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兰州大学 物理科学与技术学院
收稿:2010-01-22,
修回:1900-1-2,
网络首发:2010-06-30,
纸质出版:2010-06-30
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锁雅芹, 刘 肃, 刘凤琼, 等. Na-Mg共掺杂ZnO薄膜的结构和光学性质[J]. 发光学报, 2010,31(3):353-358.
SUO Ya-qin, LIU Su, LIU Feng-qiong, et al. Structural and Optical Properties of Na-Mg Co-doped ZnO Film[J]. Chinese Journal of Luminescence, 2010, 31(3): 353-358.
利用溶胶-凝胶法
在普通载玻片上使用旋转涂膜技术制备了具有
c
轴择优取向生长的Na-Mg共掺杂的ZnO薄膜。用XRD、SEM、光致发光(PL)及透射光谱对薄膜样品进行了表征。结果表明:Na-Mg共掺杂有利于ZnO薄膜的
c
轴择优取向生长
并且随着Na
+
掺杂浓度的增加
晶粒尺寸先增大后减小;通过比较不同掺杂浓度ZnO薄膜的PL谱
推测发光峰值位于380 nm的紫外发射与ZnO的自由激子复合有关;发现掺入Mg的确能使ZnO禁带宽度增大
掺杂组分为Na
0.04
Mg
0.2
Zn
0.76
O时
其PL谱只有一个很强的紫光发射峰
其近带边紫外光发射强度较未掺杂的ZnO增强了近10倍
极大地提高了薄膜紫外发光性能;并且随Na
+
浓度增加薄膜透光性减弱。
paper
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