柔性钙钛矿太阳能电池中电极材料和电荷传输材料的研究进展

杨立群; 马晓辉; 郑士建; 陈聪; 戴其林; 宋宏伟

doi:10.37188/CJL.20200192

您当前的位置：

首页 >

文章列表页 >

柔性钙钛矿太阳能电池中电极材料和电荷传输材料的研究进展

特邀综述 | 更新时间：2020-10-12

- 柔性钙钛矿太阳能电池中电极材料和电荷传输材料的研究进展
- Research Progress on Electrode Materials and Charge Transport Materials in Flexible Perovskite Solar Cells
- 发光学报 2020年41卷第10期页码：1175-1194
- 作者机构：
  
  1.河北工业大学材料科学与工程学院, 天津 300130
  2.Department of Chemistry, Physics and Atmospheric Sciences, Jackson State University, Jackson, Mississippi, MS 39217, USA
  3.吉林大学电子科学与工程学院集成光电子学国家重点联合实验室, 吉林长春 130012
- 作者简介：
  
  [ "杨立群(1997-), 男, 河南商丘人, 硕士研究生, 2019年于大连工业大学获得学士学位, 主要从事半导体光伏器件中柔性钙钛矿太阳能电池的开发与研究。E-mail:liqunyang_1997@163.com" ]
  [ "陈聪(1990-), 男, 吉林长春人, 博士, 副教授, 2019年于吉林大学获得博士学位, 主要从事高效与长时稳定的钙钛矿太阳能电池的研究。E-mail:chencong@hebut.edu.cn" ]
  [ "宋宏伟(1967-), 男, 黑龙江阿城人, 博士, 教授, 博士研究生导师, 1996年于中国科学院长春物理研究所获得博士学位, 主要从事稀土发光材料物理、光电子及生物应用的研究。E-mail:songhw@jlu.edu.cn" ]
- 基金信息：
  
  国家重点研发计划(2016YFC0207101);国家自然科学基金(51771201)
- DOI：10.37188/CJL.20200192
  中图分类号： TM914.4
- 纸质出版日期：2020-10，
  
  收稿日期：2020-7-5，
  
  录用日期：2020-7-24
扫描看全文
杨立群, 马晓辉, 郑士建, 等. 柔性钙钛矿太阳能电池中电极材料和电荷传输材料的研究进展[J]. 发光学报, 2020,41(10):1175-1194.

Li-qun YANG, Xiao-hui MA, Shi-jian ZHENG, et al. Research Progress on Electrode Materials and Charge Transport Materials in Flexible Perovskite Solar Cells[J]. Chinese Journal of Luminescence, 2020,41(10):1175-1194.
杨立群, 马晓辉, 郑士建, 等. 柔性钙钛矿太阳能电池中电极材料和电荷传输材料的研究进展[J]. 发光学报, 2020,41(10):1175-1194. DOI： 10.37188/CJL.20200192.

Li-qun YANG, Xiao-hui MA, Shi-jian ZHENG, et al. Research Progress on Electrode Materials and Charge Transport Materials in Flexible Perovskite Solar Cells[J]. Chinese Journal of Luminescence, 2020,41(10):1175-1194. DOI： 10.37188/CJL.20200192.

摘要

近年来，钙钛矿材料因具有良好的光电性能和电荷传输特性，被认为是太阳能电池的后起之秀。可通过低成本印刷制备的柔性钙钛矿太阳能电池（F-PSCs）具有轻便、可弯曲的优点，在便携式可穿戴电子和光伏建筑等领域应用前景广阔。通过对钙钛矿光吸收层、电荷传输层、基底和电极材料的优化，F-PSCs的效率已经超过20%。制备工艺的快速发展为F-PSCs的应用打下了坚实的基础。本文着重介绍F-PSCs中的透明导电底电极材料、电子传输材料、空穴传输材料和对电极材料的最新研究进展及其对F-PSCs光电性能和稳定性的影响，并对超薄钙钛矿光吸收层的优化进行了综述和总结。最后，对F-PSCs的大规模生产和封装技术进行了介绍。

