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Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass
Synthesis and Properties of Materials | Updated：2022-05-23
|
Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass Enhanced Publication
- Chinese Journal of Luminescence Vol.43, Issue 5, (2022)
- Affiliations：School of Materials and Chemistry, China Jiliang University,Hangzhou,China,310018;School of Optical and Electronic Technology, China Jiliang University,Hangzhou,China,310018;Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences,Shanghai,China,201899;State Key Laboratory of Particle Detection and Electronics, Beijing Institute of High Energy Physics, Chinese Academy of Sciences,Beijing,China,100049
- Author bio：
- Funds：National Natural Science Foundation of China(61505193;11904345;11975220;51972291);Department of Science and Technology of Zhejiang Province(2022C01046);Natural Science Foundation of Zhejiang(LGG22E020001);Opening Project of Key Laboratory of Inorganic Functional Materials and Devices, Chinese Academy of Sciences(KLIFMD201808)
- DOI：10.37188/CJL.20220042 CLC： TQ171
Published：2022-05，
Received：06 February 2022，
Revised：17 February 2022，
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Cite this article
Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass. [J]. Chinese Journal of Luminescence 43(5):691-701(2022)
Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass. [J]. Chinese Journal of Luminescence 43(5):691-701(2022) DOI： 10.37188/CJL.20220042.
Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass Enhanced Publication
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},
{
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"data": "（GAS∶0.5Sn"
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"data": "）玻璃。研究了玻璃的光致发光特性和Sn"
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"name": "sup",
"data": [
{
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]
},
{
"name": "text",
"data": "-Mn"
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{
"name": "sup",
"data": [
{
"name": "text",
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]
},
{
"name": "text",
"data": "能量传递过程。在365 nm激发下，随着Mn"
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"data": [
{
"name": "text",
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{
"name": "text",
"data": "浓度的增加（1.0%，1.5%，2.0%，2.5%，3.0%，3.5%，4.0%），玻璃中Sn"
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"data": [
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{
"name": "text",
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"name": "sup",
"data": [
{
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{
"name": "text",
"data": "的发光强度逐渐增大。Sn"
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{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
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]
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{
"name": "text",
"data": "的衰减时间随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
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]
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{
"name": "text",
"data": "含量的增加而减小，玻璃中产生了Sn"
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{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
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{
"name": "text",
"data": "到Mn"
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{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子的能量传递。GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
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{
"name": "text",
"data": "，"
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{
"name": "italic",
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{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的光致发光量子产率（PLQY）随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "含量的增加而减小，其最大值为25.48%。玻璃中Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子浓度达到4.0%时，其发光属于准白光发射，色坐标为（0.323，0.273）。另外，本文还研究了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂玻璃的发光热猝灭现象，Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心电子跃迁所需克服的热激活能约为0.23 eV。"
}
]
}
]
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"lang": "en",
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"data": [
{
"name": "text",
"data": "The Sn"
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"data": "-Mn"
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"data": " co-doped Gd"
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"data": "2"
}
]
},
{
"name": "text",
"data": "(GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ") glass was prepared by traditional high temperature melt-quenching technology. The photoluminescence properties of the glass and the energy transfer process of Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " were studied. Under 365 nm excitation wavelength, with the increase of Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "content(1.0%, 1.5%, 2.0%, 2.5%, 3.0%, 3.5%, 4.0%), the emission intensity of the Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " center gradually decreases, and the emission intensity of the Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " center gradually increases. Moreover, the decay time of the Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "center decreases with the increase of Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " content, indicating that energy transfer from Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " to Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " ions occurs in the glass. The photoluminescence quantum yield(PLQY) decreases with the increase of Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " content, the maximum of PLQY of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass is 25.48%. When the Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " ions concentration reaches 4.0%, the chromatic coordinate of the glass is (0.323, 0.273), which is close to the standard white light emission. In addition, the thermal quenching behavior of Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " co-doped glass was also studied. The thermal activation energy required to overcome the electronic transition of the Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " emission center is approximately 0.23 eV."
}
]
}
]
}
],
"keyword": [
{
"lang": "zh",
"data": [
[
{
"name": "text",
"data": "铝硅酸盐玻璃"
}
],
[
{
"name": "text",
"data": "Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺"
}
],
[
{
"name": "text",
"data": "能量传递"
}
],
[
{
"name": "text",
"data": "白光发射"
}
]
]
},
{
"lang": "en",
"data": [
[
{
"name": "text",
"data": "aluminum-silicate glass"
}
],
[
{
"name": "text",
"data": "Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " co-doped"
}
],
[
{
"name": "text",
"data": "energy transfer"
}
],
[
{
"name": "text",
"data": "white light emission"
}
]
]
}
],
"highlights": [],
"body": [
{
"name": "sec",
"data": [
{
"name": "sectitle",
"data": {
"label": [
{
"name": "text",
"data": "1"
}
],
"title": [
{
"name": "text",
"data": "引言"
}
],
"level": "1",
"id": "s1"
}
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "近年来，以蓝光(紫外)发光二极管+荧光材料的组合技术在白光LED(W-LED)固态照明、植物生长补光等领域取得了令人瞩目的进步"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "blockXref",
"data": {
"data": [
{
"name": "xref",
"data": {
"text": "1",
"type": "bibr",
"rid": "R1",
"data": [
{
"name": "text",
"data": "1"
}
]
}
},
{
"name": "text",
"data": "-"
},
{
"name": "xref",
"data": {
"text": "2",
"type": "bibr",
"rid": "R2",
"data": [
{
"name": "text",
"data": "2"
}
]
}
}
],
"rid": [
"R1",
"R2"
],
"text": "1-2",
"type": "bibr"
}
},
{
"name": "text",
"data": "］"
}
]
},
{
"name": "text",
"data": "。这些荧光材料的发光离子大多是稀土离子，随着研究的深入，非稀土离子的发光特性越来越引起研究者的关注。在非稀土离子中，"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "n"
