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北方交通大学, 光电子技术研究所, 信息存储、显示与材料开放研究实验室 北京,100044
纸质出版日期:2003-1-20,
收稿日期:2002-10-15,
修回日期:2002-11-21,
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刘明, 滕枫, 孙世菊, 刘姗姗, 徐征. 共轭聚合物MEH-PPV的固态阴极射线发光[J]. 发光学报, 2003,24(1): 103-106
LIU Ming, TENG Feng, SUN Shi-ju, LIU Shan-shan, XU Zheng. Solid State Cathodoluminescence in Conjugated Polymer MEH-PPV[J]. Chinese Journal of Luminescence, 2003,24(1): 103-106
在有机/无机异质结ZnS/MEHPPV/ZnS器件中
交流驱动条件下
实现了共轭聚合物MEHPPV的固态阴极射线发光
器件的发光光谱与MEHPPV的光致发光谱相同.电子经过ZnS层加速后
成为过热电子
这些过热电子直接碰撞激发MEHPPV而发光.在日光灯照明下
可以看到器件的均匀发光.
From the viewpoint of application electroluminescence(EL)is especially useful in the technology of flat panel display(FPD). Among the six types of emission FPDs
inorganic electroluminesence(IEL)and organic electroluminescence(OEL)are especially promising because of their several attractive characteristics.But there are still some deficiencies in their behavior.The main problem is the lack of blue colored emission in inorganic EL and the lack of electron transport materials and stability in organic EL.But because of the compansatory properties of IEL and OEL
it is quite natural to develop their superiority and to minimize their inferiority.From this analysis
we are convinced that the heterogeneous junction made from organic and inorganic materials as well as the excitation with AC and DC sources may satisfy the above-metioned requirements.In inorganic EL layered optimization has been proposed and investigated carefully.The aim of that structure is to strengthen the effect of electron acceleration in phosphors by spatially separated addition of pure electron acceleration layer to the ordinary IEL layer.But in reality the energy of electrons before entering phosphor layer have already enough value to excite centers of luminescence in the visible region by direct impact excitation.Since these energetic electrons are accelerated not in vacuum but in solids
the luminescence generated by their bombardment is called Solid State CL or CL-like emission.Since ZnS is well known in EL and has also good ability to accelerate electrons
so that in this paper
we prepared the organic/inorganic heterojunction of MEH-PPV under AC electric field excitation which is similar to the photoluminescence of MEH-PPV.By studying the optical characteristics of the device
we found that the emission was induced by direct bombardment of the accelerated electrons from ZnS.So it comes from the solid state cathodoluminescence.
固态阴极射线发光有机/无机异质结聚合物发光
solid state cathodoluminescenceorganic/inorganic heterojunctionpolymer electroluminescence
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