Er3+/Yb3+共掺杂氧氟硼硅酸盐微晶玻璃绿色上转换发光的温度特性

林杨杨; 陈铠炀; 唐霞艳; 赵士龙; 徐时清

doi:10.3788/fgxb20153609.1001

您当前的位置：

首页 >

文章列表页 >

Er³⁺/Yb³⁺共掺杂氧氟硼硅酸盐微晶玻璃绿色上转换发光的温度特性

材料合成及性能 | 更新时间：2020-08-12

- Er³⁺/Yb³⁺共掺杂氧氟硼硅酸盐微晶玻璃绿色上转换发光的温度特性
- Temperature Characteristic of Green Upconversion Luminescence in Er³⁺/Yb³⁺ Codoped Oxyfluoride Borosilicate Glass Ceramics
- 发光学报 2015年36卷第9期页码：1001-1005
- 作者机构：
  
  中国计量学院材料科学与工程学院,浙江杭州,310018
- 作者简介：
- 基金信息：
  
  国家自然科学基金(51372236)();国家国际科技合作专项(DFE63070)();浙江省自然科学基金(LR15F050003)();人社部留学人才科研活动择优(2
- DOI：10.3788/fgxb20153609.1001
  中图分类号： O482.31
- 纸质出版日期：2015-9-3，
  
  收稿日期：2015-5-19，
  
  修回日期：2015-7-29，
扫描看全文
林杨杨, 陈铠炀, 唐霞艳等. Er3+/Yb3+共掺杂氧氟硼硅酸盐微晶玻璃绿色上转换发光的温度特性[J]. 发光学报, 2015,36(9): 1001-1005

Lin Yang-yang, Chen Kai-yang, Tang Xia-yan etc. Temperature Characteristic of Green Upconversion Luminescence in Er3+/Yb3+ Codoped Oxyfluoride Borosilicate Glass Ceramics[J]. Chinese Journal of Luminescence, 2015,36(9): 1001-1005
林杨杨, 陈铠炀, 唐霞艳等. Er3+/Yb3+共掺杂氧氟硼硅酸盐微晶玻璃绿色上转换发光的温度特性[J]. 发光学报, 2015,36(9): 1001-1005 DOI： 10.3788/fgxb20153609.1001.

Lin Yang-yang, Chen Kai-yang, Tang Xia-yan etc. Temperature Characteristic of Green Upconversion Luminescence in Er3+/Yb3+ Codoped Oxyfluoride Borosilicate Glass Ceramics[J]. Chinese Journal of Luminescence, 2015,36(9): 1001-1005 DOI： 10.3788/fgxb20153609.1001.

摘要

采用高温熔融法和热处理工艺制备得到透明的Er

/Yb

共掺杂氧氟微晶玻璃。XRD结果证实析出的纳米晶相为BaYF

。在980nm激发下

观察到强的绿光发射

源于Er

的

11/2

15/2

和

3/2

15/2

跃迁的上转换发光。根据荧光强度比(FIR)的方法研究了微晶玻璃上转换荧光的温度传感特性

其最大灵敏度在523K时为0.0034K

-1

表明Er

/Yb

共掺氧氟硼硅酸盐微晶玻璃上转换发光在高精度温度传感器方面具有一定的应用前景。

Abstract

/Yb

codoped oxyfluoride borosilicate glass ceramics were prepared by the traditional high temperature melt-quenching method and subsequent thermal treatment procedure and all the oxyfluoride glass ceramics were transparent. XRD results certified the formation of BaYF

phase during the crystallization process. Under the excitation of 980 nm laser diode

strong green upconversion emissions were observed

which came from the transitions

11/2

15/2

and

3/2

15/2

of Er

ions. Based on the fluorescence intensity ratio(FIR) method

the temperature characteristic of green upconversion emission was investigated and the maximum sensitivity was 0.003 4 K

-1

at 523 K. The experiment results indicate that the upconversion luminescence of Er

/Yb

co-doped oxyfluoride borosilicate glass ceramics is promising for the application as optical temperature sensors with high accuracy.

关键词

上转换荧光Er3+离子氧氟微晶玻璃温度传感

Keywords

upconversion luminescenceEr3+oxyfluoride glass ceramictemperature sensor

references

Zheng K, Liu Z, Lv C, et al. Temperature sensor based on the UV upconversion luminescence of Gd3+ in Yb3+-Tm3+-Gd3+ codoped NaLuF4 microcrystals [J]. J. Mater. Chem. C, 2013, 1:5502-5507.