}
]
},
{
"name": "text",
"data": "s"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "型("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "n"
}
]
},
{
"name": "text",
"data": "≥5)发光离子(Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "、Sb"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": "、Tl"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "+"
}
]
},
{
"name": "text",
"data": "、Pb"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ")属于宇称允许的选律跃迁，具有较强的发光强度和量子效率"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "blockXref",
"data": {
"data": [
{
"name": "xref",
"data": {
"text": "3",
"type": "bibr",
"rid": "R3",
"data": [
{
"name": "text",
"data": "3"
}
]
}
},
{
"name": "text",
"data": "-"
},
{
"name": "xref",
"data": {
"text": "7",
"type": "bibr",
"rid": "R7",
"data": [
{
"name": "text",
"data": "7"
}
]
}
}
],
"rid": [
"R3",
"R4",
"R5",
"R6",
"R7"
],
"text": "3-7",
"type": "bibr"
}
},
{
"name": "text",
"data": "］"
}
]
},
{
"name": "text",
"data": "。其中由于Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心具有宽发射带，同时Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子的激发光谱与Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子的发射光谱存在重叠，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子常用于共掺，主要源于其光吸收较弱，需要敏化离子，因此可通过加入Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "阳离子来调谐宽带白光性能，近些年来受到了广泛关注"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "4",
"type": "bibr",
"rid": "R4",
"data": [
{
"name": "text",
"data": "4"
}
]
}
},
{
"name": "text",
"data": ","
},
{
"name": "blockXref",
"data": {
"data": [
{
"name": "xref",
"data": {
"text": "8",
"type": "bibr",
"rid": "R8",
"data": [
{
"name": "text",
"data": "8"
}
]
}
},
{
"name": "text",
"data": "-"
},
{
"name": "xref",
"data": {
"text": "15",
"type": "bibr",
"rid": "R15",
"data": [
{
"name": "text",
"data": "15"
}
]
}
}
],
"rid": [
"R8",
"R9",
"R10",
"R11",
"R12",
"R13",
"R14",
"R15"
],
"text": "8-15",
"type": "bibr"
}
},
{
"name": "text",
"data": "］"
}
]
},
{
"name": "text",
"data": "。"
}
]
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "2012年，Zhang等"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "16",
"type": "bibr",
"rid": "R16",
"data": [
{
"name": "text",
"data": "16"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "报道了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂α-Sr"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "P"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "7"
}
]
},
{
"name": "text",
"data": "荧光粉的发光性能，250 nm激发下，该荧光粉表现出冷白色发光，最大能量传递效率为71.16%。2015年，熊晓波等"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "17",
"type": "bibr",
"rid": "R17",
"data": [
{
"name": "text",
"data": "17"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "探究了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂的SrZn"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "(PO"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": ")"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "荧光粉的能量传递机制，判断出该荧光粉中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "→Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递机制主要为四极-四极相互作用。2014年，Masai等"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "9",
"type": "bibr",
"rid": "R9",
"data": [
{
"name": "text",
"data": "9"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "报道了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂ZnO-P"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "5"
}
]
},
{
"name": "text",
"data": "玻璃的光致发光性能，该玻璃在312 nm激发下的发光色坐标为(0.28,0.33)。同年，Lv等"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "18",
"type": "bibr",
"rid": "R18",
"data": [
{
"name": "text",
"data": "18"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "制备了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂的20CaO-50B"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "-30SiO"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "玻璃，该玻璃的能量传递效率达到了92%,305 nm激发下玻璃的色坐标为(0.321,0.238)。2018年，Wang等"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "10",
"type": "bibr",
"rid": "R10",
"data": [
{
"name": "text",
"data": "10"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "报道了Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "掺杂35SnF"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "-35SnO-30P"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "5"
}
]
},
{
"name": "text",
"data": "玻璃的光致发光性能，该玻璃在365 nm激发下的色坐标为(0.353,0.368)。这些发光材料在紫外激发下表现出较好的白光发射性能。由于Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "等非稀土发光离子的发光性能容易受到荧光材料局域环境影响，而目前已研究的荧光玻璃基质大多是磷酸盐玻璃基质，还没有关于Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂铝硅酸盐玻璃白光发射特性的报道。"
}
]
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "铝硅酸盐玻璃具有良好的热稳定性、优异的化学耐久性，在紫外和可见光区域有较高的透明度。与磷酸盐玻璃和硼酸盐玻璃相比，铝硅酸盐玻璃具有更好的物理和化学稳定性，稀土氧化物可以增加玻璃的密度而有利于潜在的闪烁发光应用"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "19",
"type": "bibr",
"rid": "R19",
"data": [
{
"name": "text",
"data": "19"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。本文选用稀土铝硅酸盐玻璃作为玻璃基质，研究了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂的Gd"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "-Al"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "-SiO"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "玻璃的荧光特性、Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递过程及相互作用机制，通过调整Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "和Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的浓度比例获得了较好的白光发射，并且探究了玻璃的发光热猝灭行为。"
}
]
}
]
},
{
"name": "sec",
"data": [
{
"name": "sectitle",
"data": {
"label": [
{
"name": "text",
"data": "2"
}
],
"title": [
{
"name": "text",
"data": "实验与表征"
}
],
"level": "1",
"id": "s2"
}
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "按照氧化物的量比精确配料，以氧化钆、硝酸铝、正硅酸乙酯为原料，用无水乙醇、硝酸、去离子水溶解，经80 ℃恒温磁力搅拌器加热搅拌成溶胶凝胶；将溶胶凝胶在 100 ℃恒温烘干24 h后放入高温炉，在500 ℃下煅烧2 h研磨成粉得到20Gd"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "-20Al"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "-60SiO"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "玻璃前驱体粉末。将前驱体粉末与SnC"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "、MnC"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "、Si"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "N"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "置于刚玉坩埚中混合并搅拌均匀。在1 400 ℃、大气气氛下熔化，并保温3 h，随后自然冷却得到玻璃"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "blockXref",
"data": {
"data": [
{
"name": "xref",
"data": {
"text": "19",
"type": "bibr",
"rid": "R19",
"data": [
{
"name": "text",
"data": "19"
}
]
}
},
{
"name": "text",
"data": "-"
},
{
"name": "xref",
"data": {
"text": "20",
"type": "bibr",
"rid": "R20",
"data": [
{
"name": "text",
"data": "20"
}
]
}
}
],
"rid": [
"R19",
"R20"
],
"text": "19-20",
"type": "bibr"
}
},
{
"name": "text",
"data": "］"
}
]
},
{
"name": "text",
"data": "。经过机械抛光得到GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=0,1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)玻璃样品。由于原料中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "、Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "在玻璃的高温制备过程中易被氧化成高价态，根据玻璃制备过程中Si"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "N"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "还原机理"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "21",
"type": "bibr",
"rid": "R21",
"data": [
{
"name": "text",
"data": "21"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "，本文通过加入Si"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "N"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "来抑制高温制备过程中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "、Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的氧化。"
}
]
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "通过紫外-可见分光光度计(UV2600,SDPTOP)在200~900 nm范围内测量玻璃的吸收光谱。使用荧光分光光度计(F"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "97pro"
}
]
},
{
"name": "text",
"data": "，上海棱光)测量玻璃光致发光的激发和发射光谱。通过瞬态稳态荧光分光光度计(FLS-1000，爱丁堡)测量玻璃的光致发光量子产率(PLQY)"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "η"
}
]
},
{
"name": "text",
"data": "。"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "η"
}
]
},
{
"name": "text",
"data": "表征荧光材料将吸收的激发光转化为发射光的能力，通过下列公式计算玻璃的"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "η"
}
]
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "22",
"type": "bibr",
"rid": "R22",
"data": [
{
"name": "text",
"data": "22"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": ":"
},
{
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"label": [
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{
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"data": "其中"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "ε"
}
]
},
{
"name": "text",
"data": "是样品发射的光子，"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "α"
}
]
},
{
"name": "text",
"data": "是样品吸收的光子。"
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{
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"data": [
{
"name": "text",
"data": "emission"
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]
},
{
"name": "text",
"data": "是样品的发射光子数，"
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{
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"data": [
{
"name": "text",
"data": "solvet"
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]
},
{
"name": "text",
"data": "是积分球中存在的激发光子数，"
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"data": "sample"
}
]
},
{
"name": "text",
"data": "是样品中未吸收的激发光子数。"
}
]
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "通过荧光分光光度计(QM8075-11,Horiba)测试光致发光的衰减时间。使用荧光分光光度计(F-4600,HITACH)和高温荧光控制器(TAP-02,Orient KOJI)测试了玻璃的热猝灭行为。"
}
]
}
]
},
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"data": {
"label": [
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"title": [
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"data": "结果与讨论"
}
],
"level": "1",
"id": "s3"
}
},
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"data": [
{
"name": "sectitle",
"data": {
"label": [
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"title": [
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"data": "吸收光谱"
}
],
"level": "2",
"id": "s3a"
}
},
{
"name": "p",
"data": [
{
"name": "xref",
"data": {
"text": "图1(a)",
"type": "fig",
"rid": "F1",
"data": [
{
"name": "text",
"data": "图1(a)"
}
]
}
},
{
"name": "text",
"data": "为不同Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "含量的GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=0,1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)玻璃和GAS玻璃基质的吸收光谱。由于Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子宇称允许的选律跃迁导致玻璃产生强烈的吸收，玻璃的光学吸收边出现明显的红移，因此我们认为玻璃中可能形成了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心。"
},
{
"name": "xref",
"data": {
"text": "图1(b)",
"type": "fig",
"rid": "F1",
"data": [
{
"name": "text",
"data": "图1(b)"
}
]
}
},
{
"name": "text",
"data": "是GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的光学吸收边，随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "掺杂浓度的增加，玻璃的光学吸收边从320 nm红移至350 nm，表明玻璃的光学吸收边受到Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子掺杂浓度的影响，这种趋势与Masai报道的Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂的ZnO-P"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "5"
}
]
},
{
"name": "text",
"data": "玻璃相同，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子影响了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的局部配位场"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "14",
"type": "bibr",
"rid": "R14",
"data": [
{
"name": "text",
"data": "14"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。锰元素在玻璃中主要以Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "或Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": "存在"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "11",
"type": "bibr",
"rid": "R11",
"data": [
{
"name": "text",
"data": "11"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "，在"
},
{
"name": "xref",
"data": {
"text": "图1(a)",
"type": "fig",
"rid": "F1",
"data": [
{
"name": "text",
"data": "图1(a)"
}
]
}
},
{
"name": "text",
"data": "测试范围内没有Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": "的吸收带(550 nm附近，"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "5"
}
]
},
{
"name": "text",
"data": "E"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "g"
}
]
},
{
"name": "text",
"data": "→"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "5"
}
]
},
{
"name": "text",
"data": "T"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2g"
}
]
},
{
"name": "text",
"data": "跃迁"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "23",
"type": "bibr",
"rid": "R23",
"data": [
{
"name": "text",
"data": "23"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": ")，表明在玻璃中几乎不存在Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": "离子。Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子的"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "(S)→["
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "(4G),"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "E(4G)]跃迁在420 nm左右表现出弱吸收特性"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "23",
"type": "bibr",
"rid": "R23",
"data": [
{
"name": "text",
"data": "23"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。玻璃在310 nm附近存在弱吸收峰，这是Gd"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": "的"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "8"
}
]
},
{
"name": "text",
"data": "S"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "7/2"
}
]
},
{
"name": "text",
"data": "→"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "P"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "7/2"
}
]
},
{
"name": "text",
"data": "和"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "8"
}
]
},
{
"name": "text",
"data": "S"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "7/2"
}
]
},
{
"name": "text",
"data": "→"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "P"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "5/2"
}
]
},
{
"name": "text",
"data": "跃迁"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "24",
"type": "bibr",
"rid": "R24",
"data": [
{
"name": "text",
"data": "24"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。另外，玻璃基质在250~280 nm附近还存在几个吸收峰，是Gd"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": "的"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "8"
}
]
},
{
"name": "text",
"data": "S"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "7/2"
}
]
},
{
"name": "text",
"data": "→"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "I"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "跃迁"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "25",
"type": "bibr",
"rid": "R25",
"data": [
{
"name": "text",
"data": "25"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。"
},
{
"name": "xref",
"data": {
"text": "图1(c)",
"type": "fig",
"rid": "F1",
"data": [
{
"name": "text",
"data": "图1(c)"
}
]
}
},
{
"name": "text",
"data": " 所示是GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "以及基质玻璃的透射光谱，可以看出玻璃的结构是无定形的，玻璃的透过率均在60%~70%之间。"
}
]
},
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"data": {
"id": "F1",
"caption": [
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"lang": "zh",
"label": [
{
"name": "text",
"data": "图1"
}
],
"title": [
{
"name": "text",
"data": "GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的归一化吸收光谱(a)、光学吸收边(b)、透射光谱(c)("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=0,1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)。"
}
]
},
{
"lang": "en",
"label": [
{
"name": "text",
"data": "Fig. 1"
}
],
"title": [
{
"name": "text",
"data": "Normalized absorption spectra(a), optical absorption edge(b), transmission spectra(c) of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=0, 1.0%, 1.5%, 2.0%, 2.5%, 3.0%, 3.5%, 4.0%)."