Abstract

In recent years

perovskite materials are considered to be the rising star of solar cells due to their good photoelectric performance and charge transport characteristics. Flexible perovskite solar cells(F-PSCs) that can be prepared by low-cost printing have the advantages of being light and flexible

and have broad application prospects in portable wearable electronics and photovoltaic buildings. By optimizing the perovskite light absorption layer

charge transport layer

substrate and electrode materials

the efficiency of F-PSCs has exceeded 20%. The rapid development of the preparation process has laid a solid foundation for the application of F-PSCs. This article focuses on the latest research progress of transparent conductive bottom electrode materials

electron transport materials

hole transport materials and counter electrode materials in F-PSCs. In addition

the influence of materials on the photoelectric performance and stability of F-PSCs and the optimization of ultra-thin perovskite light absorption layer were reviewed and summarized. Finally

we introduced the mass production and encapsulation technology of F-PSCs.

关键词

柔性钙钛矿太阳能电池电荷传输层电极

Keywords

flexibleperovskite solar cellcharge transport layerelectrode

references

HEO J H, IM S H, NOH J H, et al ..Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors[J].Nat. Photonics, 2013, 7(6):486-491.

GRAETZEL M, JANSSEN R A J, MITZI D B, et al ..Materials interface engineering for solution-processed photovoltaics[J].Nature, 2012, 488(7411):304-312.

KOJIMA A, TESHIMA K, SHIRAI Y,et al ..Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].J. Am. Chem. Soc., 2009, 131(17):6050-6051.

KUMAR M H, YANTARA N, DHARANI S, et al ..Flexible, low-temperature, solution processed ZnO-based perovskite solid state solar cells[J].Chem. Commun., 2013, 49(94):11089-11091.

RU P B, BI E B, ZHANG Y, et al.. High electron affinity enables fast hole extraction for efficient flexible inverted perovskite solar cells[J].Adv. Energy Mater., 2020, 10(12):1903487.

ZHAO Z Q, YOU S, HUANG J, et al ..Molecular modulator for stable inverted planar perovskite solar cells with efficiency enhanced by interface engineering[J].J. Mater. Chem. C, 2019, 7(31):9735-9742.

KIM B J, KIM D H, LEE Y Y, et al ..Highly efficient and bending durable perovskite solar cells:toward a wearable power source[J].Energy Environ. Sci., 2015, 8(3):916-921.

PARK M, KIM H J, JEONG I, et al ..Mechanically recoverable and highly efficient perovskite solar cells:investigation of intrinsic flexibility of organic-inorganic perovskite[J].Adv. Energy Mater., 2015, 5(22):1501406.

PARK S H, LEE S M, KO E H, et al ..Roll-to-roll sputtered ITO/Cu/ITO multilayer electrode for flexible, transparent thin film heaters and electrochromic applications[J].Sci. Rep., 2016, 6:33868-1-12.

LEWIS J S, WEAVER M S. Thin-film permeation-barrier technology for flexible organic light-emitting devices[J].IEEE J. Sel. Top. Quantum Electron., 2004, 10(1):45-57.

LIM J W, WANG H, CHOI C H, et al ..Polyethylenimine ethoxylated interlayer-mediated ZnO interfacial engineering for high-performance and low-temperature processed flexible perovskite solar cells:a simple and viable route for one-step processed CH3NH3PbI3[J].J. Power Sources, 2019, 438:226956.

MENG X C, CAI Z R, ZHANG Y Y, et al ..Bio-inspired vertebral design for scalable and flexible perovskite solar cells[J].Nat. Commun., 2020, 11(1):3016-1-10.

ZHOU H P, CHEN Q, LI G, et al ..Interface engineering of highly efficient perovskite solar cells[J].Science, 2014, 345(6196):542-546.

KIM H S, IM S H, PARK N G. Organolead halide perovskite:new horizons in solar cell research[J].J. Phys. Chem. C, 2014, 118(11):5615-5625.

杨旭东, 陈汉, 毕恩兵, 等.高效率钙钛矿太阳电池发展中的关键问题[J].物理学报, 2015, 64(3):038404-1-10.

