Back Energy Transfer Enhances Er<sup>3+</sup> Upconversion Luminescence

YANG Run; CHEN Haoran; TU Langping; LI Qiqing; CHANG Yulei

doi:10.37188/CJL.20230100

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Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence

Synthesis and Properties of Materials | 更新时间：2023-09-28

- Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 9, Pages: 1552-1559(2023)
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室，吉林长春　130033
  2.中国科学院大学，北京　100049
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(62075217;11874354;11874355;61575194);the National Key Research and Development Program of China(2021YFA0715603);Project of Science and Technology Agency, Jilin Province(20210101148JC;202512JC010475440;20230508104RC);The State Key Laboratory of Luminescence and Applications(SKLA⁃2019⁃02;SKLA⁃2020⁃09)
- DOI：10.37188/CJL.20230100
  CLC： O482.31
- Received：19 April 2023，
  
  Revised：2023-05-04，
  
  Published：05 September 2023
- 稿件说明：
移动端阅览
杨润,陈浩然,涂浪平等.反向能量传递增强Er³⁺上转换发光[J].发光学报,2023,44(09):1552-1559.

YANG Run,CHEN Haoran,TU Langping,et al.Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence[J].Chinese Journal of Luminescence,2023,44(09):1552-1559.
杨润,陈浩然,涂浪平等.反向能量传递增强Er³⁺上转换发光[J].发光学报,2023,44(09):1552-1559. DOI： 10.37188/CJL.20230100.

YANG Run,CHEN Haoran,TU Langping,et al.Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence[J].Chinese Journal of Luminescence,2023,44(09):1552-1559. DOI： 10.37188/CJL.20230100.

摘要

提高上转换发光效率是促进上转换发光材料实际应用的关键。在NaErF

@NaYF

体系中，惰性NaYF

壳层可以抑制高组分Er

掺杂下的发光浓度猝灭，其上转换发光主要来源于Er

⁃Er

的能量传递上转换。本文利用共沉淀法制备了Er

和Yb

分区掺杂的NaErF

@NaYbF

@NaYF

核壳结构的纳米颗粒，通过包覆惰性壳层研究Er

⁃Yb

⁃Er

之间的能量传递和反向能量传递过程。由于808 nm波长只能激发Er

而不能激发Yb

，因此在808 nm波长激发下，Er

在惰性壳层的保护作用下将激发态能量传递给Yb

，随后通过反向能量传递回Er

，使得Er

的上转换发光增强。实验结果发现，当中间层Yb

掺杂浓度为100%时，绿色和红色上转换发光最大增强倍数为24.9和9.79。

Abstract

Improving the upconversion luminescence efficiency is the key to promoting the practical application of upconversion luminescent materials. In the NaErF

@NaYF

system， the inert NaYF

shell can inhibit the concentration quenching under high Er

doping， and the upconversion luminescence is mainly from the energy transfer upconversion of Er

-Er

. In this paper， Er

and Yb

partition doped NaErF

@NaYbF

@NaYF

core-shell nanoparticles were prepared by the coprecipitation method， and the energy transfer and back energy transfer processes between Er

-Yb

-Er

was studied. Since the 808 nm can only excite Er

but not Yb

， under 808 nm excitation， Er

harvests the pumping energy and transfers it to Yb

and subsequently back to Er

due to the protection offered by NaYF

inert outer shell， which finally enhances the upconversion luminescence of Er

. When the doping concentration of Yb

in the intermediate layer is 100%， the maximum enhancement multiple is 24.9 and 9.79 for green and red upconversion， respectively.

关键词

Keywords

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⁰

Back Energy Transfer Enhances Er3+ Upconversion Luminescence

DOI：10.37188/CJL.20230100

摘要

Abstract

关键词

Keywords

references

Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence