紫外光辐照对偶氮苯光谱特性的影响

高学喜; 牟 娟; 王文军; 刘云龙; 陶绪泉; 谢 倩; 李 云; 李 慧

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紫外光辐照对偶氮苯光谱特性的影响

论文 | 更新时间：2020-08-12

- 紫外光辐照对偶氮苯光谱特性的影响
- Influence of UV Illumination on Fluorescence Spectrum Properties of Azobenzen
- 发光学报 2009年30卷第4期页码：549-553
- 作者机构：
  
  1. 聊城大学物理科学与信息工程学院
  2. 聊城大学材料科学与工程学院
- 作者简介：
- 基金信息：
- DOI：
  中图分类号： O482.31
- 收稿：2008-09-14，
  
  修回：1900-1-2，
  
  网络首发：2009-08-30，
  
  纸质出版：2009-08-30
- 稿件说明：
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高学喜, 牟娟, 王文军, 等. 紫外光辐照对偶氮苯光谱特性的影响[J]. 发光学报, 2009,30(4):549-553.

GAO Xue-xi, MOU Juan, WANG Wen-jun, et al. Influence of UV Illumination on Fluorescence Spectrum Properties of Azobenzen[J]. Chinese Journal of Luminescence, 2009, 30(4): 549-553.
高学喜, 牟娟, 王文军, 等. 紫外光辐照对偶氮苯光谱特性的影响[J]. 发光学报, 2009,30(4):549-553. DOI：

GAO Xue-xi, MOU Juan, WANG Wen-jun, et al. Influence of UV Illumination on Fluorescence Spectrum Properties of Azobenzen[J]. Chinese Journal of Luminescence, 2009, 30(4): 549-553. DOI：

摘要

采用紫外可见吸收、稳态荧光光谱和荧光衰减测量技术

观察了4-硝基-4'-氨基偶氮苯(NAA)在氯仿溶液中的光致变色现象及分子的跃迁能级和能级寿命。结果表明:NAA分子的顺反异构化反应并非一级反应;分子处于反式异构体和顺式异构体的跃迁能分别为255.6

240.2 kJ/mol;分子处于反式异构体的能级寿命为0.02 ns

处于顺式异构体的能级寿命为3.54 ns。顺反异构体的含量、NAA分子之间及NAA分子与溶剂分子之间的相互作用影响NAA分子激发态的能级寿命。

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references

. Bredas J L, Adant C, Tackx P, et al. Third-order nonlinear optical response in organic materials: theoretical and experimental aspects [J]. Chem. Rev., 1994, 94 (1):243-278.

. Wang Wenjun, Wu Cheng, Gao Xuexi, et al. Studies on spectra and nonlinear optical properties of NMOB in langmuir-blodgett films [J]. Chin. J. Lasers (中国激光), 2005, 32 (8):1123-1126 (in Chinese).

. Sandhya K, Yesodha, Chennakattu K, et al. Stable polymeric materials for nonlinear optics: a review based on azobenzene systems [J]. Prog. Polym. Sci., 2004, 29 (1):45-74.

. Feng Zhongyao, Hu Manli, Ma Hui, et al. Properties of photo-induced birefringence in azobenzene copolymer [J]. Acta Photonica Sinica (光子学报), 2004, 33 (8):974-977 (in Chinese).

. Hua Jianli, Li Zhen, Qin Jingui, et al. Synthesis and characterization, second-order nonlinear optical and photorefractive properties of new multifunctional polysiloxane with broad optical transparent pentafluorophenyl azo chromophore [J]. Reactive & Functional Polymers, 2007, 67 (1):25-32.

. Paul J A, Kenis Esther G Kerver, Bianca H M, et al. High hyperpolarizabilities of donor-π-acceptor-functionalized calix

. arene derivatives by pre-organization of chromophores [J]. Eur. J. Org. Chem., 1998, 1998 (6):1089-1098.

. Xu Xia, Liu Cuihong, Xu Shihua, et al. Study on the photo induced-color changing about novel azobenzocrown ether derivatives 16ABC-OH and NH2 in water solution and langmuir-blodgett film [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2000, 20 (3):415-417 (in Chinese).

. Chen Guozhen, Huang Xianzhi, Xu Jingou, et al. Analysis Method of Fluorescence [M]. Beijing: Science Press, 2000, 75.

. Wu Shikang. Introduction of Macromolecules Photochemistry [M]. Beijing: Science Press, 2003, 247.

. Lee Geon Joon, Kim Dongho, Lee Minyung. Photophysical properties and photoisomerization processes of methyl red embedded in rigid polymer [J]. Appl. Optics, 1995, 34 (1):138-143.

. Egami C, Suzuki Y, Sugihara O, et al. Third-order resonant optical nonlinearity from trans-cis photoisomerization of an azo dye in a rigid matrix [J]. Appl. Phys. B, 1997, 64 (4):471-478.

. Sekkat Z, MorichGre D, Dumont M J. Photoisomerization of azobenzene derivatives in polymeric thin films [J]. Appl. Phys., 1992, 71 (3):1543-1545.

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