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1. 中国科学院大学 北京,100049
2. 同济大学物理科学与工程学院 精密光学工程技术研究所, 先进微结构材料教育部重点实验室 上海,200092
3. 中国科学院上海光学精密机械研究所 强场激光物理国家重点实验室 上海,201800
4. 华南理工大学材料学院 光通信材料研究所, 发光材料与器件国家重点实验室,广东 广州,510640
纸质出版日期:2015-7-3,
收稿日期:2015-4-13,
修回日期:2015-5-15,
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张扬, 钱静, 李鹏飞等. 飞秒激光诱导的Mn<sup>2+ </sup>掺杂锗酸盐玻璃上转换发光[J]. 发光学报, 2015,36(7): 738-743
ZHANG Yang, QIAN Jing, LI Peng-fei etc. Upconversion Luminescence of Mn<sup>2+</sup> Doped-germanate Glass Induced by Femtosecond Laser Pulses[J]. Chinese Journal of Luminescence, 2015,36(7): 738-743
张扬, 钱静, 李鹏飞等. 飞秒激光诱导的Mn<sup>2+ </sup>掺杂锗酸盐玻璃上转换发光[J]. 发光学报, 2015,36(7): 738-743 DOI: 10.3788/fgxb20153607.0738.
ZHANG Yang, QIAN Jing, LI Peng-fei etc. Upconversion Luminescence of Mn<sup>2+</sup> Doped-germanate Glass Induced by Femtosecond Laser Pulses[J]. Chinese Journal of Luminescence, 2015,36(7): 738-743 DOI: 10.3788/fgxb20153607.0738.
研究了室温下的飞秒激光诱导过渡金属Mn
2+
掺杂锗酸盐玻璃的上转换发光现象。样品的激发光谱与发射光谱表明
激发过程是能级
6
A(
6
S)
4
E(
4
G)/
4
A
1
(
4
G)的跃迁
该过程源于Mn
2+
离子的
4
T
1
(
4
G)
6
A
1
(
6
S)跃迁。由409 nm单色光激发样品得到的发射光谱与800 nm飞秒激光激发的光谱相一致。通过分析飞秒激光泵浦功率密度与荧光强度的依赖关系以及飞秒激光辐照样品前后的吸收谱
认为该上转换过程为双光子同时吸收过程。随着Mn
2+
浓度的提高
上转换发光的中心波长发生红移。
The upconversion luminescence of Mn
2+
doped transparent germanate glass induced by 800 nm femtosecond laser at room temperature was investigated. The excitation and emission spectra show that the excitation process stems from the
6
A(
6
S)
4
E(
4
G)/
4
A
1
(
4
G) transition while the emission originates from the
4
T
1
(
4
G)
6
A
1
(
6
S) transition of Mn
2+
. The emission spectrum excited by 409 nm monochromatic light is similar to that irradiated by 800 nm femtosecond laser. Moreover
by measuring the dependence of the fluorescence intensity on the pump power together with the absorption spectra of both the undoped and doped glass
the conversion of infrared radiation to the visible emission dominated by a two-photon absorption process is confirmed. As Mn
2+
is the only emission center
a significant red-shift with the increasing of Mn
2+
concentration is also observed.
上转换荧光双光子吸收飞秒激光Mn2+同时吸收
upconversionluminescencefemtosecond laserMn2+two-photon absorption
Parthenopoulos D A, Rentzepis P M. Three-dimensional optical storage memory [J]. Science, 1989, 245:843-845.
Johnson L F, Guggenhe H J. Infrared-pumped visible laser [J]. Appl. Phys. Lett., 1971, 19(1):44-47.
Downing E, Hesselink L, Ralston J, et al. A three-color, solid-state, three-dimensional display [J]. Science, 1996, 273:1185-1189.
Denk W, Strickler J H, Webb W W. Two-photon laser scanning fluorescence microscopy [J]. Science, 1990, 248:73-76.
Wang F, Liu X. Recent advances in the chemistry of lanthanide-doped upconversion nanocrystals [J]. Chem. Soc. Rev., 2009, 38:976-989.
Chen W, Su F, Li G, et al. Temperature and pressure dependences of the Mn2+ and donor-acceptor emissions in ZnS:Mn2+ nanoparticles [J]. J. Appl. Phys., 2002, 92:1950-1955.
Auzel F. A general fundamental condition for flat gain optical amplification: Application to Er3+-doped glasses and glass ceramics [J]. J. Non-Cryst. Solids, 2008, 354:4765-4769.
Yang L, Wang C, Dong Y, et al. Three-photon-excited upconversion luminescence of YVO4 single crystal by infrared femtosecond laser irradiation [J]. Opt. Express, 2005, 13:10157-10162.
