α-Ba₃Y (BO₃)₃:Dy³⁺荧光粉的合成及其发光性能

{ "defaultlang": "zh", "titlegroup": { "articletitle": [ { "lang": "zh", "data": [ { "name": "text", "data": "α-Ba" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "Y (BO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": ")" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": ":Dy" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "荧光粉的合成及其发光性能" } ] }, { "lang": "en", "data": [ { "name": "text", "data": "Synthesis and Luminescence of α-Ba" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "Y(BO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": ")" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": ":Dy" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " Phosphors" } ] } ] }, "contribgroup": { "author": [ { "name": [], "stringName": [ { "lang": "zh", "surname": "宁宏宇", "prefix": "" }, { "lang": "en", "surname": "NING Hong-yu", "prefix": "" } ], "aff": [], "role": [ "first-author" ], "deceased": false }, { "name": [], "stringName": [ { "lang": "zh", "surname": "程志远", "prefix": "" }, { "lang": "en", "surname": "CHENG Zhi-yuan", "prefix": "" } ], "aff": [], "role": [], "deceased": false }, { "name": [], "stringName": [ { "lang": "zh", "surname": "董超", "prefix": "" }, { "lang": "en", "surname": "DONG Chao", "prefix": "" } ], "aff": [], "role": [], "deceased": false }, { "name": [], "stringName": [ { "lang": "zh", "surname": "胡泽青", "prefix": "" }, { "lang": "en", "surname": "HU Ze-qing", "prefix": "" } ], "aff": [], "role": [], "deceased": false }, { "name": [], "stringName": [ { "lang": "zh", "surname": "于晶杰", "prefix": "" }, { "lang": "en", "surname": "YU Jing-jie", "prefix": "" } ], "aff": [], "role": [], "deceased": false }, { "name": [], "stringName": [ { "lang": "zh", "surname": "张彦杰", "prefix": "" }, { "lang": "en", "surname": "ZHANG Yan-jie", "prefix": "" } ], "aff": [], "role": [], "deceased": false } ], "aff": [ { "id": "1637398", "intro": [ { "lang": "zh", "label": "1", "text": " 大连工业大学 光子学研究所,辽宁 大连,116034", "data": [ { "name": "text", "data": " 大连工业大学 光子学研究所,辽宁 大连,116034" } ] }, { "lang": "en", "label": "1", "text": " Research Institute of Photonics, Dalian Polytechnic University", "data": [ { "name": "text", "data": " Research Institute of Photonics, Dalian Polytechnic University" } ] } ] } ] }, "abstracts": [ { "lang": "zh", "data": [ { "name": "p", "data": [ { "name": "text", "data": "采用传统的固相法成功合成了一系列-Ba" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "Y（BO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "）" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "：Dy" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "荧光粉，使用X射线衍射（XRD）、扫描电镜（SEM）、荧光光谱（FL）和寿命衰减曲线等对样品进行表征。结果表明：在近紫外/蓝光激发下，样品的发射光谱主要包含黄（577 nm）、蓝（488 nm）两个发射峰组成，分别对应电子跃迁" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "F" }, { "name": "sub", "data": [ { "name": "text", "data": "9/2" } ] }, { "name": "text", "data": " " }, { "name": "sup", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": "H" }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "/2" } ] }, { "name": "text", "data": "和" }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "F" }, { "name": "sub", "data": [ { "name": "text", "data": "9/2" } ] }, { "name": "sup", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": "H" }, { "name": "sub", "data": [ { "name": "text", "data": "1" } ] }, { "name": "sub", "data": [ { "name": "text", "data": "5/2" } ] }, { "name": "text", "data": "。最佳合成温度为1 100℃，该条件下合成的样品具有纯相、最大结晶度和最大发光强度。研究了荧光粉的浓度猝灭效应，猝灭机理主要是dipole-dipole interaction，同时exchange interaction无法忽略，临界摩尔分数为0.07。