Back Energy Transfer Enhances Er<sup>3+</sup> Upconversion Luminescence

YANG Run; CHEN Haoran; TU Langping; LI Qiqing; CHANG Yulei

doi:10.37188/CJL.20230100

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Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence

Synthesis and Properties of Materials | 更新时间：2023-09-28

- Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 9, Pages: 1552-1559(2023)
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室，吉林长春　130033
  2.中国科学院大学，北京　100049
- 作者简介：
- 基金信息：
  
  the National Natural Science Foundation of China(62075217;11874354;11874355;61575194);the National Key Research and Development Program of China(2021YFA0715603);Project of Science and Technology Agency, Jilin Province(20210101148JC;202512JC010475440;20230508104RC);The State Key Laboratory of Luminescence and Applications(SKLA⁃2019⁃02;SKLA⁃2020⁃09)
- DOI：10.37188/CJL.20230100
  CLC： O482.31
- Published：05 September 2023，
  
  Received：19 April 2023，
  
  Revised：04 May 2023，
- 稿件说明：
移动端阅览
杨润,陈浩然,涂浪平等.反向能量传递增强Er³⁺上转换发光[J].发光学报,2023,44(09):1552-1559.

YANG Run,CHEN Haoran,TU Langping,et al.Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence[J].Chinese Journal of Luminescence,2023,44(09):1552-1559.
杨润,陈浩然,涂浪平等.反向能量传递增强Er³⁺上转换发光[J].发光学报,2023,44(09):1552-1559. DOI： 10.37188/CJL.20230100.

YANG Run,CHEN Haoran,TU Langping,et al.Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence[J].Chinese Journal of Luminescence,2023,44(09):1552-1559. DOI： 10.37188/CJL.20230100.

摘要

提高上转换发光效率是促进上转换发光材料实际应用的关键。在NaErF

@NaYF

体系中，惰性NaYF

壳层可以抑制高组分Er

掺杂下的发光浓度猝灭，其上转换发光主要来源于Er

⁃Er

的能量传递上转换。本文利用共沉淀法制备了Er

和Yb

分区掺杂的NaErF

@NaYbF

@NaYF

核壳结构的纳米颗粒，通过包覆惰性壳层研究Er

⁃Yb

⁃Er

之间的能量传递和反向能量传递过程。由于808 nm波长只能激发Er

而不能激发Yb

，因此在808 nm波长激发下，Er

在惰性壳层的保护作用下将激发态能量传递给Yb

，随后通过反向能量传递回Er

，使得Er

的上转换发光增强。实验结果发现，当中间层Yb

掺杂浓度为100%时，绿色和红色上转换发光最大增强倍数为24.9和9.79。

Abstract

Improving the upconversion luminescence efficiency is the key to promoting the practical application of upconversion luminescent materials. In the NaErF

@NaYF

system， the inert NaYF

shell can inhibit the concentration quenching under high Er

doping， and the upconversion luminescence is mainly from the energy transfer upconversion of Er

-Er

. In this paper， Er

and Yb

partition doped NaErF

@NaYbF

@NaYF

core-shell nanoparticles were prepared by the coprecipitation method， and the energy transfer and back energy transfer processes between Er

-Yb

-Er

was studied. Since the 808 nm can only excite Er

but not Yb

， under 808 nm excitation， Er

harvests the pumping energy and transfers it to Yb

and subsequently back to Er

due to the protection offered by NaYF

inert outer shell， which finally enhances the upconversion luminescence of Er

. When the doping concentration of Yb

in the intermediate layer is 100%， the maximum enhancement multiple is 24.9 and 9.79 for green and red upconversion， respectively.

关键词

稀土纳米材料上转换发光反向能量传递β-NaErF4

Keywords

rare earth nanoparticlesupconversion luminescenceback energy transferβ-NaErF4

references

DING M Y， CUI S S， FANG L， et al. NIR-I-responsive single-band upconversion emission through energy migration in core-shell-shell nanostructures ［J］. Angew. Chem. Int. Ed.， 2022， 61（29）： e202203631. doi: 10.1002/anie.202203631http://dx.doi.org/10.1002/anie.202203631

RESZCZYŃSKA J， GRZYB T， SOBCZAK J W， et al. Visible light activity of rare earth metal doped （Er3+， Yb3+ or Er3+/Yb3+） titania photocatalysts ［J］. Appl. Catal. B Environ.， 2015， 163： 40-49. doi: 10.1016/j.apcatb.2014.07.010http://dx.doi.org/10.1016/j.apcatb.2014.07.010

PARNICKA P， MAZIERSKI P， GRZYB T， et al. Influence of the preparation method on the photocatalytic activity of Nd-modified TiO2 ［J］. Beilstein J. Nanotechnol.， 2018， 9： 447-459. doi: 10.3762/bjnano.9.43http://dx.doi.org/10.3762/bjnano.9.43