}
]
}
],
"subcaption": [],
"note": [],
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"title": [
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"name": "text",
"data": "光致发光发射光谱"
}
],
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}
},
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"data": [
{
"name": "xref",
"data": {
"text": "图2(a)",
"type": "fig",
"rid": "F2",
"data": [
{
"name": "text",
"data": "图2(a)"
}
]
}
},
{
"name": "text",
"data": "是GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的三维发光图，清楚地表明玻璃中存在两种不同类型的发光，发射峰分别位于440 nm和630 nm附近。"
},
{
"name": "xref",
"data": {
"text": "图2(b)",
"type": "fig",
"rid": "F2",
"data": [
{
"name": "text",
"data": "图2(b)"
}
]
}
},
{
"name": "text",
"data": "是GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的光致发光(PL)发射光谱，激发波长为365 nm，对应于Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心的激发峰。Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的发光位于450 nm附近，随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "掺杂浓度的增加，其发光强度降低。而在630 nm附近的Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光强度逐渐增大。"
},
{
"name": "xref",
"data": {
"text": "图2(c)",
"type": "fig",
"rid": "F2",
"data": [
{
"name": "text",
"data": "图2(c)"
}
]
}
},
{
"name": "text",
"data": "为GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的归一化光致发光发射光谱，通过计算发现Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心的发射峰与发射带的半高全宽(FWHM)变化不大。"
},
{
"name": "xref",
"data": {
"text": "图2(d)",
"type": "fig",
"rid": "F2",
"data": [
{
"name": "text",
"data": "图2(d)"
}
]
}
},
{
"name": "text",
"data": "是GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃在630 nm监测下的归一化激发光谱，随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "浓度的增加，玻璃的激发峰位置与半高全宽几乎不发生变化。说明Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "并不会影响Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心与发射相关的能级"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "11",
"type": "bibr",
"rid": "R11",
"data": [
{
"name": "text",
"data": "11"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。"
}
]
},
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"name": "fig",
"data": {
"id": "F2",
"caption": [
{
"lang": "zh",
"label": [
{
"name": "text",
"data": "图2"
}
],
"title": [
{
"name": "text",
"data": "(a)GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的三维发光图；GAS∶0.5Sn"
},
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"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
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"name": "italic",
"data": [
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"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的发射光谱(b)、归一化发射光谱(c)、激发光谱(d)("
},
{
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"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)。"
}
]
},
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"label": [
{
"name": "text",
"data": "Fig. 2"
}
],
"title": [
{
"name": "text",
"data": "(a)Contour plots of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass. PL spectra(b), normalized PL spectra(b), PL excitation spectra(d) of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=1.0%, 1.5%, 2.0%, 2.5%, 3.0%, 3.5%, 4.0%)."
}
]
}
],
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"note": [],
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"data": {
"text": "图3(a)",
"type": "fig",
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"data": [
{
"name": "text",
"data": "图3(a)"
}
]
}
},
{
"name": "text",
"data": "比较了GAS∶Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "和GAS∶Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的激发和发射光谱，可以发现Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "激发光谱中的"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "→["
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "(4G),"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "E(4G)]、"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "→"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "T"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "(4G)和"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "→"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "T"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "(4G)跃迁与激发波长为365 nm的GAS∶Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的发射带之间有部分光谱重叠。因此，可以预计GAS∶"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "x"
}
]
},
{
"name": "text",
"data": "Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃中存在Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递。"
},
{
"name": "xref",
"data": {
"text": "图3(b)",
"type": "fig",
"rid": "F3",
"data": [
{
"name": "text",
"data": "图3(b)"
}
]
}
},
{
"name": "text",
"data": "为GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的能量传递示意图，揭示了玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "→Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "可能存在的能量传递过程：Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "从激发态无辐射跃迁至基态，并将能量传递给邻近的Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子，使Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "从"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "(S)基态激发到不同的激发能级，激发能级上的Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子经过多声子弛豫，最后通过辐射跃迁回到"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "6"
}
]
},
{
"name": "text",
"data": "A"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1"
}
]
},
{
"name": "text",
"data": "(S)基态，发射出Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的红光"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "18",
"type": "bibr",
"rid": "R18",
"data": [
{
"name": "text",
"data": "18"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。此外，随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子含量的增加，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的发射峰逐渐红移。这是因为随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子含量的增加，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的距离减小，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "与Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "周围配位场的相互作用增强，使Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的激发态接近基态，最后产生长波长的发射"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "26",
"type": "bibr",
"rid": "R26",
"data": [
{
"name": "text",
"data": "26"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。"
}
]
},
{
"name": "fig",
"data": {
"id": "F3",
"caption": [
{
"lang": "zh",
"label": [
{
"name": "text",
"data": "图3"
}
],
"title": [
{
"name": "text",
"data": "(a)GAS∶1.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "和GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的激发和发射光谱；(b)GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的能量传递示意图。"
}
]
},
{
"lang": "en",
"label": [
{
"name": "text",
"data": "Fig. 3"
}
],
"title": [
{
"name": "text",
"data": "(a)Excitation and emission spectra of GAS∶1.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " and GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass. (b)Schematic diagram of energy transfer of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass."
