快速退火对PLD法制备SnS薄膜结构和光学性质的影响

刘磊; 马明杰; 刘丹丹; 郭慧尔; 史成武; 梁齐

doi:10.3788/fgxb20153607.0811

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快速退火对PLD法制备SnS薄膜结构和光学性质的影响

器件制备及器件物理 | 更新时间：2020-08-12

- 快速退火对PLD法制备SnS薄膜结构和光学性质的影响
- Influence of Rapid Thermal Annealing on The Structural and Optical Properties of Pulsed Laser Deposited SnS Thin Films
- 发光学报 2015年36卷第7期页码：811-820
- 作者机构：
  
  1. 合肥工业大学电子科学与应用物理学院,安徽合肥,230009
  2. 合肥工业大学化学与化工学院,安徽合肥,230009
- 作者简介：
- 基金信息：
  
  SnS thin film|pulsed laser deposition|rapid thermal annealing|optical properties()
- DOI：10.3788/fgxb20153607.0811
  中图分类号： O484;TN304
- 纸质出版日期：2015-7-3，
  
  收稿日期：2015-4-13，
  
  修回日期：2015-4-29，
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刘磊, 马明杰, 刘丹丹等. 快速退火对PLD法制备SnS薄膜结构和光学性质的影响[J]. 发光学报, 2015,36(7): 811-820

LIU Lei, MA Ming-jie, LIU Dan-dan etc. Influence of Rapid Thermal Annealing on The Structural and Optical Properties of Pulsed Laser Deposited SnS Thin Films[J]. Chinese Journal of Luminescence, 2015,36(7): 811-820
刘磊, 马明杰, 刘丹丹等. 快速退火对PLD法制备SnS薄膜结构和光学性质的影响[J]. 发光学报, 2015,36(7): 811-820 DOI： 10.3788/fgxb20153607.0811.

LIU Lei, MA Ming-jie, LIU Dan-dan etc. Influence of Rapid Thermal Annealing on The Structural and Optical Properties of Pulsed Laser Deposited SnS Thin Films[J]. Chinese Journal of Luminescence, 2015,36(7): 811-820 DOI： 10.3788/fgxb20153607.0811.

摘要

利用脉冲激光沉积(PLD) 法在玻璃基片上室温生长SnS 薄膜

并在Ar气保护下分别在200

300

400

500

600 ℃对薄膜进行快速退火处理。利用X射线衍射(XRD)、拉曼光谱仪(Raman)、原子力显微镜(AFM)、场发射扫描电子显微镜(FE-SEM)、紫外-可见-近红外分光光度计(UV-Vis-NIR)、Keithley 4200-SCS半导体参数分析仪研究了快速退火温度对SnS薄膜的晶体结构、表面形貌以及有关光学性质和电学性能的影响。所制备的SnS 薄膜样品沿(111)晶面择优取向生长

退火温度为400 ℃时的薄膜结晶质量最好。薄膜均具有SnS 特征拉曼峰。随着退火温度的升高

薄膜厚度逐渐减小

而平均颗粒尺寸逐渐增大。不同退火温度下的SnS 薄膜在可见光范围内的吸收系数均为10

-1

量级

400 ℃时退火薄膜的直接带隙为1.92 eV。随着退火温度从300 ℃升高到500 ℃

电阻率由1.8510

cm下降到14.97 cm。

Abstract

SnS thin films were grown by pulsed laser deposition on glass substrates at room temperature

and then the deposited films were rapidly annealed at 200

300

400

500

600 ℃ under flowing argon atmosphere. The effects of rapid thermal annealing(RTA) temperature on the microstructural

morphological

optical properties and electrical properties of SnS thin films were studied by X-ray diffraction(XRD)

laser Raman spectrometry(Raman)

atomic force microscopy(AFM)

field emission scanning electron microscopy (FESEM)

ultraviolet-visible-near infrared spectrophotometer (UV-Vis-NIR) and Keithley 4200-SCS semiconductor parameter analyzer. The results show that SnS thin films grow preferentially oriented in the (111) direction

and the crystalline quality of SnS thin films is the best at 400 ℃. Raman characteristic peaks of SnS appear in Raman spectra of the thin films. While the increasing of the annealing temperature

the thickness of the films gradually decrease whereas the average particle sizes of the films increase. The absorption coefficient in the visible region is in the order of 10

-1

at different thermal annealing temperature. The direct bandgap of the film is 1.92 eV at 400 ℃. With the increasing of the thermal annealing temperature from 300 to 500 ℃

the resistivity of the films decreases from 1.85×10

to 14.97 Ω·cm.

