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1.上海理工大学 材料与化学学院,上海 200093
2.中国科学院上海硅酸盐研究所 新材料中试研发中心,上海 201899
3.华中师范大学 物理科学与技术学院,武汉 430079
4.中国科学院大学 材料科学与光电工程研究中心,北京 100049
5.中国科学院稀土重点实验室, 赣州 341119
Published Online:17 March 2025,
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左晓艺,武彤,王绍涵等.超快闪烁晶体Cs2ZnCl4的研究进展[J].发光学报,
ZUO Xiaoyi,WU Tong,WANG Shaohan,et al.Research progress of Cs2ZnCl4 ultrafast scintillation crystals[J].Chinese Journal of Luminescence,
左晓艺,武彤,王绍涵等.超快闪烁晶体Cs2ZnCl4的研究进展[J].发光学报, DOI:10.37188/CJL.20240346 CSTR: 32170.14.CJL.20240346.
ZUO Xiaoyi,WU Tong,WANG Shaohan,et al.Research progress of Cs2ZnCl4 ultrafast scintillation crystals[J].Chinese Journal of Luminescence, DOI:10.37188/CJL.20240346 CSTR: 32170.14.CJL.20240346.
下一代高能物理实验与飞行时间正电子发射断层扫描成像对闪烁体提出了更快衰减时间的要求,以满足更高时间辐射探测精度的需求,希望闪烁体具有ns甚至ps量级的超快闪烁衰减时间。Cs
2
ZnCl
4
晶体具有衰减快、无慢发光、熔点低、不易潮解以及发光谱与光电倍增管匹配较好等优势,近年以来作为一种交叉发光的超快闪烁体受到越来越多的关注。本文围绕发光机制、物化特性、晶体生长、闪烁性能等方面,较为全面地回顾了Cs
2
ZnCl
4
晶体的研究历史与进展,重点介绍了Cs
2
ZnCl
4
的光学与闪烁性能,总结和展望了Cs
2
ZnCl
4
晶体作为一种独特超快闪烁体的应用潜力。
The next generation of high energy physics experiments and time-of-flight positron emission tomography imaging require scintillators with ultrafast decay ranging from nanoseconds (ns) to picoseconds (ps) to fulfill the need for higher time resolution. The Cs
2
ZnCl
4
crystal stands out due to its remarkable advantages of an ultrafast decay without slow component, a low melting point, non-hygroscopic, as well as the proper emission band matching
well with commercial photomultiplier tube. In recent years, Cs
2
ZnCl
4
crystal has attracted worldwide research interests as a kind of ultrafast scintillator with core-valence luminescence (CVL). The review emphasis on the research history and progress of Cs
2
ZnCl
4
crystals, including luminescence mechanism, physicochemical properties, crystal growth techniques and the scintillation properties. Particularly, emphasis is placed on the optical and scintillation properties of Cs
2
ZnCl
4
crystal. The application potential of Cs
2
ZnCl
4
crystals as a unique ultrafast scintillator is then concluded.
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