YANG X D, CHEN H, BI E B, et al.. Key issues in highly efficient perovskite solar cells[J].Acta Phys. Sinica, 2015, 64(3):038404-1-10. (in Chinese)

FUAD A, FIBRIYANTI A A, MUFTI N, et al ..Growth of CH3NH3PbI3 perovskite on stainless steel substrate layered by ZnO nanoparticles using one-step spin coating route[J].J. Phys. Conf. Ser., 2018, 1011:012011-1-5.

ZARDETTO V, BROWN T M, REALE A, et al ..Substrates for flexible electronics:a practical investigation on the electrical, film flexibility, optical, temperature, and solvent resistance properties[J].Polym. Phys., 2011, 49(9):638-648.

JUNG H S, HAN G S, PARK N G, et al ..Flexible perovskite solar cells[J].Joule, 2019, 3(8):1850-1880.

YE T, LIM S L, LI X Q, et al ..Pinhole-free mixed perovskite film for bending durable mixed perovskite solar cells[J].Solar Energy Mater. Solar Cells, 2018, 175:111-117.

NOVOSELOV K S, GEIM A K, MOROZOV S V, et al ..Electric field effect in atomically thin carbon films[J].Science, 2004, 306(5696):666-669.

CHEN J H, JANG C, XIAO S D, et al ..Intrinsic and extrinsic performance limits of graphene devices on SiO2[J].Nat. Nanotechnol., 2008, 3(4):206-209.

KIM S, SHIN S H, CHOI S H. N-i-p-type perovskite solar cells employing n-type graphene transparent conductive electrodes[J].J. Alloys Compd., 2019, 786:614-620.

SHIN D H, KIM J M, SHIN S H,et al ..Highly-flexible graphene transparent conductive electrode/perovskite solar cells with graphene quantum dots-doped PCBM electron transport layer[J].Dyes Pigm., 2019, 170:107630.

ⅡJIMA S. Helical microtubules of graphitic carbon[J].Nature, 1991, 354(6348):56-58.

YU L P, SHEARER C, SHAPTER J. Recent development of carbon nanotube transparent conductive films[J].Chem. Rev., 2016, 116(22):13413-13453.

SHAO Y C, YUAN Y B, HUANG J S. Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells[J].Nat. Energy, 2016, 1(1):15001-1-9.

WANG X Y, LI Z, XU W J, et al ..TiO2 nanotube arrays based flexible perovskite solar cells with transparent carbon nanotube electrode[J].Nano Energy, 2015, 11:728-735.

HU L B, KIM H S, LEE J Y, et al ..Scalable coating and properties of transparent, flexible, silver nanowire electrodes[J].ACS Nano, 2010, 4(5):2955-2963.

LEE E, AHN J, KWON H C, et al ..All-solution-processed silver nanowire window electrode-based flexible perovskite solar cells enabled with amorphous metal oxide protection[J].Adv. Energy Mater., 2018, 8(9):1702182-1-11.

KANG S, JEONG J, CHO S, et al ..Ultrathin, lightweight and flexible perovskite solar cells with an excellent power-per-weight performance[J].J. Mater. Chem. A, 2019, 7(3):1107-1114.

XIE M L, WANG J, KANG J C, et al ..Super-flexible perovskite solar cells with high power-per-weight on 17 μm thick PET substrate utilizing printed Ag nanowires bottom and top electrodes[J].Flexible Printed Electron., 2019, 4(3):034002.

DI GIACOMO F, FAKHARUDDIN A, JOSE R, et al ..Progress, challenges and perspectives in flexible perovskite solar cells[J].Energy Environ. Sci., 2016, 9(10):3007-3035.

TROUGHTON J, BRYANT D, WOJCIECHOWSKI K, et al ..Highly efficient, flexible, indium-free perovskite solar cells employing metallic substrates[J].J. Mater. Chem. A, 2015, 3(17):9141-9145.

NEJAND B A, NAZARI P, GHARIBZADEH S, et al ..All-inorganic large-area low-cost and durable flexible perovskite solar cells using copper foil as a substrate[J].Chem. Commun., 2017, 53(4):747-750.