}
]
}
],
"subcaption": [],
"note": [],
"graphics": [
{
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{
"name": "sec",
"data": [
{
"name": "sectitle",
"data": {
"label": [
{
"name": "text",
"data": "3.3"
}
],
"title": [
{
"name": "text",
"data": "CIE色坐标"
}
],
"level": "2",
"id": "s3c"
}
},
{
"name": "p",
"data": [
{
"name": "xref",
"data": {
"text": "图4",
"type": "fig",
"rid": "F4",
"data": [
{
"name": "text",
"data": "图4"
}
]
}
},
{
"name": "text",
"data": "所示是GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=0, 1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)玻璃的照片以及玻璃在365 nm紫外激发下的照片。随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "掺杂浓度的增加，玻璃的发光由蓝至红连续变化，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "浓度大于2.5%时，玻璃产生准白光发射。"
},
{
"name": "xref",
"data": {
"text": "图5",
"type": "fig",
"rid": "F5",
"data": [
{
"name": "text",
"data": "图5"
}
]
}
},
{
"name": "text",
"data": "显示了GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的色坐标配位图。样品的组分与色坐标如"
},
{
"name": "xref",
"data": {
"text": "表1",
"type": "table",
"rid": "T1",
"data": [
{
"name": "text",
"data": "表1"
}
]
}
},
{
"name": "text",
"data": "所示。通过添加Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "，玻璃的色坐标从蓝色到红色连续变化。"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=4.0时，玻璃的色坐标为(0.323,0.273)，接近准白光发射。另外，玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的发射峰在440 nm附近，不需要额外的蓝色荧光粉提高其显色性，这也是目前Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "掺杂发光玻璃的一个显著优势"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "12",
"type": "bibr",
"rid": "R12",
"data": [
{
"name": "text",
"data": "12"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。因此，GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂玻璃材料在W-LED中具有潜在的应用前景。"
}
]
},
{
"name": "fig",
"data": {
"id": "F4",
"caption": [
{
"lang": "zh",
"label": [
{
"name": "text",
"data": "图4"
}
],
"title": [
{
"name": "text",
"data": "GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的常规状态(a)以及365 nm激发下的照片(b)("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "= 0,1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)"
}
]
},
{
"lang": "en",
"label": [
{
"name": "text",
"data": "Fig. 4"
}
],
"title": [
{
"name": "text",
"data": "Photos of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass under conventional state(a) and excitation at 365 nm(b)("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "= 0, 1.0%, 1.5%, 2.0%, 2.5%, 3.0%, 3.5%, 4.0%)"
}
]
}
],
"subcaption": [],
"note": [],
"graphics": [
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"caption": [
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"lang": "zh",
"label": [
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"data": "图5"
}
],
"title": [
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"name": "text",
"data": "GAS∶0.5Sn"
},
{
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"data": [
{
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"data": "2+"
}
]
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{
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}
]
}
]
},
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}
]
},
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},
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},
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}
]
}
]
},
{
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"data": "17.52"
}
]
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"data": [
{
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"data": "This work"
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[
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}
]
},
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"data": ",3.0Mn"
},
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"data": [
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"data": "2+"
}
]
}
]
},
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"data": "15.85"
}
]
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"data": "This work"
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"data": "GAS∶0.5Sn"
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"data": [
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"data": "2+"
}
]
},
{
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"data": ",3.5Mn"
},
{
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"data": [
{
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"data": "2+"
}
]
}
]
},
{
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"data": [
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"data": "14.61"
}
]
},
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"rowspan": "1",
"align": "center",
"data": [
{
"name": "text",
"data": "This work"
}
]
}
],
[
{
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"rowspan": "1",
"align": "center",
"data": [
{
"name": "text",
"data": "GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
}
]
},
{
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"data": [
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"data": "13.79"
}
]
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"data": "This work"
}
]
}
],
[
{
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"data": [
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"name": "text",
"data": "YAG∶Ce"
},
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"data": [
{
"name": "text",
"data": "3+"
}
]
}
]
},
{
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"data": "88.56"
}
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"data": [
{
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"data": "This work as standard sample"
}
]
}
],
[
{
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"data": [
{
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"data": "α-Sr"
},
{
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"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "P"
},
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"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "7"
}
]
},
{
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"data": "∶Sn"
},
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"data": [
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"data": "2+"
}
]
},
{
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"data": ",Mn"
},
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{
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"data": "2+"
}
]
}
]
},
{
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"data": [
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"data": "56"
}
]
},
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"data": [
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"data": "["
},
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"data": {
"text": "16",
"type": "bibr",
"rid": "R16",
"data": [
{
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"data": "16"
}
]
}
},
{
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}
]
}
],
[
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"data": "FPG glass∶Sn"
},
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"data": [
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"data": "2+"
}
]
},
{
"name": "text",
"data": ",Dy"
},
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{
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"data": "3+"
}
]
}
]
},
{
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"align": "center",
"style": "border-bottom:1px solid #000;",
"data": [
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"data": "56.3"
}
]
},
{
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"align": "center",
"style": "border-bottom:1px solid #000;",
"data": [
{
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"data": "["
},
{
"name": "xref",
"data": {
"text": "27",
"type": "bibr",
"rid": "R27",
"data": [
{
"name": "text",
"data": "27"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
}
]
],
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}
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}
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"type": "fig",
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"data": "图6"
}
]
}
},
{
"name": "text",
"data": "所示为激发波长为365 nm、监测发射波长为455 nm时GAS∶0.5Sn"
},
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"data": "2+"
}
]
},
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"data": ","
},
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"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
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"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃中Sn"
},
{
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"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心的PL衰减时间曲线。衰减时间曲线表明，加入Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子后，Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的衰减时间随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "含量的增加而减小。Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心的PL发射强度和衰减时间的减小清楚地表明在光致发光过程中从Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心的能量传递(ET)。为了定量讨论，发射过程中的ET效率("
},
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{
"name": "text",
"data": "η"
}
]
},
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"data": [
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"data": "ET"
}
]
},
{
"name": "text",
"data": ")由下式给出"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "12",
"type": "bibr",
"rid": "R12",
"data": [
{
"name": "text",
"data": "12"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
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"name": "text",
"data": ":"
},
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"data": "(2)"
}
],
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{
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"data": "其中"
},
{
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"data": [
{
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"data": "τ"
}
]
},
{
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"data": [
{
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"data": "DA"
}
]
},
{
"name": "text",
"data": "和"
},
{
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"data": [
{
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"data": "τ"
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]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "D"
}
]
},
{
"name": "text",
"data": "分别是具有和不具有激活剂Mn"
},
{
"name": "sup",
"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": "阳离子的Sn"
},
{
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"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": "中心的衰减时间。"
},
{
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"data": {
"text": "表1",
"type": "table",
"rid": "T1",
"data": [
{
"name": "text",
"data": "表1"
}
]
}
},
{
"name": "text",
"data": "显示了不同GAS∶0.5Sn"
},
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"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心的衰减时间数值和能量传递效率。"
}
]
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"label": [
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],
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"data": "GAS∶0.5Sn"
},
{
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"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