关键词

SnS 薄膜脉冲激光沉积快速退火光学性质

Keywords

SnS thin filmpulsed laser depositionrapid thermal annealingoptical properties

references

Hartman K, Johnson J L, Bertoni M I, et al. SnS thin film by RF sputtering at room temperature [J]. Thin Solid Films, 2011, 519(21):7421-7423.

Miles R W, Ogah O E, Zoppi G, et al. Thermally evaporated thin films of SnS for application in solar cell devices [J]. Thin Solid Films, 2009, 517(14):4702-4705.

Subramanian B, Chinnappanadar S. Cathodic electrodeposition and analysis of SnS films for photoelectrochemical cells [J]. Mater. Chem. Phys., 2001, 71(1):40-46.

Feng J, Honglie S, Chao G, et al. Preparation and properties of SnS films grown by two-stage process [J]. Appl. Surf. Sci., 2011, 257(11):4901-4902.

Ghosh B, Bhattacharjee R, Banerjee P, et al. Structural and optoelectronic properties of vacuum evaporated SnS thin films annealed in argon ambient [J]. Appl. Surf. Sci., 2011, 257(8):3670-3675.

Calixto-Rodriguez M, Martinez H, Sanchez-Juarez A, et al. Structural, optical, and electrical properties of tin sulfide thin films grown by spray pyrolysis [J]. Thin Solid Films, 2009, 517(7):2497-2499.

Avellaneda D, Delgado G, Nair M T S, et al. Structural and chemical transformations in SnS thin films used in chemically deposited photovoltaic cells [J]. Thin Solid Films, 2007, 515(15):5771-5776.

Guastavino Y F, Llinares C, Djessas K, et al. SnS thin films grown by close spaced vapor transport [J]. J. Mater. Sci. Lett., 2000, 19(23):2135-2137.

Cruz M, Morales J. XRD, XPS and Sn NMR study of tin sulfides by using chemical vaportransport methods [J]. J. Solid State Chem., 2003, 175(2):359-365.

Sousa M G, Cunha A F, Fernandes P A. Annealing of RF-magnetron sputtered SnS2 as a new route for single phase SnS thin films [J]. J. Alloys Compd., 2014, 592:80-85.

Ran F Y, Xiao Z W, Hiramatsu H, et al. Growth of high-quality SnS epitaxial film by H2S flow pulsed laser deposition [J]. Appl. Phys. Lett., 2014, 104(7):072106-1-3.

Bian J M, Du G T, Hu L Z, et al. Growth and photo luminescence characteristic of high quality ZnO films by pulsed laser deposition(PLD) method [J]. Chin. J. Lumin.(发光学报), 2006, 27(6):958-962 (in Chinese).

Mathews N R, Garca C C, Torres I Z. Effect of annealing on structural, optical and electrical properties of pulse electrodeposited tin sulfide films [J]. Mater. Sci. Semicond. Proc., 2013, 16(1):29-37.

Chandrasekhar H R, Humphreys R G, Zwick U, et al. Infrared and Raman-spectra of the Ⅳ-Ⅵ compounds SnS and SnSe [J]. Phys. Rev. B, 1977, 16(15):2177-2183.

Nikolic P M, Miljkovic L, Mihajlovic P, et al. Splitting and coupling of lattice modes in layer compound SnS [J]. Phys. C: Solid State, 1977, 10(11):L289-L292.

Koteeswara N, Reddy. Growth-temperature dependent physical properties of SnS nanocrystalline thin films [J]. ECS J. Sloid State Sci. Technol., 2013, 2(6):259-263.

Banai R E, Lee H, Motyka M A, et al. Optical properties of sputtered SnS thin films for photovolatic absorbers [J]. Browse J. Mag., 2013, 3(3):1084-1089.

Cheng S Y, Chen Y Q, Huang C C, et al. Characterization of SnS films prepared by constant-current electro-deposition [J]. Thin Solid Films, 2006, 500(2):96-100.

Cheng S Y, Conibeer G. Physical properties of very thin SnS films deposited by thermal evaporation [J]. Thin Solid Films, 2011, 520(2):837-841.

Devika M, Reddy K N, Ramesh K, et al. Thickness effect on the physical properties of evaporated SnS films [J]. J. Electrochem. Soc., 2007, 154(2):H67-H73.

Kumar K S, Manoharan C, Dhanapandian S, et al. Effect of Sb dopant on the structural, optical and electrical properties of SnS thin films by spray pyrolysis technique [J]. Mol. Biomol. Spectrosc., 2013, 115:842-844.

Selim M S, Gonda M E, El-Shaarawy M G, et al. Effect of thickness on optical properties of theamally evaporated SnS films [J]. Thin Sold Films, 2013, 527(1):164-169.

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