TAVAKOLI M M, TSUI K H, ZHANG Q P, et al ..Highly efficient flexible perovskite solar cells with antireflection and self-cleaning nanostructures[J].ACS Nano, 2015, 9(10):10287-10295.

ZHU K P, LU Z, CONG S, et al ..Ultraflexible and lightweight bamboo-derived transparent electrodes for perovskite solar cells[J].Small, 2019, 15(33):1902878.

SUN Q, CHEN J D, ZHENG J W, et al ..Surface plasmon-assisted transparent conductive electrode for flexible perovskite solar cells[J].Adv. Opt. Mater., 2019, 7(20):1900847.

KIEE M, KO, Y, MIN B K, et al ..Silver nanowire top electrodes in flexible perovskite solar cells using titanium metal as substrate[J].ChemSusChem, 2016, 9:31-35

PISONI S, FU F, FEURER T, et al ..Flexible NIR-transparent perovskite solar cells for all-thin-film tandem photovoltaic devices[J].J. Mater. Chem. A, 2017, 5(26):13639-13647.

LI L B, ZHANG S S, YANG Z C, et al ..Recent advances of flexible perovskite solar cells[J].J. Energy Chem., 2018, 27(3):673-689.

HAGFELDT A, BOSCHLOO G, SUN L C, et al ..Dye-sensitized solar cells[J].Chem. Rev., 2010, 110(11):6595-6663.

DI GIACOMO F, ZARDETTO V, D'EPIFANIO A, et al ..Flexible perovskite photovoltaic modules and solar cells based on atomic layer deposited compact layers and UV-irradiated TiO2 scaffolds on plastic substrates[J].Adv. Energy Mater., 2015, 5(8):1401808-1-9.

CHEN C, CHENG Y, DAI Q L, et al ..Radio frequency magnetron sputtering deposition of TiO2 thin films and their perovskite solar cell applications[J].Sci. Rep., 2015, 5:17684-1-12.

QIU W M, PAETZOLD U W, GEHLHAAR R, et al ..An electron beam evaporated TiO2 layer for high efficiency planar perovskite solar cells on flexible polyethylene terephthalate substrates[J].J. Mater. Chem. A, 2015, 3(45):22824-22829.

CHEN C, LIU D L, WU Y J, et al ..Dual interfacial modifications by conjugated small-molecules and lanthanides doping for full functional perovskite solar cells[J].Nano Energy, 2018, 53:849-862.

ZHANG B X, SONG Z L, JIN J J, et al ..Efficient rare earth co-doped TiO2 electron transport layer for high-performance perovskite solar cells[J].J. Colloid Interface Sci., 2019, 553:14-21.

TSENG Z L, CHEN L C. Low-temperature ZnO films as electron transporting layers for perovskite-based solar cells[C].Proceedings of The 2018 7th International Symposium on Next Generation Electronics, Taipei, China, 2018: 369-372.

CHU W J, YANG J Y, JIANG Q H, et al ..Enhancement of photovoltaic performance of flexible perovskite solar cells by means of ionic liquid interface modification in a low temperature all solution process[J].Appl. Surf. Sci., 2018, 440:1116-1122.

朱立华, 商雪妮, 雷凯翔, 等.应用于钙钛矿太阳能电池中金属氧化物电子传输材料的研究进展[J].发光学报, 2020, 41(5):481-497.

ZHU L H, SHANG X N, LEI K X, et al.. Research progress of metal oxide electron transporting materials applied in perovskite solar cells[J].Chin. J. Lumin., 2020, 41(5):481-497. (in Chinese)

WANG M H, FENG Y L, DONG Q S, et al ..Degradation mechanism of flexible perovskite solar cells:investigated by tracking of the heterojunction property[J].Mater. Res. Bull., 2020, 123:110696.

PANG A Y, LI J L, WEI X F, et al ..UV-O3 treated annealing-free cerium oxide as electron transport layers in flexible planar perovskite solar cells[J].Nanoscale Adv., 2020, doi:10.1039/D0NA00367K.

SONG Z l, BI W b, ZHUANG X m, et al ..Low-temperature electron beam deposition of Zn-SnOx for stable and flexible perovskite solar cells[J].Solar RRL., 2020, 4(2):1900266.

