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1. 北京交通大学 理学院 北京,100044
2. 中国科学院大学 材料科学与光电技术学院 北京,101408
纸质出版日期:2016-2-10,
收稿日期:2015-10-19,
修回日期:2015-11-3,
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李晨, 李剑峰, 段武彪等. 一种新型尾式卟啉的合成及其光电性质研究[J]. 发光学报, 2016,37(2): 158-164
LI Chen, LI Jian-feng, DUAN Wu-biao etc. Synthesis, Spectral and Electrochemical Properties of A New Tailed Porphyrin[J]. Chinese Journal of Luminescence, 2016,37(2): 158-164
李晨, 李剑峰, 段武彪等. 一种新型尾式卟啉的合成及其光电性质研究[J]. 发光学报, 2016,37(2): 158-164 DOI: 10.3788/fgxb20163702.0158.
LI Chen, LI Jian-feng, DUAN Wu-biao etc. Synthesis, Spectral and Electrochemical Properties of A New Tailed Porphyrin[J]. Chinese Journal of Luminescence, 2016,37(2): 158-164 DOI: 10.3788/fgxb20163702.0158.
合成了新型尾式5-(2-(-咪唑基间甲基苯甲酰胺基)苯基)-10
15
20-三苯基卟啉(H
2
TPP-BzIm)及其Fe、Co、Zn配合物
并用核磁、质谱、红外光谱、紫外-可见光谱等对其化合物进行了表征
通过紫外吸收、荧光分析、循环伏安法研究了化合物的光电性质。结果表明
与四苯基卟啉(H
2
TPP)相比
该尾式卟啉及其配合物的紫外和荧光光谱均出现较明显红移。Fe和Co卟啉的循环伏安曲线表明不仅发生了卟啉环上的氧化还原反应
还发生了金属离子的氧化还原反应。
A new tailed-porphyrin H
2
TPP-BzIm and different transition metalloporphyrins (Fe
Co
Zn) were synthesized and characterized by
1
H NMR
MS
IR
UV-Vis. The spectral and electrochemical properties were studied by UV-Vis spectrum
fluorescence spectrum and cyclic voltammetry method. Compared with tetraphenyporphyrin(H
2
TPP)
the absorption and emission peaks of the tailed porphyrin have obvious red-shifts. The CV curves of Fe
Co metalloporphyrins indicate that Fe and Co undergo the changing of oxidation state in addition to the redox on the porphyrin ring.
尾式卟啉荧光循环伏安
tailed porphyrinfluorescencecyclic voltammetry
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