样品的寿命衰减曲线为二次指数型，这与Ba" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "Y（BO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "）" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "特有的晶格结构有直接关系。-Ba" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "Y（BO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "）" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "：Dy" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": "荧光粉有应用于荧光转换型白光LED照明的潜力。" } ] } ] }, { "lang": "en", "data": [ { "name": "p", "data": [ { "name": "text", "data": "A series of phosphors -Ba " }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": "Y(BO" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": ")" }, { "name": "sub", "data": [ { "name": "text", "data": "3" } ] }, { "name": "text", "data": ":Dy" }, { "name": "sup", "data": [ { "name": "text", "data": "3+" } ] }, { "name": "text", "data": " have been synthesized via conventional solid-state method and characterized. Fluorescence spectra (FL) show that the as-synthesized phosphors mainly exhibit two dominating emission peaks at 488 and 577 nm corresponding to the transitions from " }, { "name": "sup", "data": [ { "name": "text", "data": "4" } ] }, { "name": "text", "data": "F" }, { "name": "sub", "data": [ { "name": "text", "data": "9/2" } ] }, { "name": "text", "data": " to " }, { "name": "sup", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": "H" }, { "name": "sub", "data": [ { "name": "text", "data": "15/2" } ] }, { "name": "text", "data": " and " }, { "name": "sup", "data": [ { "name": "text", "data": "6" } ] }, { "name": "text", "data": "H" }, { "name": "sub", "data": [ { "name": "text", "data": "13/2" } ] }, { "name": "text", "data": ", respectively under ultraviolet (UV) or blue radiation. The best synthesis temperature is 1 100℃, leading to the most intensive luminescence, pure phase and most sufficient crystal growth ensured by FL, X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The concentration quenching mechanism has been determined to be mainly dipole-dipole interaction and exchange interaction is not negligible due to the specific unit cell structure; the critical concentration is 0.07. The second-order exponential lifetime decay curves are observed and its origin related to the specific unit cell structure is discussed. The as-synthesized phosphor has potential application for pc-WLEDs in the lighting field." } ] } ] } ], "keyword": [ { "lang": "zh", "data": [ [ { "name": "text", "data": "荧光粉" } ], [ { "name": "text", "data": "&alpha" } ], [ { "name": "text", "data": "-Ba3Y (BO3)3:Dy3+" } ], [ { "name": "text", "data": "晶格结构" } ] ] }, { "lang": "en", "data": [ [ { "name": "text", "data": "phosphors" } ], [ { "name": "text", "data": "&alpha" } ], [ { "name": "text", "data": "-Ba3Y(BO3)3:Dy3+" } ], [ { "name": "text", "data": "crystal structure" } ] ] } ], "highlights": [], "body": [], "footnote": [], "reflist": { "data": [ { "id": "ref1", "label": "1", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "SCHUBERT E F, KIM J K. Solid-state light sources getting smart[J]. Science, 2005, 308(5726):1274-1278." } ] } ] }, { "id": "ref2", "label": "2", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "DUPUIS R D, KRAMES M R. History, development, and applications of high-brightness visible light-emitting diodes[J]. J. Lightwave Technol., 2008, 26(9):1154-1171." } ] } ] }, { "id": "ref3", "label": "3", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "ZHANG Y, GONG W J, YU J J, et al.. Tunable white-light emission via energy transfer in single-phase LiGd(WO4)2:Re3+ (Re=Tm, Tb, Dy, Eu) phosphors for UV-excited WLEDs[J]. RSC Adv., 2015, 