Feng Z, Bai L, Cao B, et al. Er3+-Yb3+ codoped boroslicate glass for optical thermometry [J]. Sci. China-Phys. Mech. Astro., 2010, 40(8):955-958.

Li J, Sun J, Zhang J, et al. Temperature effect of downconversion luminescence in Er3+, Yb3+ codoped Gd2WO6 phosphors [J]. Chin. J. Lumin.(发光学报), 2013, 34(4):400-405 (in Chinese).

Zheng L, Gao X, Xu W, et al. Temperature characteristic of blue upconversion emission in Tm3+, Yb3+ codoped oxyfluoride glass ceramic [J]. Chin. J. Lumin.(发光学报), 2012, 33(9):944-948 (in Chinese).

Yang Y, Mi C, Yu F, et al. Optical thermometry based on the upconversion fluorescence from Yb3+/Er3+ codoped La2O2S phosphor [J]. Ceram. Int., 2014, 40:9875-9880.

Bao Y, Zhao Z, Fu Y. Temperature sensing based on fluorescence intensity ratio of rare earth doped fiber [J]. Opt. Fiber & Electric Cable (光纤与电缆及其应用技术), 2010, 5:1-4 (in Chinese).

Zheng H, Xiang S, Chen B. Laser irradiation induced temperature effect of NaY(WO4)2 :Tm3+,Yb3+ using Er3+ as optical temperature sensor [J]. Chin. J. Lumin.(发光学报), 2014, 35(7):800-806 (in Chinese).

Cai Z, Xu H. Point temperature sensor based on green upconversion emission in an Er :ZBLALiP microsphere [J]. Sens. Actuat. A, 2003, 108:187-192.

Xu W, Gao X, Zheng L, et al. An optical temperature sensor based on the upconversion luminescence from Tm3+/Yb3+ codoped oxyfluoride glass ceramic [J]. Sens. Actuat. B: Chem., 2012, 173:250-253.

Jiang S, Zeng P, Liao L, et al. Optical thermometry based on upconverted luminescence in transparent glass ceramics containing NaYF4 :Yb3+/Er3+ nanocrystals [J]. J. Alloys Compd., 2014, 617:538-541.

Chen D, Zhou Y, Wan Z, et al. Enhanced upconversion luminescence in phase-separation-controlled crystal crystallization glass ceramics containing Yb/Er(Tm) :NaLuF4 nanocrystals [J]. J. Eur. Ceram. Soc., 2015, 35(7):2129-2137.

Chen D, Wan Z, Zhou Y, et al. Bulk glass ceramics containing Yb3+/Er3+ :-NaGdF4 nanocrystals: Phase-separation-controlled crystallization, optical spectroscopy and upconverted temperature sensing behavior [J]. J. Alloys Compd., 2015, 638:21-28.

Chen D, Wan Z, Zhou Y, et al. Tuning into blue and red: Europium single-doped nano-glass-ceramics for potential application in photosynthesis [J]. J. Mater. Chem. C, 2015, 3:3141-3149.

Chen D, Zhou Y, Wan Z, et al. Tunable upconversion luminescence in self-crystallized Er3+ :K(Y1-xYbx)3F10 nano-glass-ceramics [J]. Phys. Chem. Chem. Phys., 2015, 17:7100-7103.

Yoo M Y, Lee J H, Jeong H M, et al. Enhancement of photoluminescence and upconversion in Er-Yb codoped nanocrytalline glass-ceramics [J]. Opt. Mater., 2013, 35(11):1922-1926.

Vijaya N, Babu P, Venkatramu V, et al. Optical characterization of Er3+-doped zinc fluophosphate glasses for optical temperature sensors [J]. Sens. Actuat. B: Chem., 2013, 186:156-164.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

六角柱形NaErF₄和NaErF₄@NaYF₄核壳微粒制备及多色上转换荧光调控性能

NaYF₄:Yb³⁺,Tm³⁺/CdSe纳米异质结构的近红外上转换发光性能

掺Er³⁺钆硼硅酸盐玻璃及玻璃陶瓷的红外发光特性和热稳定性