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深圳大学材料学院 深圳市特种功能材料重点实验室,广东 深圳,518060
收稿日期:2009-11-25,
修回日期:1900-01-02,
网络出版日期:2010-04-30,
纸质出版日期:2010-04-30
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马晓翠, 叶家聪, 曹培江, 等. 射频溅射功率对AZO薄膜结构及 光电特性和热稳定性的影响[J]. 发光学报, 2010,31(2):235-238.
MA Xiao-cui, YE Jia-cong, CAO Pei-jiang, et al. Influence of Sputtering Power on the Structure, Optoelectronic Properties and Thermal Stability of ZnO ∶ Al Films[J]. Chinese journal of luminescence, 2010, 31(2): 235-238.
马晓翠, 叶家聪, 曹培江, 等. 射频溅射功率对AZO薄膜结构及 光电特性和热稳定性的影响[J]. 发光学报, 2010,31(2):235-238. DOI:
MA Xiao-cui, YE Jia-cong, CAO Pei-jiang, et al. Influence of Sputtering Power on the Structure, Optoelectronic Properties and Thermal Stability of ZnO ∶ Al Films[J]. Chinese journal of luminescence, 2010, 31(2): 235-238. DOI:
采用射频磁控溅射法
在玻璃基片上制备了ZnO ∶ Al (AZO)透明导电薄膜。用X射线衍射(XRD)仪、紫外-可见分光光度计、方块电阻测试仪和台阶仪对不同溅射功率下Al掺杂ZnO薄膜的结晶、光学、电学性能、沉积速率以及热稳定性进行了研究。研究结果表明:不同溅射功率下沉积的AZO薄膜具有六角纤锌矿结构
均呈
c
轴择优取向;(002)衍射峰强和薄膜的结晶度随溅射功率的提高逐渐增强;随溅射功率的提高
AZO薄膜的透射率有所下降
但在可见光(380~780 nm)范围内平均透射率仍>80%; 薄膜的方块电阻随溅射功率的增加逐渐减小;功率为160~200 W时
薄膜的热稳定性最好
升温前后方块电阻变化率为13%。
Al-doped ZnO (AZO) film has high transmittance in the visible region
low resistance and better stability
so AZO films have been actively investigated for potential applications in a variety of opto-electronic devices
such as solar cells
flat panel displays
transparent heat mirrors and organic light-emitting diodes. The properties of ZnO film are critically dependent on various deposition parameters
such as radio-frequency power
working gas pressure
and substrate temperature
and so on
Among these factors
the study of influence of rf power on film properties is important to build on the understanding of the relationship between film properties and process conditions. In this paper
using ZnO mixed with Al
2
O
3
(2%) as target
thin AZO films were prepared on glass substrates by radio frequency magnetron sputtering at different rf powers of 40
80
120
160 and 200 W. The influence of sputtering power on structure
optoelectronic properties
thickness and thermal stability of thin AZO films were investigated by XRD
UV-Vis spectrophotometer
four point probe and instrument level. It was found that the AZO thin films with hexagonal wurtzite structure have a (002)
c
-axis preferential orientation
and the intensity of the (002) peak increase as the increase of RF power. For all of the AZO thin films
the average transmittance of the visible light is above 80%. The sheet resistance decreases as the increase of RF power. The films deposited at 160 and 200 W show good thermal stability
which change of sheet resis-tance before and after heat treatment is about 13%. This high thermal stability indicated that AZO films can replace thin Sn-doped In
2
O
3
(ITO) films applying in the touch screen.
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