 35(8):897-904. GU L S, SHI N, ZHANG L, et al.. Synthesis and luminescent properties of Tb/Eu co-doped zinc borophosphate glasses for white light generation [J]. Chin. J. Lumin., 2014, 35(8):897-904. (in Chinese)
LIANG X L, YANG Y X, ZHU C F, et al.. Luminescence properties of Tb3+-Sm3+ codoped glasses for white light emitting diodes [J]. Appl. Phys. Lett., 2007, 91(9):091104-1-3.
JIAO H, ZHANG N, JING X P, et al.. Influence of rare earth elements (Sc, La, Gd and Lu) on the luminescent properties of green phosphor Y2SiO5:Ce,Tb [J]. Opt. Mater., 2007, 29(8):1023-1028.
LIN H, PUN E Y B, WANG X J, et al.. Intense visible fluorescence and energy transfer in Dy3+, Tb3+, Sm3+ and Eu3+ doped rare-earth borate glasses [J]. J. Alloys Compd., 2005, 390(1-2):197-201.
ZHANG X G, ZHOU L Y, PANG Q, et al.. Tunable luminescence and Ce3+Tb3+Eu3+ energy transfer of broadband-excited and narrow line red emitting Y2SiO5:Ce3+,Tb3+,Eu3+ phosphor [J]. J. Phys. Chem. C, 2014, 118(14):7591-7598.
RODRGUEZ-ROJAS R A, DE LA ROSA-CRUZ E, DAZ-TORRES L A, et al.. Preparation, photo- and thermo-luminescence characterization of Tb3+ and Ce3+ doped nanocrystalline Y3Al5O12 exposed to UV-irradiation [J]. Opt. Mater., 2004, 25(3):285-293.
RODRGUEZ-GARCA C E, PEREA-LPEZ N, HIRATA G A, et al.. Red-emitting SrIn2O4:Eu3+ phosphor powders for applications in solid state white lamps [J]. J. Phys. D: Appl. Phys., 2008, 41(9):092005.
杨建龙,李友芬,吴纪颖. Eu2+, Tb3+共掺杂3/2-莫来石发光特性及Eu2+Tb3+的能量传递 [J]. 科学通报, 2009, 54(5):569-573. YANG J L, LI Y F, WU J Y. The luminescence characteristics of 3/2-mullite co-doped by Eu and Tb and energy transfer between them [J]. Chin. Sci. Bull., 2009, 54(5):569-573. (in Chinese)
SASIKALA T, RAMA MOORTHY L. Photoluminescence properties of singly doped Tm3+ and co-doped Tm3+/Tb3+ ions in tellurite glasses [J]. J. Mol. Struct., 2014, 1076:529-534.
KAO F S, CHEN T M. A study on the luminescent properties of new green-emitting terbium-activated CaIn2O4:xTb phosphors [J]. J. Lumin., 2002, 96(2-4):261-267.
BOUKERIKA, GUERBOUS L. Annealing effects on structural and luminescence properties of red Eu3+-doped Y2O3 nanophosphors prepared by sol-gel method [J]. J. Lumin., 2014, 145:148-153.
RAJU G S R, BUDDHUDU S. Emission analysis of Eu3+:MgLaLiSi2O7 powder phosphor [J]. Phys. B, 2008, 403(4):619-623.
0
浏览量
40
下载量
1
CSCD
关联资源
相关文章
相关作者
相关机构