飞秒激光诱导的Mn2+ 掺杂锗酸盐玻璃上转换发光

张扬; 钱静; 李鹏飞; 鲍宗杰; 王承伟; 赵全忠

doi:10.3788/fgxb20153607.0738

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飞秒激光诱导的Mn²⁺掺杂锗酸盐玻璃上转换发光

材料合成及性能 | 更新时间：2020-08-12

- 飞秒激光诱导的Mn²⁺掺杂锗酸盐玻璃上转换发光
- Upconversion Luminescence of Mn²⁺ Doped-germanate Glass Induced by Femtosecond Laser Pulses
- 发光学报 2015年36卷第7期页码：738-743
- 作者机构：
  
  1. 中国科学院大学北京,100049
  2. 同济大学物理科学与工程学院精密光学工程技术研究所, 先进微结构材料教育部重点实验室上海,200092
  3. 中国科学院上海光学精密机械研究所强场激光物理国家重点实验室上海,201800
  4. 华南理工大学材料学院光通信材料研究所, 发光材料与器件国家重点实验室,广东广州,510640
- 作者简介：
- 基金信息：
  
  国家自然科学基金(11374316,61178024)();973 国家重点基础研究发展计划(2011CB808103)资助项目()
- DOI：10.3788/fgxb20153607.0738
  中图分类号： O433.1;O482.31
- 纸质出版日期：2015-7-3，
  
  收稿日期：2015-4-13，
  
  修回日期：2015-5-15，
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张扬, 钱静, 李鹏飞等. 飞秒激光诱导的Mn2+ 掺杂锗酸盐玻璃上转换发光[J]. 发光学报, 2015,36(7): 738-743

ZHANG Yang, QIAN Jing, LI Peng-fei etc. Upconversion Luminescence of Mn2+ Doped-germanate Glass Induced by Femtosecond Laser Pulses[J]. Chinese Journal of Luminescence, 2015,36(7): 738-743
张扬, 钱静, 李鹏飞等. 飞秒激光诱导的Mn2+ 掺杂锗酸盐玻璃上转换发光[J]. 发光学报, 2015,36(7): 738-743 DOI： 10.3788/fgxb20153607.0738.

ZHANG Yang, QIAN Jing, LI Peng-fei etc. Upconversion Luminescence of Mn2+ Doped-germanate Glass Induced by Femtosecond Laser Pulses[J]. Chinese Journal of Luminescence, 2015,36(7): 738-743 DOI： 10.3788/fgxb20153607.0738.

摘要

研究了室温下的飞秒激光诱导过渡金属Mn

掺杂锗酸盐玻璃的上转换发光现象。样品的激发光谱与发射光谱表明

激发过程是能级

G)/

(

G)的跃迁

该过程源于Mn

离子的

(

S)跃迁。由409 nm单色光激发样品得到的发射光谱与800 nm飞秒激光激发的光谱相一致。通过分析飞秒激光泵浦功率密度与荧光强度的依赖关系以及飞秒激光辐照样品前后的吸收谱

认为该上转换过程为双光子同时吸收过程。随着Mn

浓度的提高

上转换发光的中心波长发生红移。

Abstract

The upconversion luminescence of Mn

doped transparent germanate glass induced by 800 nm femtosecond laser at room temperature was investigated. The excitation and emission spectra show that the excitation process stems from the

G)/

(

G) transition while the emission originates from the

(

S) transition of Mn

. The emission spectrum excited by 409 nm monochromatic light is similar to that irradiated by 800 nm femtosecond laser. Moreover

by measuring the dependence of the fluorescence intensity on the pump power together with the absorption spectra of both the undoped and doped glass

the conversion of infrared radiation to the visible emission dominated by a two-photon absorption process is confirmed. As Mn

is the only emission center

a significant red-shift with the increasing of Mn

concentration is also observed.

关键词

上转换荧光双光子吸收飞秒激光Mn2+同时吸收

Keywords

upconversionluminescencefemtosecond laserMn2+two-photon absorption

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