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1.中国计量大学 材料与化学学院,浙江 杭州 310018
2.中国计量大学 光学与电子科技学院,浙江 杭州 310018
3.中国科学院上海硅酸盐研究所 无机功能材料与器件重点实验室,上海 201899
4.中国科学院高能物理研究所 核探测与核电子学国家重点实验室,北京 100049
Received:06 February 2022,
Revised:17 February 2022,
Published:2022-05
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Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass[J]. Chinese journal of luminescence, 2022, 43(5): 691-701.
Zhe-hao HUA, Gao TANG, Qin-hua WEI, et al. Photoluminescence Properties and Energy Transfer of Sn2+-Mn2+ Co-doped Gd2O3-Al2O3-SiO2 Glass[J]. Chinese journal of luminescence, 2022, 43(5): 691-701. DOI: 10.37188/CJL.20220042.
通过传统的高温熔融淬火技术制备了Sn
2+
-Mn
2+
共掺杂的Gd
2
O
3
-Al
2
O
3
-SiO
2
(GAS∶0.5Sn
2+
,
y
Mn
2+
)玻璃。研究了玻璃的光致发光特性和Sn
2+
-Mn
2+
能量传递过程。在365 nm激发下,随着Mn
2+
浓度的增加(1.0%,1.5%,2.0%,2.5%,3.0%,3.5%,4.0%),玻璃中Sn
2+
的发光强度逐渐降低,而Mn
2+
的发光强度逐渐增大。Sn
2+
的衰减时间随着Mn
2+
含量的增加而减小,玻璃中产生了Sn
2+
到Mn
2+
离子的能量传递。GAS∶0.5Sn
2+
,
y
Mn
2+
玻璃的光致发光量子产率(PLQY)随着Mn
2+
含量的增加而减小,其最大值为25.48%。玻璃中Mn
2+
离子浓度达到4.0%时,其发光属于准白光发射,色坐标为(0.323,0.273)。另外,本文还研究了Sn
2+
-Mn
2+
共掺杂玻璃的发光热猝灭现象,Sn
2+
发光中心电子跃迁所需克服的热激活能约为0.23 eV。
The Sn
2+
-Mn
2+
co-doped Gd
2
O
3
-Al
2
O
3
-SiO
2
(GAS∶0.5Sn
2+
y
Mn
2+
) glass was prepared by traditional high temperature melt-quenching technology. The photoluminescence properties of the glass and the energy transfer process of Sn
2+
-Mn
2+
were studied. Under 365 nm excitation wavelength
with the increase of Mn
2+
content(1.0%
1.5%
2.0%
2.5%
3.0%
3.5%
4.0%)
the emission intensity of the Sn
2+
center gradually decreases
and the emission intensity of the Mn
2+
center gradually increases. Moreover
the decay time of the Sn
2+
center decreases with the increase of Mn
2+
content
indicating that energy transfer from Sn
2+
to Mn
2+
ions occurs in the glass. The photoluminescence quantum yield(PLQY) decreases with the increase of Mn
2+
content
the maximum of PLQY of GAS∶0.5Sn
2+
y
Mn
2+
glass is 25.48%. When the Mn
2+
ions concentration reaches 4.0%
the chromatic coordinate of the glass is (0.323
0.273)
which is close to the standard white light emission. In addition
the thermal quenching behavior of Sn
2+
-Mn
2+
co-doped glass was also studied. The thermal activation energy required to overcome the electronic transition of the Sn
2+
emission center is approximately 0.23 eV.
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