钆铝石榴石(GdAG)基发光材料研究进展

薛秉国; 吕清洋; 王婷婷; 刘丽娜; 王世立; 朱海澄; 刘绍宏; 孙旭东

doi:10.37188/CJL.20200237

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钆铝石榴石(GdAG)基发光材料研究进展

特邀报告 | 更新时间：2020-12-10

- 钆铝石榴石(GdAG)基发光材料研究进展
- Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials
- 发光学报 2020年41卷第12期页码：1538-1553
- 作者机构：
  
  东北大学材料科学与工程学院, 辽宁沈阳 110819
- 作者简介：
  
  [ "薛秉国(1996-), 男, 湖南株洲人, 硕士研究生, 2018年于江苏科技大学获得学士学位, 主要从事闪烁薄膜的研究。E-mail:1800558@stu.neu.edu.cn" ]
  [ "刘绍宏(1981-), 男, 湖北十堰人, 博士, 副教授, 2010年于东北大学获得博士学位, 主要从事光功能材料的研究。E-mail:liush@smm.neu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51977027);教育部基本科研业务费项目(N182508026)
- DOI：10.37188/CJL.20200237
  中图分类号： O482.31
- 收稿日期：2020-08-05，
  
  录用日期：2020-8-31，
  
  纸质出版日期：2020-12
- 稿件说明：
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薛秉国, 吕清洋, 王婷婷, 等. 钆铝石榴石(GdAG)基发光材料研究进展[J]. 发光学报, 2020,41(12):1538-1553.

Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials[J]. Chinese journal of luminescence, 2020, 41(12): 1538-1553.
薛秉国, 吕清洋, 王婷婷, 等. 钆铝石榴石(GdAG)基发光材料研究进展[J]. 发光学报, 2020,41(12):1538-1553. DOI： 10.37188/CJL.20200237.

Bing-guo XUE, Qing-yang LYU, Ting-ting Wang, et al. Research Progress of Gd₃Al₅O₁₂-based Luminescent Materials[J]. Chinese journal of luminescence, 2020, 41(12): 1538-1553. DOI： 10.37188/CJL.20200237.

摘要

钆铝石榴石（Gd

，GdAG）是性能优异的发光基质材料，但其在高温煅烧时易发生分解，导致得到纯相GdAG基发光材料比较困难。近年来，研究证实通过小半径

（

=Y，Lu，Tb）取代部分Gd

，或通过离子半径更大的

来取代Al的位置扩大十二面体间隙，可以稳定GdAG晶格，得到纯相GdAG基发光材料。本文综述了GdAG基发光材料在晶格稳定化、下转换发光、上转换发光等方面的研究进展，并探讨了GdAG基单晶、薄膜和陶瓷的制备、性能及其在射线探测和医学成像等领域的应用前景。

Abstract

Gadolinium aluminum garnet(Gd

GdAG) is an excellent luminescent host material. But GdAG is easy to decompose during high temperature calcination

which makes it difficult to obtain a pure phase GdAG-based luminescent material. In recent years

research has confirmed that substituting the smaller radius

(

Tb) for part of Gd

or replacing the Al

with the larger radius

to expand the dodecahedral gap

can stabilize the GdAG lattice and thus obtain a pure phase GdAG-based luminescent material. This article reviews the research progress of GdAG-based luminescent materials including the lattice stabilization

down-conversion luminescence

and up-conversion luminescence

and also discusses the preparation and performances of GdAG-based single crystals

thin films and ceramics

and their applications in radiological detection and medical imaging.

关键词

Keywords

references

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