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"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的衰减时间曲线("
},
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"data": [
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"data": "y"
}
]
},
{
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"data": "=0, 1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)"
}
]
},
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"label": [
{
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"data": "Fig. 6"
}
],
"title": [
{
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"data": "Decay time curves of GAS∶0.5Sn"
},
{
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"data": [
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"data": "2+"
}
]
},
{
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"data": ","
},
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"data": [
{
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"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
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"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": " glass("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=0, 1.0%, 1.5%, 2.0%, 2.5%, 3.0%, 3.5%, 4.0%)"
}
]
}
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"data": {
"text": "图7(a)",
"type": "fig",
"rid": "F7",
"data": [
{
"name": "text",
"data": "图7(a)"
}
]
}
},
{
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"data": "显示了GAS∶0.5Sn"
},
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{
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"data": "2+"
}
]
},
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"data": ","
},
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"data": [
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]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心的衰减时间和ET效率的函数关系。随着Mn"
},
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"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": "含量的增加，ET效率逐渐增加。当Mn"
},
{
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"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "含量大于4.0%时，ET效率超过25%。"
},
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"data": {
"text": "图7(b)",
"type": "fig",
"rid": "F7",
"data": [
{
"name": "text",
"data": "图7(b)"
}
]
}
},
{
"name": "text",
"data": "显示了Mn"
},
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"data": [
{
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"data": "2+"
}
]
},
{
"name": "text",
"data": "/Sn"
},
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"data": [
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"data": "2+"
}
]
},
{
"name": "text",
"data": "比与ET效率的函数关系，它表明敏化剂与激活剂之间的距离缩短了。由于"
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"data": "ET"
}
]
},
{
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"data": "值取决于Sn"
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}
]
},
{
"name": "text",
"data": "/Mn"
},
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"data": [
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"data": "2+"
}
]
},
{
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"data": "比，但是该玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "→Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递效率不高(与之相比，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂的ZnO-P"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "5"
}
]
},
{
"name": "text",
"data": "玻璃的能量传递效率超过90%"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "11",
"type": "bibr",
"rid": "R11",
"data": [
{
"name": "text",
"data": "11"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": ")，因此我们认为GAS玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "和Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心几乎均匀地分散在玻璃中，并未形成Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "簇状结构"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "14",
"type": "bibr",
"rid": "R14",
"data": [
{
"name": "text",
"data": "14"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。"
}
]
},
{
"name": "fig",
"data": {
"id": "F7",
"caption": [
{
"lang": "zh",
"label": [
{
"name": "text",
"data": "图7"
}
],
"title": [
{
"name": "text",
"data": "GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的衰减时间与能量传递效率的关系(a)、Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "与Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "比率与能量传递效率的关系(b)("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%)。"
}
]
},
{
"lang": "en",
"label": [
{
"name": "text",
"data": "Fig. 7"
}
],
"title": [
{
"name": "text",
"data": "Relationship between decay time and energy transfer efficiency(a), Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " and Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " ratio and energy transfer efficiency(b) of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "=1.0%, 1.5%, 2.0%, 2.5%, 3.0%, 3.5%, 4.0%)."
}
]
}
],
"subcaption": [],
"note": [],
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"label": [
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"data": "3.6"
}
],
"title": [
{
"name": "text",
"data": "能量传递机制"
}
],
"level": "2",
"id": "s3f"
}
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "在交换相互作用或者多级相互作用中，有Dexter的敏化剂与激活剂之间的能量传递公式"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "28",
"type": "bibr",
"rid": "R28",
"data": [
{
"name": "text",
"data": "28"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "，即："
},
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"label": [
{
"name": "text",
"data": "(3)"
}
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},
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"data": {
"label": [
{
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"data": "(4)"
}
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"data": [
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},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "I"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "Sn0"
}
]
},
{
"name": "text",
"data": "是单掺Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的积分强度，"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "I"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "Sn"
}
]
},
{
"name": "text",
"data": "是Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "部分的积分强度，"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "C"
}
]
},
{
"name": "text",
"data": "是Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的浓度。公式(3)对应了交换相互作用，而公式(4)中"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "α"
}
]
},
{
"name": "text",
"data": "=6,8,10，分别对应偶极-偶极相互作用、偶极-四极相互作用和四极-四极相互作用。"
}
]
},
{
"name": "p",
"data": [
{
"name": "xref",
"data": {
"text": "图8",
"type": "fig",
"rid": "F8",
"data": [
{
"name": "text",
"data": "图8"
}
]
}
},
{
"name": "text",
"data": "给出了ln"
},
{
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"data": [
{
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},
{
"name": "text",
"data": "对"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "C"
}
]
},
{
"name": "text",
"data": "以及"
},
{
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},
{
"name": "text",
"data": "对"
},
{
"name": "inlineformula",
"data": [
{
"name": "math",
"data": {
"graphicsData": {
"print": "http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=28019929&type=",
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]
},
{
"name": "text",
"data": "的实际计算值和拟合曲线。"
},
{
"name": "xref",
"data": {
"text": "图8(a)、(b)",
"type": "fig",
"rid": "F8",
"data": [
{
"name": "text",
"data": "图8(a)、(b)"
}
]
}
},
{
"name": "text",
"data": "的拟合曲线为直线，"
},
{
"name": "xref",
"data": {
"text": "图8(c)",
"type": "fig",
"rid": "F8",
"data": [
{
"name": "text",
"data": "图8(c)"
}
]
}
},
{
"name": "text",
"data": "的拟合曲线接近直线。这说明从Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递机制有可能是通过交换相互作用、偶极-偶极相互作用或偶极-四极相互作用进行的。根据Dexter公式"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "29",
"type": "bibr",
"rid": "R29",
"data": [
{
"name": "text",
"data": "29"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": ":"
},
{
"name": "dispformula",
"data": {
"label": [
{
"name": "text",
"data": "(5)"
}
],
"data": [
{
"name": "math",
"data": {
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],
"id": "DF5"
}
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "R"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "C"
}
]
},
{
"name": "text",
"data": "表示敏化剂到激活剂能量传递的距离；"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "λ"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "S"
}
]
},
{
"name": "text",
"data": "是敏化剂Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的发射波长；"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "P"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "A"
}
]
},
{
"name": "text",
"data": "是Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子的光吸收跃迁振子强度，在此取为10"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "-10"
}
]
},
{
"name": "text",
"data": ";"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "S"
}
]
},
{
"name": "text",
"data": "为敏化剂Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的发射能量；"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "F"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "s"
}
]
},
{
"name": "text",
"data": "("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "text",
"data": ")和"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "F"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "A"
}
]
},
{
"name": "text",
"data": "("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "text",
"data": ")分别表示敏化剂的发射光谱和激活剂的激发光谱能量归一化后的函数，即1。通过公式计算"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "R"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "C"
}
]
},
{
"name": "text",
"data": "为0.56 nm，由此可知在Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递过程中，偶极-偶极相互作用起主要作用"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "30",
"type": "bibr",
"rid": "R30",
"data": [
{
"name": "text",
"data": "30"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。由于极高的能量传递效率，Masai等认为磷酸盐玻璃中交换相互作用在Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递过程中起重要作用"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "14",
"type": "bibr",
"rid": "R14",
"data": [
{
"name": "text",
"data": "14"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。另外，Masai研究了Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到稀土离子("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "RE"
}
]
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": ")的能量传递过程，同样认为交换相互作用起主要作用"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "31",
"type": "bibr",
"rid": "R31",
"data": [
{
"name": "text",
"data": "31"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "。"
}
]
},
{
"name": "fig",
"data": {
"id": "F8",
"caption": [
{
"lang": "zh",
"label": [
{
"name": "text",
"data": "图8"
}
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"data": "I"
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"data": "Fig. 8"
}
],
"title": [
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"data": ") "
},
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{
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"data": "vs"
}
]
},
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"data": " "
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"data": "Sn0"
}
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},
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"data": " ions."
