Ce3+掺杂LiLuF4氟氧微晶玻璃的发光性质

李杨; 黄立辉

doi:10.3788/fgxb20163704.0387

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Ce³⁺掺杂LiLuF₄氟氧微晶玻璃的发光性质

材料合成及性能 | 更新时间：2020-08-12

- Ce³⁺掺杂LiLuF₄氟氧微晶玻璃的发光性质
- Luminescence Properties of Ce³⁺ Doped Oxyfluoride Glass Ceramics Containing LiLuF₄ Nanocrystals
- 发光学报 2016年37卷第4期页码：387-391
- 作者机构：
  
  中国计量学院材料科学与工程学院,浙江杭州,310018
- 作者简介：
- 基金信息：
  
  国家自然科学基金面上项目(11375166)();人社部留学人员科研活动择优资助项目()
- DOI：10.3788/fgxb20163704.0387
  中图分类号： O482.31
- 纸质出版日期：2016-4-5，
  
  收稿日期：2015-12-18，
  
  修回日期：2016-1-18，
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李杨, 黄立辉,. Ce3+掺杂LiLuF4氟氧微晶玻璃的发光性质[J]. 发光学报, 2016,37(4): 387-391

LI Yang, HUANG Li-hui,. Luminescence Properties of Ce3+ Doped Oxyfluoride Glass Ceramics Containing LiLuF4 Nanocrystals[J]. Chinese Journal of Luminescence, 2016,37(4): 387-391
李杨, 黄立辉,. Ce3+掺杂LiLuF4氟氧微晶玻璃的发光性质[J]. 发光学报, 2016,37(4): 387-391 DOI： 10.3788/fgxb20163704.0387.

LI Yang, HUANG Li-hui,. Luminescence Properties of Ce3+ Doped Oxyfluoride Glass Ceramics Containing LiLuF4 Nanocrystals[J]. Chinese Journal of Luminescence, 2016,37(4): 387-391 DOI： 10.3788/fgxb20163704.0387.

摘要

通过熔融法以及热处理

制备了Ce

掺杂含LiLuF

纳米晶的透明氟氧微晶玻璃。XRD结果表明

玻璃中析出的晶相为LiLuF

其晶粒大小随热处理温度的升高和时间的延长而变大。在330 nm紫外光激发下

掺杂的氟氧玻璃和LiLuF

微晶玻璃的发射为一峰值波长为370 nm的宽带光谱。微晶玻璃的发光强度显著高于未经过热处理的基础玻璃

并且随着热处理温度的升高及时间的延长

微晶玻璃的发光逐渐增强。微晶玻璃的370 nm发射的荧光寿命均长于基础玻璃的。

Abstract

Transparent Ce

doped glass ceramics containing LiLuF

nanocrystals were prepared by melt-quenching method with subsequent heat treatment. XRD results show that the precipitated crystalline phase in the glass matrix is LiLuF

. Under 330 nm light excitation

doped oxyfluoride glass ceramics containing LiLuF

nanocrystals show more intense emission than the as-made glass

and the emission intensity increases with the increasing of heat treatment temperature and time. The lifetimes of 370 nm emission of Ce

doped oxyfluoride glass ceramics are longer than that of as-made glass.

关键词

Ce3+微晶玻璃LiLuF4纳米晶发光性质

Keywords

Ce3+glass ceramicLiLuF4 nanocrystalsluminescence properties

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