ZHOU Yong-hui, LIN Jun, YU Min, ZHANG Hong-jie. Progress in Luminescent Materials Prepared by Spray Pyrolysis Process[J]. Chinese Journal of Luminescence, 2002,23(5): 503-508
ZHOU Yong-hui, LIN Jun, YU Min, ZHANG Hong-jie. Progress in Luminescent Materials Prepared by Spray Pyrolysis Process[J]. Chinese Journal of Luminescence, 2002,23(5): 503-508DOI:
the morphology and size of materials must be studied and controlled so that the desired objectives of improved powder phosphors can be achieved.It has been pre dicted that the optimum phosphor characteristics can be obtained with particle size on the order of 1μm. For the improved phosphors
the ideal morphology is that of perfect sphere. Spherical morphology is required for high brightness and high resolution. Additionally
high packing densities and low scattering of light can also be obtained by using spherical phosphors. A range of methods has been developed for the preparation of spherical particles. Spray pyrolysis is a newly developed method for the preparation of inorganic functional materials. In general
luminescent materials derived from this method have spherical morphology and fine narrow size distribution. In this method
a misted stream of precursor solution is dried
precipitated
and decomposed in a tubular furnace reactor. Particles produced by spray pyrolysis are relatively uniform in size and composition because of microscale reaction within a droplet and the lack of a milling process. Moreover
various preparation conditions have influence on the characteristics of particles prepared by spray pyrolysis.Therefore
the morphology
composition and size of particles can be controlled for good luminescent characteristics by changing the concentration of solution
spray rate
flowing rate of carrier gas and characteristics of solution. Accordingly
the luminescent intensity of powder phosphors prepared by spray pyrolysis can be improved with the changing of characteristics of particles caused by sintering temperature
morphology and size
crystallization and additive. Despite good luminescent performance
spray pyrolysis method also has a number of advantages such as simplicity of apparatus
low costing and without pollution. In conclusion
spray pyrolysis method can be a hopeful developing direction for preparation of powder phosphors.