SHIN S S, YANG W S, YEOM E J, et al ..Tailoring of electron-collecting oxide nanoparticulate layer for flexible perovskite solar cells[J].J. Phys. Chem. Lett., 2016, 7(10):1845-1851.

SUBBIAH A S, DHARA A K, MAHULI N, et al ..Ultra-thin atomic layer deposited-Nb2O5 as electron transport layer for co-evaporated MAPbI3 planar perovskite solar cells[J].Energy Technol., 2019, 8(4):1900878.

WOJCIECHOWSKI K, LEIJTENS T, SIPROVA S, et al ..C60 as an efficient n-type compact layer in perovskite solar cells[J].J. Phys. Chem. Lett., 2015, 6(12):2399-2405.

LIAN J R, LU B, NIU F F, et al ..Electron-transport materials in perovskite solar cells[J].Small Methods, 2018, 2(10):1800082-1-27.

YANG D, YANG R X, REN X D, et al ..Hysteresis-suppressed high-efficiency flexible perovskite solar cells using solid-state ionic-liquids for effective electron transport[J].Adv. Mater., 2016, 28(26):5206-5213.

LIU X Y, LIU Z Y, YE H B, et al ..Novel efficient C60-based inverted perovskite solar cells with negligible hysteresis[J].Electrochim. Acta, 2018, 288:115-125.

LIU C, CAI M L, YANG Y, et al ..A C60/TiOx bilayer for conformal growth of perovskite films for UV stable perovskite solar cells[J].J. Mater. Chem. A, 2019, 7(18):11086-11094.

YOU J B, HONG Z R, YANG Y, et al ..Low-temperature solution-processed perovskite solar cells with high efficiency and flexibility[J].ACS Nano, 2014, 8(2):1674-1680.

MA S, LIU X P, WU Y Z, et al ..Efficient and flexible solar cells with improved stability through incorporation of a multifunctional small molecule at PEDOT: PSS/perovskite interface[J].Solar Energy Mater. Solar Cells, 2020, 208:110379.

YE T L, CHEN W B, JIN S, et al ..Enhanced efficiency of planar heterojunction perovskite solar cells by a light soaking treatment on tris(pentafluorophenyl)borane-doped poly(triarylamine) solution[J].ACS Appl. Mater. Interfaces, 2019, 11(15):14004-14010.

CHEN C, LI H, JIN J J, et al ..Highly enhanced long time stability of perovskite solar cells by involving a hydrophobic hole modification layer[J].Nano Energy, 2017, 32:165-173.

JUNG J W, PARK J S, HAN I K, et al ..Flexible and highly efficient perovskite solar cells with a large active area incorporating cobalt-doped poly(3-hexylthiophene) for enhanced open-circuit voltage[J].J. Mater. Chem. A, 2017, 5(24):12158-12167.

JO J W, SEO M S, JUNG J W, et al ..Development of organic-inorganic double hole-transporting material for high performance perovskite solar cells[J].J. Power Sources, 2018, 378:98-104.

LIMA F A S, BELIATIS M J, ROTH B, et al ..Flexible ITO-free organic solar cells applying aqueous solution-processed V2O5 hole transport layer:an outdoor stability study[J].APL Mater., 2016, 4(2):026104-1-7.

CHANDRASEKHAR P S, SEO Y H, NOH Y J, et al ..Room temperature solution-processed Fe doped NiOx as a novel hole transport layer for high efficient perovskite solar cells[J].Appl. Surf. Sci., 2019, 481:588-596.

WANG Z Y, RONG X, WANG L Y, et al ..Dual role of amino-functionalized graphene quantum dots in NiOx films for efficient inverted flexible perovskite solar cell[J].ACS Appl. Mater. Interfaces, 2020, 12(7):8342-8350.

MURUGADOSS G, THANGAMUTHU R, SENTHIL KUMAR S M. Fabrication of CH3NH3PbI3 perovskite-based solar cells:developing various new solvents for CuSCN hole transport material[J].Solar Energy Mater. Solar Cells, 2017, 164:56-62.

BURSCHKA J, PELLET N, MOON S J, et al ..Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature, 2013, 499(7458):316-319.