}
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}
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"title": [
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}
],
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}
},
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"data": [
{
"name": "text",
"data": "通常白光LED由于大功率应用会导致温度升高，造成发光强度降低或波长漂移的现象"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "20",
"type": "bibr",
"rid": "R20",
"data": [
{
"name": "text",
"data": "20"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "，因此荧光材料需要保持在一定温度下的发光稳定性。"
},
{
"name": "xref",
"data": {
"text": "图9",
"type": "fig",
"rid": "F9",
"data": [
{
"name": "text",
"data": "图9"
}
]
}
},
{
"name": "text",
"data": "是GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",3.5Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "与GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃在30~250 ℃温度范围内随温度变化的发射光谱。在365 nm激发下，随着温度升高，玻璃的整体发射强度逐渐降低。在210 ℃时，GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",3.5Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "与GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的发光强度分别是室温下的37.20%和37.28%。另外，随着温度升高，玻璃的色坐标几乎没有发生变化，说明该玻璃的热猝灭行为不会影响Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "→Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递过程。"
}
]
},
{
"name": "fig",
"data": {
"id": "F9",
"caption": [
{
"lang": "zh",
"label": [
{
"name": "text",
"data": "图9"
}
],
"title": [
{
"name": "text",
"data": "365 nm激发下，GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",3.5Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃(a)与GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃(b)的变温发射光谱(303.15~523.15 K)。"
}
]
},
{
"lang": "en",
"label": [
{
"name": "text",
"data": "Fig. 9"
}
],
"title": [
{
"name": "text",
"data": "Variable temperature emission spectra of GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",3.5Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass(a), GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": " glass(b) under excitation at 365 nm(303.15-523.15 K)."
}
]
}
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"data": [
{
"name": "text",
"data": "根据Arrhenius公式"
},
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"data": [
{
"name": "text",
"data": "["
},
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"data": {
"text": "32",
"type": "bibr",
"rid": "R32",
"data": [
{
"name": "text",
"data": "32"
}
]
}
},
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}
]
},
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"data": "，荧光光谱发光强度与温度的关系由下述公式表示："
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{
"name": "text",
"data": "其中"
},
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"data": [
{
"name": "text",
"data": "k"
}
]
},
{
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"data": [
{
"name": "text",
"data": "B"
}
]
},
{
"name": "text",
"data": "为玻尔兹曼常数(8.617×10"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "-5"
}
]
},
{
"name": "text",
"data": " eV/K),"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "I"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "0"
}
]
},
{
"name": "text",
"data": "为室温下玻璃的发光强度，"
},
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"data": [
{
"name": "text",
"data": "I"
}
]
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "("
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "T"
}
]
},
{
"name": "text",
"data": ")"
}
]
},
{
"name": "text",
"data": "为不同温度下玻璃的发光强度，Δ"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "text",
"data": "为Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心电子跃迁所需克服的热激活能，"
},
{
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"data": [
{
"name": "text",
"data": "A"
}
]
},
{
"name": "text",
"data": "为常数。以 "
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"name": "text",
"data": "为横坐标拟合得到"
},
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"data": {
"text": "图10",
"type": "fig",
"rid": "F10",
"data": [
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"name": "text",
"data": "图10"
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},
{
"name": "text",
"data": "，斜率即为"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "A"
}
]
},
{
"name": "text",
"data": "*Δ"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "text",
"data": "，再通过MATLAB拟合得到玻璃的常数"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "A"
}
]
},
{
"name": "text",
"data": "与热激活能Δ"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "text",
"data": "的值。"
},
{
"name": "xref",
"data": {
"text": "表3",
"type": "table",
"rid": "T3",
"data": [
{
"name": "text",
"data": "表3"
}
]
}
},
{
"name": "text",
"data": "为拟合后得到的玻璃常数"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "A"
}
]
},
{
"name": "text",
"data": "与热激活能Δ"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "text",
"data": "的值，可知GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",3.5Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "与GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心电子跃迁所需克服的热激活能约为0.227 eV和0.245 eV。即当环境温度升高时，Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心的电子获得的热激活能如果大于该能量时，就能到达"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3"
}
]
},
{
"name": "text",
"data": "P能级与电荷迁移态的交点处以无辐射跃迁的形式回到基态。通常来说，热激活能越大，材料的热稳定性越好。GAS玻璃的热激活能高于氮氧化物荧光材料(Li"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "CaSi"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "N"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "∶0.05Ce"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": ")，与硅酸盐荧光材料(Ba"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "0.4"
}
]
},
{
"name": "text",
"data": "Sr"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "1.4"
}
]
},
{
"name": "text",
"data": "SiO"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "4"
}
]
},
{
"name": "text",
"data": "∶0.1Ce"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "3+"
}
]
},
{
"name": "text",
"data": ",0.1Na"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "+"
}
]
},
{
"name": "text",
"data": ")相当"
},
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"data": [
{
"name": "text",
"data": "["
},
{
"name": "xref",
"data": {
"text": "33",
"type": "bibr",
"rid": "R33",
"data": [
{
"name": "text",
"data": "33"
}
]
}
},
{
"name": "text",
"data": "]"
}
]
},
{
"name": "text",
"data": "，在W-LED中具有潜在的应用前景。"
}
]
},
{
"name": "fig",
"data": {
"id": "F10",
"caption": [
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"lang": "zh",
"label": [
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],
"title": [
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"data": "GAS∶0.5Sn"
},
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"name": "sup",
"data": [
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}
]
},
{
"name": "text",
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},
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]
},
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"data": "玻璃(a)、GAS∶0.5Sn"
},
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}
]
},
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},
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{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃(b)的激活能线性拟合曲线。"
}
]
},
{
"lang": "en",
"label": [
{
"name": "text",
"data": "Fig. 10"
}
],
"title": [
{
"name": "text",
"data": "Thermal activation energy linear fitting curve of GAS∶0.5Sn"
},
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"data": [