Joly A G, Chen W, McCready D E, et al. Upconversion luminescence of CdTe nanoparticles [J]. Phys. Rev. B: Condens. Matter, 2005, 71(16):165304-1-7.
Jacobsen S M, Gdel H U. Higher excited state luminescence in Ti2+:MgCl2 dynamics of radiative and nonradiative processes [J]. J. Lumin., 1989, 43:125-137.
Oetliker U, Riley M J, May P S, et al. Excitation avalanche in Ni2+-doped CsCdCl3 [J]. J. Lumin., 1992, 53:553-556.
Heer S, Wermuth M, Krmer K, et al. Upconversion excitation of Cr3+ 2E emission in Y3Ga5O12 codoped with Cr3+ and Yb3+ [J]. Chem. Phys. Lett., 2001, 334:293-297.
Micheletti R, Minguzzi P, Noginov M, et al. Upconversion luminescence of Er and Cr in YSGG laser crystals [J]. J. Opt. Soc. Am. B: Opt. Phys., 1994, 11:2095-2099.
Gamelin D R, Gdel H U. Two-photon spectroscopy of d3 transition metals: Near-IR-to-visible upconversion luminescence by Re4+ and Mo3+ [J]. J. Amer. Chem. Soc., 1998, 120:12143-12144.
Gamelin D R, Gdel H U. Spectroscopy and dynamics of Re4+ near-IR-to-visible luminescence upconversion [J]. Inorg. Chem., 1999, 38:5154-5164.
Davis K M, Miura K, Sugimoto N, et al. Writing waveguides in glass with a femtosecond laser [J]. Opt. Lett., 1996, 21:1729-1731.
Miura K, Qiu J, Inouye H, et al. Photowritten optical waveguides in various glasses with ultrashort pulse laser [J]. Appl. Phys. Lett., 1997, 71:3329-3331.
Qiu J, Miura K, Inouye H, et al. Femtosecond laser-induced three-dimensional bright and long-lasting phosphorescence inside calcium aluminosilicate glasses doped with rare earth ions [J]. Appl. Phys. Lett., 1998, 73:1763-1765.
Miura K, Qiu J, Mitsuyu T, et al. Space-selective growth of frequency-conversion crystals in glasses with ultrashort infrared laser pulses [J]. Opt. Lett., 2000, 25:408-410.
Ronda C, Amrein T. Evidence for exchange-induced luminescence in Zn2SiO4:Mn [J]. J. Lumin., 1996, 69:245-248.
Da N, Peng M, Krolikowski S, et al. Intense red photoluminescence from Mn2+-doped (Na+; Zn2+) sulfophosphate glasses and glass ceramics as LED converters [J]. Opt. Express, 2010, 18:2549-2557.
Li P, Peng M, Yin X, et al. Temperature dependent red luminescence from a distorted Mn4+ site in CaAl4O7:Mn4+ [J]. Opt. Express, 2013, 21:18943-18948.
Qiu J, Kondo Y, Miura K, et al. Infrared femtosecond laser induced visible long-lasting phosphorescence in Mn2+-doped sodium borate glasses [J]. Jpn. J. Appl. Phys., 1999, 38:L649-L651.
Chin R, Shen Y, Petrova-Koch V. Photoluminescence from porous silicon by infrared multiphoton excitation [J]. Science, 1995, 270:776-778.
Yang Q, Lin S, Xu L, et al. Observation of upconversion fluorescence and stimulated emission based on three-photon absorption [J]. Appl. Phys. B, 2005, 80:953-955.
Dong Y, Xu J, Zhao G, et al. Simultaneous three-photon-excited violet upconversion luminescence of Ce3+:Lu2Si2O7 single crystals by femtosecond laser irradiation [J]. Opt. Lett., 2006, 31:2175-2177.
Yang L, Dong Y, Chen D, et al. Three-photon-excited upconversion luminescence of Ce3+:YAP crystal by femtosecond laser irradiation [J]. Opt. Express, 2006, 14:243-247.
Scheps R. Upconversion laser processes [J]. Prog. Quant. Electron., 1996, 20:271-358.
Chivian J S, Case W E, Eden D D. The photon avalanche: A new phenomenon in Pr3+-based infrared quantum counters [J]. Appl. Phys. Lett., 1979, 35:124-125.
Auzel F. Upconversion and anti-stokes processes with f and d ions in solids [J]. Chem. Rev., 2004, 104:139-174.
Kaiser W, Garrett C. Two-photon excitation in CaF2:Eu2+ [J]. Phys. Rev. Lett., 1961, 7:229-231.
Kawata S, Sun H B, Tanaka T, et al. Finer features for functional microdevices [J]. Nature, 2001, 412(6848):697-698.
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