HAN G S, LEE S, DUFF M L, et al ..Multi-functional transparent electrode for reliable flexible perovskite solar cells[J].J. Power Sources, 2019, 435:226768.

MENDES M J, HAQUE S, SANCHEZ-SOBRADO O, et al ..Optimal-enhanced solar cell ultra-thinning with broadband nanophotonic light capture[J].iScience, 2018, 3:238-254.

WU Y J, CHEN C, WANG H, et al ..Toward ultra-thin and full functional perovskite solar cells by broadband light scattering management and efficient interfacial modification[J].Solar Energy Mater. Solar Cells, 2020, 206:110297.

ZHANG B X, BI W B, WU Y J, et al ..High-performance CsPbIBr2 perovskite solar cells:effectively promoted crystal growth by antisolvent and organic ion strategies[J].ACS Appl. Mater. Interfaces, 2019, 11(37):33868-33878.

ONO L K, PARK N G, ZHU K, et al ..Perovskite solar cells-towards commercialization[J].ACS Energy Lett., 2017, 2(8):1749-1751.

SHEIKH A D, MUNIR R, HAQUE A, et al ..Effects of high temperature and thermal cycling on the performance of perovskite solar cells:acceleration of charge recombination and deterioration of charge extraction[J].ACS Appl. Mater. Interfaces, 2017, 9(40):35018-35029.

YANG Z C, AHMAD W, CHU L, et al ..Three-dimensional nanocomposite formed by hydrophobic multiwalled carbon nanotubes threading titanium dioxide as the counter electrode of enhanced performance dye-sensitized solar cells[J].RSC Adv., 2016, 6(60):55071-55078.

DENG Y H, VAN BRACKLE C H, DAI X Z, et al ..Tailoring solvent coordination for high-speed, room-temperature blading of perovskite photovoltaic films[J].Sci. Adv., 2019, 5(12):eaax7537-1-8.

WANG Z, ZENG L X, ZHANG C L, et al ..Rational interface design and morphology control for blade-coating efficient flexible perovskite solar cells with a record fill factor of 81%[J].Adv. Funct. Mater., 2020, 30(32):2001240.

BU T L, LI J, ZHENG F, et al ..Universal passivation strategy to slot-die printed SnO2 for hysteresis-free efficient flexible perovskite solar module[J].Nat. Commun., 2018, 9(1):4609.

PARK M, CHO W, LEE G,et al ..Highly reproducible large-area perovskite solar cell fabrication via continuous megasonic spray coating of CH3NH3PbI3[J].Small, 2019, 15(1):1804005.

JIANG Q L, REBOLLAR D, GONG J, et al ..Pseudohalide-induced moisture tolerance in perovskite CH3NH3Pb(SCN)2I thin films[J].Angew. Chem. Int. Ed., 2015, 54(26):7617-7620.

HAN Y, MEYER S, DKHISSI Y, et al ..Degradation observations of encapsulated planar CH3NH3PbI3 perovskite solar cells at high temperatures and humidity[J].J. Mater. Chem. A, 2015, 3(15):8139-8147.

KIM I S, CAO D H, BUCHHOLZ D B, et al ..Liquid water- and heat-resistant hybrid perovskite photovoltaics via an inverted ALD oxide electron extraction layer design[J].Nano Lett., 2016, 16(12):7786-7790.

THEJO KALYANI N, DHOBLE S J. Novel materials for fabrication and encapsulation of OLEDs[J].Renew. Sustain. Energy Rev., 2015, 44:319-347.

WEERASINGHE H C, DKHISSI Y, SCULLY A D, et al ..Encapsulation for improving the lifetime of flexible perovskite solar cells[J].Nano Energy, 2015, 18:118-125.

ZHANG J, ZHANG W, CHENG H M, et al ..Critical review of recent progress of flexible perovskite solar cells[J].Mater. Today, 2020, doi:10.1016/j.mattod.2020.05.002.

浏览量

259

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

柔性钙钛矿光伏：研究进展、商业化进程和展望

柔性电极的喷墨印刷制备

缺陷对全无机钙钛矿太阳能电池性能的影响