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中国科学院长春应用化学研究所, 稀土化学与物理开放实验室,吉林 长春,130022
纸质出版日期:2003-1-20,
收稿日期:2002-9-11,
修回日期:2002-11-12,
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于敏, 林君, 周永慧, 逄茂林, 韩秀梅, 王树彬. 溶胶-凝胶法合成Sr<sub>2</sub>CeO<sub>4</sub>及其发光性能的研究[J]. 发光学报, 2003,24(1): 91-94
YU Min, LIN Jun, ZHOU Yong- hui, PANG Mao-lin, HAN Xiu-mei, WANG Shu-bin. Synthesis and Properties of Sr<sub>2</sub>CeO<sub>4</sub> Powder Phosphor by the Sol-gel Method[J]. Chinese Journal of Luminescence, 2003,24(1): 91-94
于敏, 林君, 周永慧, 逄茂林, 韩秀梅, 王树彬. 溶胶-凝胶法合成Sr<sub>2</sub>CeO<sub>4</sub>及其发光性能的研究[J]. 发光学报, 2003,24(1): 91-94 DOI:
YU Min, LIN Jun, ZHOU Yong- hui, PANG Mao-lin, HAN Xiu-mei, WANG Shu-bin. Synthesis and Properties of Sr<sub>2</sub>CeO<sub>4</sub> Powder Phosphor by the Sol-gel Method[J]. Chinese Journal of Luminescence, 2003,24(1): 91-94 DOI:
采用Pechini溶胶凝胶法合成了Sr
2
CeO
4
粉末.利用X射线衍射(XRD)、扫描电镜(SEM)、热重及差热分析(TGDTA)以及发光光谱等测试手段对Sr
2
CeO
4
的结晶过程、发光性质进行了研究.XRD结果表明
用Pechini溶胶 凝胶法合成的样品 800℃时已开始结晶
900℃时可得到三斜晶系的Sr
2
CeO
4
多晶粉末.扫描电镜照片可以看出颗粒大小不均匀
粒径约为1~5μm.发光光谱测试表明Sr
2
CeO
4
粉末的激发光谱是一个宽带双峰结构
分别位于310nm和340nm.这个宽带属于Ce
4+
的电荷迁移带.用340nm激发样品
其发射光谱也是一个宽带
最大峰位于475nm
这个峰属于Ce
4+
的f
→
t1g跃迁.用310nm激发得到的发射光谱与用340nm激发得到的发射光谱相同.
Field emission displays(FEDs)offer the potential of achieving comparable or superior levels of performance to the cathode ray tubes(CRTs). However
FEDs must operate at significantly lower excitation voltages(≤5kV)and higher current densities(10~100A/cm
2
)than that of CRTs. Thus the phosphors for FEDs are required to have a high efficiency at low voltages
high resistance saturation
long service time
and equal or better chromaticity than that of CRT phosphors. For full color flat panel displays
vary satisfactory red and green commercial phosphors are being produced by the f
→
f transitions of Tb
3+
and Eu
3+
but suitable blue phosphors are still lacking
because wide band gap materials are required and the eye sensitivity is quite low in the blue spectra region. Sr
2
CeO
4
is an efficient blue phosphor found by combinatorial method and prepared by the decomposition of carbonates
acetates and oxalates. But these methods always were realized at temperatures above 1000℃ for a period as long as 48h. The sol-gel method
because of its apparent advantages of fine homogeneity
high reactivity of starting materials and lower sintering temperature
is a new route to synthesize fine powders. It has attracted more and more attention. The method was widely used to prepare multicomponent oxides
such as superconductors etc. In this paper
Sr
2
CeO
4
phosphors were prepared by a Pechini sol-gel method via inorganic precursors Sr(NO
3
)
2
and Ce(NO
3
)
3
together with organic chelating agent citric acid and cross-linking agent polyethylene glycol(PEG). X-ray diffraction(XRD)
scanning electron microscope(SEM)
and photoluminescence spectra were used to characterize the Sr
2
CeO
4
phosphors. The results of XRD show that the crystallization of Sr
2
CeO
4
begins at about 800℃
completes around 900℃ with a triclinic structure. SEM studies show that the 900℃ annealed samples are well crystallized
with grain size range from 1μm to 5μm. The excitation spectrum of Sr
2
CeO
4
phosphor displays a broad double peaks band with one around 310nm and the other around 340nm. This broad band is due to the charge transfer(CT)band of the Ce
4+
ion. Excited with a radiation of 340nm
a broad emission band is observed with a peak position at 475nm
and the full width at half maximum(FWHM)of 93nm
the band can be assigned to the f
→
t1g transition of Ce
4+
. The emission spectrum of Sr
2
CeO
4
excited with 310nm radiation is similar to that excited with 340nm radiation.
Pechini溶胶凝胶法发光Sr2CeO4
Pechini sol-gelluminescenceSr2CeO4
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