5(117):96272-96280." } ] } ] }, { "id": "ref4", "label": "4", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "VAN DEUN R, NDAGSI D, LIU J, et al.. Dopant and excitation wavelength dependent color-tunable white light-emitting Ln3+:Y2WO6 materials (Ln3+=Sm, Eu, Tb, Dy)[J]. Dalton Ttans., 2015, 44(33):5022-5030." } ] } ] }, { "id": "ref5", "label": "5", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "WANG Y X, SONG Y H, ZHOU X Q, et al.. 3D-hierachical spherical LuVO4:Tm3+, Dy3+, Eu3+, microcrystal:synthesis, energy transfer, and tunable color[J]. Chem. Eng. J., 2016, 306:155-163." } ] } ] }, { "id": "ref6", "label": "6", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "CAO Y Y, LIU N D, TIAN J, et al.. Solid state synthesis and tunable luminescence of LiSrPO4:Eu2+/Mn2+/Tb3+ phosphors[J]. Polyhedron, 2016, 107:78-82." } ] } ] }, { "id": "ref7", "label": "7", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "DOBROWOLSKA A, KARSU E C, BOS A J J, et al.. Spectroscopy, thermoluminescence and afterglow studies of CaLa4-(SiO4)3O:Ln (Ln=Ce, Nd, Eu, Tb, Dy)[J]. J. Lumin., 2015, 160:321-327." } ] } ] }, { "id": "ref8", "label": "8", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "CHEN Y. J, CHEN L, XIAO L J, et al.. The effect of different lattice sites substitution on photoluminescence characteristics of Eu2+/Ce3+ doped M5(ZO4)3X[J]. Mat. Sci. Semicon. Proc., 2014, 18(1):59-64." } ] } ] }, { "id": "ref9", "label": "9", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "SANG H J, KANG D S, JEON D Y. Effect of substitution of nitrogen ions to red-emitting Sr3B2O6-3/2xNx:Eu2+ oxy-nitride phosphor for the application to white LED[J]. J. Cryst. Growth, 2011, 326(1):116-119." } ] } ] }, { "id": "ref10", "label": "10", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "LI P L, WANG Z J, YANG Z P, et al.. Luminescent characteristics of LiCaBO3:M (M=Eu3+, Sm3+, Tb3+, Ce3+, Dy3+) phosphor for white LED[J]. J. Lumin., 2010, 130(2):222-225." } ] } ] }, { "id": "ref11", "label": "11", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "DENAULT K A, CHENG Z Y, BRGOCH J, et al.. Structure-composition relationships and optical properties in cerium-substituted (Sr,Ba)3(Y,La)(BO3)3 borate phosphors[J]. J. Mater. Chem. C, 2013, 1(44):7339-7345." } ] } ] }, { "id": "ref12", "label": "12", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "AMAR N B, KOUBAA T, HASSAIRI M A, et al.. Optical spectroscopy of Eu3+ ions doped in YAl3(BO3)4 crystal[J]. J. Lumin., 2015, 160:95-100." } ] } ] }, { "id": "ref13", "label": "13", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "HE J, SHI R, BRIK G M, et al.. Luminescence and multi-step energy transfer in GdAl3(BO3)4 doped with Ce3+/Tb3+[J]. J. Lumin., 2015, 161:257-263." } ] } ] }, { "id": "ref14", "label": "14", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "CAI G M, SUN Y, LI H K, et al.. Crystal structure and photoluminescence of Tb3+-activated Ba3InB3O9[J]. Mater. Chem. Phys. 2011, 129(3):761-768." } ] } ] }, { "id": "ref15", "label": "15", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "ZHOU L Y, HUANG J L, YI L H, et al.. Luminescent properties of Ba3Gd(BO3)3:Eu3+ phosphor for white LED applications[J]. J. Rare Earth, 2009, 27(1):54-57." } ] } ] }, { "id": "ref16", "label": "16", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "CHUNG W K, JUNG H C, LEE C H, et al.. Warm with high color rendering index white light from hybridization of Ca2BO3Cl:Eu2+ yellow phosphor and CdSe/ZnS nanocrystals[J]. J. Ind. Eng. Chem., 2013, 19(5):1743-1746." } ] } ] }, { "id": "ref17", "label": "17", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "LI X X. Synthesis and luminescence