聚合物太阳能电池中石墨烯量子点掺杂材料的优化

孙强; 范思大; 董金鹏; 苏和平; 王丽娟; 李占国; 曲轶

doi:10.37188/fgxb20204109.1137

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聚合物太阳能电池中石墨烯量子点掺杂材料的优化

材料合成及性能 | 更新时间：2020-09-10

- 聚合物太阳能电池中石墨烯量子点掺杂材料的优化
- Optimization of Graphene Quantum Dots as Doping Materials in Polymer Solar Cells
- 发光学报 2020年41卷第9期页码：1137-1145
- 作者机构：
  
  1.长春工业大学化学工程学院, 吉林长春 130012
  2.长春理工大学光电工程学院, 吉林长春 130022
  3.海南师范大学物理电子工程学院, 海南海口 571158
- 作者简介：
  
  [ "孙强(1996-), 男, 山东临沂人, 硕士研究生, 2014年于长春工业大学获得学士学位, 主要从事有机薄膜晶体管、聚合物太阳能电池与光显示的研究。E-mail:836681640@qq.com" ]
  [ "王丽娟(1975-), 女, 黑龙江集贤人, 博士, 副教授, 2008年于长春理工大学获得博士学位, 主要从事有机薄膜晶体管、气体传感器、太阳能电池、新型显示技术等方面的研究。E-mail:wlj15@163.com" ]
- 基金信息：
  
  海南省自然科学基金(2018CXTD336);长春工业大学大学生创新创业训练计划项目(2020cxcy0091);长春工业大学大学生创新创业训练计划项目(202010190106);吉林省科技厅重点攻关项目(20180201005SF);吉林省科技厅重点攻关项目(20200403146SF);国家自然科学基金(61864002)
- DOI：10.37188/fgxb20204109.1137
  中图分类号： O482.31
- 纸质出版日期：2020-9，
  
  收稿日期：2020-5-28，
  
  录用日期：2020-6-20
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孙强, 范思大, 董金鹏, 等. 聚合物太阳能电池中石墨烯量子点掺杂材料的优化[J]. 发光学报, 2020,41(9):1137-1145.

Qiang SUN, Si-da FAN, Jin-peng DONG, et al. Optimization of Graphene Quantum Dots as Doping Materials in Polymer Solar Cells[J]. Chinese Journal of Luminescence, 2020,41(9):1137-1145.
孙强, 范思大, 董金鹏, 等. 聚合物太阳能电池中石墨烯量子点掺杂材料的优化[J]. 发光学报, 2020,41(9):1137-1145. DOI： 10.37188/fgxb20204109.1137.

Qiang SUN, Si-da FAN, Jin-peng DONG, et al. Optimization of Graphene Quantum Dots as Doping Materials in Polymer Solar Cells[J]. Chinese Journal of Luminescence, 2020,41(9):1137-1145. DOI： 10.37188/fgxb20204109.1137.

摘要

采用溶剂热法，以氧化石墨烯为前驱体制备了石墨烯量子点（GQDs），将不同制备条件和质量分数的GQDs掺杂到聚3-己基噻吩和[6

6]-苯基-C61-丁酸甲酯（PCBM:P3HT）中作为敏感层制备了太阳能电池器件。实验结果表明，敏感层掺杂0.2%质量分数的GQDs时，太阳能电池光电转换效率较未掺杂器件提高了16.45%。敏感层掺杂反应时间4 h和温度220℃制备的GQDs，获得低粗糙度和高紫外可见光吸收强度的敏感层薄膜，制备的太阳能电池器件光电转换效率为1.34%，较未掺杂GQDs器件提高了12.60%。因此，GQDs适宜的制备条件和掺杂浓度可以提高太阳能电池器件的光电转换效率。

Abstract

Graphene oxide quantum dots(GQDs) were prepared by solvothermal method

using graphene oxide as a precursor. The solar cell devices were prepared by doping GQDs with different preparation conditions and mass fractions into poly 3-hexylthiophene and[6

