CuInS<sub>2</sub>/ZnS量子点光纤发光性质的理论计算

李帅; 张蕾

doi:10.37188/CJL.20200229

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CuInS₂/ZnS量子点光纤发光性质的理论计算

理论计算及光谱分析 | 更新时间：2020-11-10

- CuInS₂/ZnS量子点光纤发光性质的理论计算
- Theoretical Calculation of Emission Properties of CuInS₂/ZnS Quantum Dot Fiber
- 发光学报 2020年41卷第11期页码：1403-1410
- 作者机构：
  
  牡丹江师范学院物理与电子工程学院, 黑龙江省超硬材料重点实验室, 黑龙江牡丹江 157011
- 作者简介：
  
  [ "李帅(1985-), 男, 吉林长春人, 学士, 实验员, 2017年于牡丹江师范学院获得学士学位, 主要从事量子点材料的研究。E-mail:shuaili@mdjnu.edu.cn" ]
  [ "张蕾(1985-), 女, 吉林长春人, 博士, 副教授, 2014年于吉林大学获得博士学位, 主要从事量子点材料及量子点光纤的研究。E-mail:leizhang@mdjnu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(61604065);黑龙江省青年科学基金(QC2016007);黑龙江省高等学校青年创新人才培养计划(UNPYSCT-2017197);牡丹江师范学院科学技术研究项目(YB2019009);黑龙江省高校基本科研项目(1355MSYYB008)
- DOI：10.37188/CJL.20200229
  中图分类号： O436
- 纸质出版日期：2020-11，
  
  收稿日期：2020-8-2，
  
  录用日期：2020-8-31
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李帅, 张蕾. CuInS₂/ZnS量子点光纤发光性质的理论计算[J]. 发光学报, 2020,41(11):1403-1410.

Shuai LI, Lei ZHANG. Theoretical Calculation of Emission Properties of CuInS₂/ZnS Quantum Dot Fiber[J]. Chinese Journal of Luminescence, 2020,41(11):1403-1410.
李帅, 张蕾. CuInS₂/ZnS量子点光纤发光性质的理论计算[J]. 发光学报, 2020,41(11):1403-1410. DOI： 10.37188/CJL.20200229.

Shuai LI, Lei ZHANG. Theoretical Calculation of Emission Properties of CuInS₂/ZnS Quantum Dot Fiber[J]. Chinese Journal of Luminescence, 2020,41(11):1403-1410. DOI： 10.37188/CJL.20200229.

摘要

在二能级系统近似下，对CuInS

/ZnS量子点光纤的发光性质进行理论计算，得到在不同量子点荧光寿命、斯托克斯频移和吸收-发射截面时，量子点发光沿光纤的传输情况。结果表明，当3个参数一定时，量子点光纤的发光强度随着光纤长度的增加而增加，但最后都趋于饱和或有所下降。当光纤长度一定时，荧光寿命、斯托克斯频移和吸收-发射截面每变化原来数值的1倍，光纤发光的相对强度分别改变7.1，10.52和2.8，因此斯托克斯频移对光纤发光强度的影响最大，其次为荧光寿命，影响最小的是吸收-发射截面。但是对光谱峰值位置影响最大的是吸收-发射截面，在80 cm光纤中，截面每增加1倍，光谱红移5.36 nm。理论计算的发光强度随光纤长度的变化趋势符合文献中的实验数据。本文为量子点光纤中掺杂材料的选择提供了一种实用的方法。

Abstract

The emission properties of CuInS

/ZnS quantum dot optical fibers(QD-OFs) were theoretically calculated under the two-level system approximation

and the transmission of QD emission along the optical fiber was obtained under different QD fluorescence lifetime

Stokes shift and absorption-emission cross section(AECS). The results showed that when the three parameters were fixed

the emission intensity of QD-OFs increased with the increasing fiber length

but all of them eventually tended to saturation or decreased. When the fiber length was fixed

the relative intensity of the fiber emission was changed by 7.1

10.52 and 2.8 for each change of the fluorescence lifetime

Stokes shift and AECS by 1 time. Therefore

Stokes shift had the greatest influence on the OF emission intensity

followed by the fluorescence lifetime

and the least influence was the AECS. However

the AECS had the greatest influence on the spectral peak position. In the 80 cm OF

the spectral redshift was 5.36 nm when the AECS increased by 1 time. The variation trend of emission intensity with fiber length calculated by theory accorded with the experimental data in the literature. This paper provides a practical method for the selection of doped materials in QD-OFs.

关键词

量子点光纤荧光寿命吸收-发射截面斯托克斯频移

Keywords

quantum dot fiberfluorescence lifetimeabsorption-emission cross-sectionStokes shift

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CuInS2/ZnS量子点光纤发光性质的理论计算

Theoretical Calculation of Emission Properties of CuInS2/ZnS Quantum Dot Fiber

DOI：10.37188/CJL.20200229

摘要

Abstract

关键词

Keywords

references

CuInS₂/ZnS量子点光纤发光性质的理论计算

Theoretical Calculation of Emission Properties of CuInS₂/ZnS Quantum Dot Fiber