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}
]
},
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},
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{
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}
]
},
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"name": "text",
"data": " glass(a) and GAS∶0.5Sn"
},
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"data": "2+"
}
]
},
{
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"data": ",4.0Mn"
},
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"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
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"name": "text",
"data": " glass(b)"
}
]
}
],
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"data": "MATLAB拟合GAS∶0.5Sn"
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]
},
{
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"data": "玻璃后的"
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"data": "A"
}
]
},
{
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},
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"data": [
{
"name": "text",
"data": "E"
}
]
},
{
"name": "text",
"data": "值"
}
]
},
{
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"label": [
{
"name": "text",
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}
],
"title": [
{
"name": "text",
"data": "The data of "
},
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"data": [
{
"name": "text",
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}
]
},
{
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"data": ", Δ"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "E"
}
]
},
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"data": " of GAS∶0.5Sn"
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}
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},
{
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},
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]
},
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"data": " glass obtained by MATLAB fitting"
}
]
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],
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}
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}
]
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},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "BaCa(PO"
},
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"name": "sub",
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{
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"data": "4"
}
]
},
{
"name": "text",
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},
{
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"data": "2+ ["
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}
]
},
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"name": "text",
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}
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"data": [
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"name": "text",
"data": "本文通过传统的高温熔融淬火法制备了Sn"
},
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}
]
},
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"data": "-Mn"
},
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"data": [
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}
]
},
{
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"data": "共掺杂Gd"
},
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"data": [
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"data": "2"
}
]
},
{
"name": "text",
"data": "O"
},
{
"name": "sub",
"data": [
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"data": "3"
}
]
},
{
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"data": "-Al"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "O"
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]
},
{
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"data": "-SiO"
},
{
"name": "sub",
"data": [
{
"name": "text",
"data": "2"
}
]
},
{
"name": "text",
"data": "玻璃。Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子的加入会影响Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心的局部配位场，但不会影响Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心的发射能级。在光致发光过程中，清楚地观察到了从敏化剂Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到激活剂Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递。加入Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子后，Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的衰减时间随着Mn"
},
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"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "含量的增加而减小，Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子浓度为4.0%时，能量传递效率超过25%。阐述了铝硅酸盐玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递机制，在Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "到Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "的能量传递过程中，偶极-偶极相互作用起主要作用。玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "和Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "中心几乎均匀地分散在这些玻璃中。Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "-Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂玻璃中最大光致发光量子产率为25.48%，随着Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "离子浓度的增加而减小。GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃的色坐标为(0.323,0.273)，接近准白光发射。且GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",3.5Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "、GAS∶0.5Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ",4.0Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "玻璃中Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "发光中心电子跃迁所需克服的热激活能大约为0.227 eV和0.245 eV，与常见的硅酸盐荧光材料相当。因此GAS∶"
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "x"
}
]
},
{
"name": "text",
"data": "Sn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": ","
},
{
"name": "italic",
"data": [
{
"name": "text",
"data": "y"
}
]
},
{
"name": "text",
"data": "Mn"
},
{
"name": "sup",
"data": [
{
"name": "text",
"data": "2+"
}
]
},
{
"name": "text",
"data": "共掺杂玻璃材料在W-LED中具有潜在的应用前景。"
}
]
},
{
"name": "p",
"data": [
{
"name": "text",
"data": "本文专家审稿意见及作者回复内容的下载地址：http://cjl.lightpublishing.cn/thesisDetails#10.37188/CJL.20220042."
}
]
}
]
}
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"response": [],
"contributions": [],
"acknowledgements": [],
"conflict": [],
"supportedby": [],
"articlemeta": {
"doi": "10.37188/CJL.20220042",
"clc": [
[
{
"name": "text",
"data": "TQ171"
}
]
],
"dc": [
{
"name": "text",
"data": "A"
}
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"publisherid": "1000-7032(2022)05-0691-11",
"citeme": [],
"fundinggroup": [
{
"lang": "zh",
"text": [
{
"name": "text",
"data": "国家自然科学基金（61505193，11904345，11975220，51972291）；浙江省科技厅2022年度“尖兵”研发攻关计划（2022C01046）；浙江省自然科学基金（LGG22E020001）；中国科学院无机功能材料与器件重点实验室开放项目（KLIFMD201808）资助"
}
]
},
{
"lang": "en",
"text": [
{
"name": "text",
"data": "Supported by National Natural Science Foundation of China (61505193, 11904345, 11975220, 51972291); Department of Science and Technology of Zhejiang Province (2022C01046); Natural Science Foundation of Zhejiang (LGG22E020001); Opening Project of Key Laboratory of Inorganic Functional Materials and Devices, Chinese Academy of Sciences (KLIFMD201808)"
}
]
}
],
"history": {
"received": "2022-02-06",
"revised": "2022-02-17",
"opub": "2022-05-23"
},
"copyright": {
"data": [],
"year": "2022"
}
},
"appendix": [],
"type": "research-article",
"ethics": [],
"supplementary": [],
"journalTitle": "发光学报",
"issue": "5",
"volume": "43",
"originalSource": []
}
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