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1. 中国科学院长春光学精密机械与物理研究所激发态物理重点实验室,吉林 长春,130033
2. 东北大学秦皇岛分校 材料科学与工程系,河北 秦皇岛,066004
3. 东北大学秦皇岛分校 自动化系,河北 秦皇岛,066004
纸质出版日期:2010-9-21,
网络出版日期:2010-9-21,
收稿日期:2009-10-19,
修回日期:2009-12-2,
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钟瑞霞, 张家骅, 郝振东, 张 霞, 刘自然, 齐西伟, 李明亚, 韩秀梅. Eu<sup>2+</sup> , Cr<sup>3+</sup>共掺杂SrAl<sub>12</sub>O<sub>19</sub>发光体的发光性质及能量传递[J]. 发光学报, 2010,31(5): 728-731
ZHONG Rui-xia, ZHANG Jia-hua, HAO Zhen-dong, ZHANG Xia, LIU Zi-ran, QI Xi-wei, LI Ming-ya, HAN Xiu-mei. Luminescent Properties and Energy Transfer in SrAl<sub>12</sub>O<sub>19</sub> ∶ Eu<sup>2+</sup>, Cr<sup>3+</sup>[J]. 发光学报, 2010,31(5): 728-731
钟瑞霞, 张家骅, 郝振东, 张 霞, 刘自然, 齐西伟, 李明亚, 韩秀梅. Eu<sup>2+</sup> , Cr<sup>3+</sup>共掺杂SrAl<sub>12</sub>O<sub>19</sub>发光体的发光性质及能量传递[J]. 发光学报, 2010,31(5): 728-731 DOI:
ZHONG Rui-xia, ZHANG Jia-hua, HAO Zhen-dong, ZHANG Xia, LIU Zi-ran, QI Xi-wei, LI Ming-ya, HAN Xiu-mei. Luminescent Properties and Energy Transfer in SrAl<sub>12</sub>O<sub>19</sub> ∶ Eu<sup>2+</sup>, Cr<sup>3+</sup>[J]. 发光学报, 2010,31(5): 728-731 DOI:
采用高温固相法制备了Eu
2+
Cr
3+
单掺杂及共掺杂的SrAl
12
O
19
发光体
研究了它的发光性质和能量传递动力学过程。Eu
2+
的5d4f发射峰位于400 nm
与Cr
3+
位于350~450 nm波长范围的
4
A
2
4
T
1
的吸收带有显著的光谱重叠
有利于Eu
2+
Cr
3+
的能量传递发生
从而将来自于Eu
2+
离子的紫光转换为Cr
3+
的深红光发射。在共掺杂的样品中
当激发Eu
2+
时观察到Cr
3+
离子的
2
E
4
A
2
红色线谱发射。当监测该红色线谱发射时
激发光谱中包含有Eu
2+
的吸收
证明了在SrAl
12
O
19
体系中Eu
2+
Cr
3+
能量传递的存在。能量传递导致Eu
2+
的荧光寿命随Cr
3+
浓度的增加而缩短
计算表明能量传递效率随Cr
3+
浓度增加而提高
当Cr
3+
浓度为5%时能量传递效率可达到50%。
There exists an increasing demand for red emitting phosphors to be used in color display and illumination. SrAl
12
O
19
∶ Eu
2+
has attracted much attention for its excellent properties such as high quantum efficiency and good stability. However
the emission of SrAl
12
O
19
∶ Eu
2+
peaks at 400 nm
which is hard to be used in display and illumination. As we know
Cr
3+
with red emission lines is one of the most used activators for solid state laser and other luminescent materials. Therefore
we have studied the emission and excitation spectra as well as energy transfer in SrAl
12
O
19
∶ Eu
2+
Cr
3+
. The Cr
3+
Eu
2+
singly doped and co-doped samples were synthesized by solid-state reaction at 1 400 ℃. The emission band of Eu
2+
peaked at 400 nm is originating from the 5d-4f transition
which has large spectral overlaps with the
4
A
2
4
T
1
absorption band of Cr
3+
covering between 350 nm and 450 nm in the ultraviolet-blue region. It means the possibility of energy transfer from Eu
2+
to Cr
3+
. The conversion of violet-blue emission to the red may be obtained by the energy transfer. In the co-doped samples
the emission band of Eu
2+
appears in the range of excitation spectra of Cr
3+
emission
which indicates the occurrence of energy transfer from Eu
2+
to Cr
3+
. In order to explain energy transfer further
the lifetime of Eu
2+
emission in SrAl
12
O
19
∶ 1%Eu
2+
x
%Cr
3+
(
x
=0
0.2
1.0
2.0
3.0
4.0
5.0) has been measured. It shows that the lifetime of Eu
2+
reduces following increasing Cr
3+
concentration due to the energy transfer from Eu
2+
to Cr
3+
. The energy transfer efficiency as a function of Cr
3+
concentration has been calculated using the measured fluorescent lifetimes of Eu
2+
indicating the transfer efficiency increases with increasing Cr
3+
concentration
and may reach 50% as Cr
3+
concentration is 0.05.
红色发光粉能量传递Eu2+Cr3+
red phosphorenergy transferEu2+Cr3+
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. Appl. Phys. Lett., 1964, 4 (10):182-184.
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. Philips Res. Rep., 1968, 23 :201-206.
Zhong R X, Zhang J H, Zhang X, et al. Energy transfer and red phosphorescence in strontium aluminates co-doped with Cr3+, Eu2+ and Dy3+
. J. Lumin., 2006, 119-120 :327-331.
Zhong R X, Zhang J H, Zhang X, et al. Red phosphorescence in Sr4Al14O25 ∶ Cr3+, Eu2+, Dy3+ through persistent energy transfer
. Appl. Phys. Lett., 2006, 88 (20):201916-1-3.
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