6]-phenyl-C61-Methyl butyrate(PCBM:P3HT) as a sensitive layer. The experimental results show that when the sensitive layer is doped with GQDs of 0.2% mass fraction

the photoelectric conversion efficiency of solar cells is increased by 16.45% compared with that of undoped devices. When the sensitive layer is doped with GQDs prepared at a reaction time of 4 h and a temperature of 220℃

a sensitive layer film with low roughness and high ultraviolet visible light absorption strength is obtained. The photoelectric conversion efficiency of the prepared solar cells device was 1.34%

which was 12.60% higher than that of the undoped device. Therefore

suitable preparation conditions and doping concentration of GQDs can improve the photoelectric conversion efficiency of solar cell devices.

关键词

石墨烯量子点敏感层P3HT:PCBM聚合物太阳能电池表面粗糙度UV-Vis吸收光谱

Keywords

graphene quantum dotsactive layer P3HT:PCBMpolymer solar cellssurface roughnessUV-Vis absorption spectra

references

HEEGER A J. 25th anniversary article:bulk heterojunction solar cells:understanding the mechanism of operation[J].Adv. Mater., 2014, 26(1):10-28.

LIU Y H, ZHAO J B, LI Z K, et al.. Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells[J].Nat. Commun., 2014, 5:5293-1-8.

YU G, GAO J, HUMMELEN J C, et al.. Polymer photovoltaic cells:enhanced efficiencies via a network of internal donor-acceptor heterojunctions[J].Science, 1995, 270(5243):1789-1791.

SØNDERGAARD R, HÖSEL M, ANGMO D, et al.. Roll-to-roll fabrication of polymer solar cells[J].Mater. Today, 2012, 15(1-2):36-49.

HUANG Y, KRAMER E J, HEEGER A J, et al.. Bulk heterojunction solar cells:morphology and performance relationships[J].Chem. Rev., 2014, 114(14):7006-7043.

LIU J, XUE Y H, DAI L M, et al.. Sulfated graphene oxide as a hole-extraction layer in high-performance polymer solar cells[J].J. Phys. Chem. Lett., 2012, 3(14):1928-1933.

王俊, 禹豪, 张继华, 等.采用MoO3阳极缓冲层的钙钛矿太阳能电池研究[J].发光学报, 2018, 39(3):322-328.

WANG J, YU H, ZHANG J H, et al.. Study on perovskite solar cells with MoO3 anode buffer layer[J].Chin. J. Lumin., 2018, 39(3):322-328. (in Chinese)

JELTSCH K F, SCHÄDEL M, BONEKAMP J B, et al.. Efficiency enhanced hybrid solar cells using a blend of quantum dots and nanorods[J].Adv. Func. Mater., 2012, 22(2):397-404.

PANG S Z, ZHANG C F, ZHANG H R, et al.. Boosting performance of perovskite solar cells with graphene quantum dots decorated SnO2 electron transport layers[J].Appl. Surf. Sci., 2020, 507:145099.

GONZÁLEZ D M, KÖRSTGENS V, YAO Y, et al.. Improved power conversion efficiency of P3HT:PCBM organic solar cells by strong spin-orbit coupling-induced delayed fluorescence[J].Adv. Energy Mater., 2015, 5(8):1401770.

张梁, 孙强, 朱阳阳, 等. PbSe量子点调控的聚合物太阳能电池性能[J].发光学报, 2019, 40(10):1267-1273.

ZHANG L, SUN Q, ZHU Y Y, et al.. Improving performance of polymer solar cells by regulating PbSe quantum dots[J].Chin. J. Lumin., 2019, 40(10):1267-1273. (in Chinese)

GEIM A K, NOVOSELOV K S. The rise of graphene[J].Nat. Mater., 2007, 6(3):183-191.