properties of Ba3Y1-xEuxB3O9 (0.05 x 0.35) under UV excitation[J]. Adv. Mater. Res., 2014, 906:60-65." } ] } ] }, { "id": "ref18", "label": "18", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "CHENG Z Y, YU J J, ZHANG Y J, et al.. Luminescence and energy transfer mechanism of -Ba3Y(BO3)3:Ce3+,Tb3+[J]. J. Lumin., 2017, 192:1004-1009." } ] } ] }, { "id": "ref19", "label": "19", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "DURAIRAJAN A, BALAJI D, KAVI R K, et al.. Sol-gel synthesis and photoluminescence studies on colour tuneable Dy3+/Tm3+ co-doped NaGd(WO4)2 phosphor for white light emission[J]. J. Lumin., 2015, 157:357-364." } ] } ] }, { "id": "ref20", "label": "20", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "MENG F G, ZHANG X M, SEO H J. Optical properties of Sm3+ and Dy3+ ions in Gd2MoB2O9 host lattice[J]. Opt. Laser Technol., 2012, 44(1):185-189." } ] } ] }, { "id": "ref21", "label": "21", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "XU Q G, SUN J Y, CUI D P, et al.. Synthesis and luminescence properties of novel Sr3Gd(PO4)3:Dy3+ phosphor[J]. J. Lumin., 2015, 158:301-305." } ] } ] }, { "id": "ref22", "label": "22", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "WANG D Y, CHEN T M, CHENG B M, et al.. Host sensitization of Tb3+ ions in tribarium lanthanide borates Ba3Ln-(BO3)3 (Ln=Lu and Gd)[J]. Inorg. Chem., 2012, 51(51):2961-2965." } ] } ] }, { "id": "ref23", "label": "23", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "JING L D, LIU X H, LI Y T, et al.. Synthesis and photoluminescence properties of Ca9Y(VO4)7:Dy phosphors for white light-emitting diodes[J]. J. Lumin., 2015, 162:185-190." } ] } ] }, { "id": "ref24", "label": "24", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "DEXTER D L. A theory of sensitized luminescence in solids[J]. J. Chem. Phys., 1953, 21(5):836-850." } ] } ] }, { "id": "ref25", "label": "25", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "VAN UITERT L G. Characterization of energy transfer interactions between rare earth ions[J]. J. Electrochem. Soc., 1967, 114(10):1048-1053." } ] } ] }, { "id": "ref26", "label": "26", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "WANG L X, XU M J, ZHAO H Y, et al.. Luminescence, energy transfer and tunable color of Ce3+, Dy3+/Tb3+ doped BaZn2(PO4)2 phosphors[J]. New J. Chem., 2016, 40(4):3086-3093." } ] } ] }, { "id": "ref27", "label": "27", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "WU X, HUANG Y L, SHI L, et al.. Spectroscopy characteristics of vanadate Ca9Dy(VO4)7, for application of white-light-emitting diodes[J]. Mater. Chem. Phys., 2009, 116(2-3):449-452." } ] } ] }, { "id": "ref28", "label": "28", "citation": [ { "lang": "zh", "text": [ { "name": "text", "data": "ZHANG Z W, SONG A J, YUE Y, et al.. White light emission from Ca9Bi(PO4)7:Dy3+, single-phase phosphors for light-emitting diodes[J]. J. Alloys Compd., 2015, 650(47):410-414." } ] } ] } ] }, "response": [], "contributions": [], "acknowledgements": [], "conflict": [], "supportedby": [], "articlemeta": { "doi": "10.3788/fgxb20183908.1087", "clc": [ [ { "name": "text", "data": "O482.31" } ] ], "dc": [], "citeme": [], "fundinggroup": [ { "lang": "zh", "text": [ { "name": "text", "data": "辽宁省自然科学基金（20170540074）资助项目" } ] }, { "lang": "en", "text": [ { "name": "text", "data": "Supported by Natural Science Foundation of Liaoning Province(20170540074)" } ] } ], "history": { "received": "2017-12-11", "revised": "2018-01-25", "epub": "2018-04-10", "ppub": "2018-08-05", "opub": "2020-08-11" } }, "appendix": [], "ethics": [], "supplementary": [], "issue": "8", "volume": "39", "originalSource": [] }