谢世伟, 肖啸, 谭建军, 等.基于石墨烯基电极染料敏化太阳能电池的研究进展[J].中国光学, 2014, 7(1):47-56.

XIE S W, XIAO X, TAN J J, et al.. Recent progress in dye-sensitized solar cells using graphene-based electrodes[J].Chin. Opt., 2014, 7(1):47-56. (in Chinese)

庞渊源.石墨烯在半导体光电器件中的应用[J].液晶与显示, 2011, 26(3):296-300.

PANG Y Y. Application of graphene in semiconductor optoelectronic devices[J].Chin. J. Liq. Cryst. Disp., 2011, 26(3):296-300. (in Chinese)

NOVOSELOV K S, GEIM A K, MOROZOV S V, et al.. Electric field effect in atomically thin carbon films[J].Science, 2004, 306(5696):666-669.

ZHANG Y B, TAN Y W, STORMER H L, et al.. Experimental observation of the quantum Hall effect and Berry's phase in graphene[J].Nature, 2005, 438(7065):201-204.

NOVOSELOV K S, JIANG D, SCHEDIN F, et al.. Two-dimensional atomic crystals[J].Proc. Natl. Acad. Sci. USA, 2005, 102(30):10451-10453.

NOVOSELOV K S, GEIM A K, MOROZOV S V, et al.. Two-dimensional gas of massless dirac fermions in graphene[J].Nature, 2005, 438(7065):197-200.

HAN M Y, ÖZYILMAZ B, ZHANG Y B, et al.. Energy band-gap engineering of graphene nanoribbons[J].Phys. Rev. Lett., 2007, 98(20):206805-1-4.

LIU F, JANG M H, HA H D, et al.. Facile synthetic method for pristine graphene quantum dots and graphene oxide quantum dots:origin of blue and green luminescence[J].Adv. Mater., 2013, 25(27):3657-3662.

吴春霞, 宋泽琳.一步水热法合成的石墨烯量子点及其在锰离子探测中的应用[J].发光学报, 2015, 36(4):413-418.

WU C X, SONG Z L. One-step hydrothermal synthesis of graphene quantum dots and the application for Mn2+ detection[J].Chin. J. Lumin., 2015, 36(4):413-418. (in Chinese)

ZHOU X J, ZHANG Y, WANG C, et al.. Photo-Fenton reaction of graphene oxide:a new strategy to prepare graphene quantum dots for DNA cleavage[J].ACS Nano, 2012, 6(8):6592-6599.

LIU W W, FENG Y Q, YAN X B, et al.. Superior micro-supercapacitors based on graphene quantum dots[J].Adv. Funct. Mater., 2013, 23(33):4111-4122.

邹凤君, 范思大, 谢强, 等.掺杂石墨烯量子点对P3HT:PCBM太阳能电池性能的影响[J].发光学报, 2016, 37(9):1082-1089.

ZOU F J, FAN S D, XIE Q, et al.. Effect of doping graphene quantum dots on the performance of P3HT:PCBM solar cells[J].Chin. J. Lumin., 2016, 37(9):1082-1089. (in Chinese)

WU W T, ZHANG J L, SHEN W Z, et al.. Graphene quantum dots band structure tuned by size for efficient organic solar cells[J].Phys. Status Solidi A, 2019, 216(24):1900657.

LI W W, CHENG N, CAO Y, et al.. Boost the performance of inverted perovskite solar cells with PEDOT:PSS/graphene quantum dots composite hole transporting layer[J].Org. Electron., 2020, 78:105575.

DING Z C, HAO Z, MENG B, et al.. Few-layered graphene quantum dots as efficient hole-extraction layer for high-performance polymer solar cells[J].Nano Energy, 2015, 15:186-192.

HUMMERS W S JR, OFFEMAN R E. Preparation of graphitic oxide[J].J. Am. Chem. Soc., 1985, 80(6):1339.

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