CHEN Y， CHEN Q， SONG L， et al. Preparation and characterization of encapsulation of europium complex into meso-structured silica monoliths using PEG as the template ［J］. Microporous Mesoporous Mater.， 2009， 122（1-3）： 7-12. doi: 10.1016/j.micromeso.2008.12.021http://dx.doi.org/10.1016/j.micromeso.2008.12.021

CAVALLO C， SALLEO A， GOZZI D， et al. Solid solutions of rare earth cations in mesoporous anatase beads and their performances in dye-sensitized solar cells ［J］. Scientific Reports， 2015， 5： 16785-1-15. doi: 10.1038/srep16785http://dx.doi.org/10.1038/srep16785

ADHIKARI R， GYAWALI G， CHO S H， et al. Er3+/Yb3+ co-doped bismuth molybdate nanosheets upconversion photocatalyst with enhanced photocatalytic activity ［J］. J. Solid State Chem.， 2014， 209： 74-81. doi: 10.1016/j.jssc.2013.10.028http://dx.doi.org/10.1016/j.jssc.2013.10.028

RESZCZYNSKA J， IWULSKA A， SLIWINSKI G， et al. Characterization and photocatalytic activity of rare earth metal-doped titanium dioxide ［J］. Physicochem. Probl. Miner. Process.， 2012， 48（1）： 201-208.

GRAUEL B， WÜRTH C， HOMANN C， et al. Volume and surface effects on two-photonic and three-photonic processes in dry co-doped upconversion nanocrystals ［J］. Nano Res.， 2022， 15（3）： 2362-2373. doi: 10.1007/s12274-021-3727-yhttp://dx.doi.org/10.1007/s12274-021-3727-y

KAISER M， WÜRTH C， KRAFT M， et al. Explaining the influence of dopant concentration and excitation power density on the luminescence and brightness of β-NaYF4∶Yb3+，Er3+ nanoparticles： measurements and simulations ［J］. Nano Res.， 2019， 12（8）： 1871-1879. doi: 10.1007/s12274-019-2450-4http://dx.doi.org/10.1007/s12274-019-2450-4

ZHANG F， WAN Y， SHI Y F， et al. Ordered mesostructured rare-earth fluoride nanowire arrays with upconversion fluorescence ［J］. Chem. Mater.， 2008， 20（11）： 3778-3784. doi: 10.1021/cm800489ehttp://dx.doi.org/10.1021/cm800489e

FRENZEL F， WÜRTH C， DUKHNO O， et al. Multiband emission from single β-NaYF4（Yb， Er） nanoparticles at high excitation power densities and comparison to ensemble studies ［J］. Nano Res.， 2021， 14（11）： 4107-4115. doi: 10.1007/s12274-021-3350-yhttp://dx.doi.org/10.1007/s12274-021-3350-y

CHEN J， GAO Y X， WANG C， et al. Effective regulation of upconversion luminescence in NaErF4 and NaErF4@SiO2 core-shell particles ［J］. Ceram. Int.， 2022， 48（10）： 14315-14322. doi: 10.1016/j.ceramint.2022.01.321http://dx.doi.org/10.1016/j.ceramint.2022.01.321

GAO W， XING Y， CHEN B H， et al. Enhancing red upconversion emission in NaErF4@NaYF4 core-shell nanoparticles by introducing Yb3+ ions as energy trapping centers ［J］. J. Alloys Compd.， 2023， 936： 168371. doi: 10.1016/j.jallcom.2022.168371http://dx.doi.org/10.1016/j.jallcom.2022.168371

LIU Y F， PAN G C， GAO H P， et al. Single band red emission of Er3+ ions heavily doped upconversion nanoparticles realized by active-core/active-shell structure ［J］. Ceram. Int.， 2021， 47（13）： 18824-18830. doi: 10.1016/j.ceramint.2021.03.220http://dx.doi.org/10.1016/j.ceramint.2021.03.220

LI Q Q， XIE X Y， WU H， et al. Superenhancement photon upconversion nanoparticles for photoactivated nanocryometer ［J］. Nano Lett.， 2023， 23（8）： 3444-3450. doi: 10.1021/acs.nanolett.3c00495http://dx.doi.org/10.1021/acs.nanolett.3c00495

禹庭，郑成中，赵闪闪，等. Monte Carlo模拟在稀土掺杂发光材料能量传递机理研究中的应用进展［J］. 发光学报， 2022， 43（9）： 1390-1404. doi: 10.37188/cjl.20220188http://dx.doi.org/10.37188/cjl.20220188

YU T， ZHENG C Z， ZHAO S S， et al. Progress on application of monte carlo simulation in studying energy transfer mechanisms for rare-earth luminescent materials ［J］. Chin. J. Lumin.， 2022， 43（9）： 1390-1404. （in Chinese）. doi: 10.37188/cjl.20220188http://dx.doi.org/10.37188/cjl.20220188

ANGELI G K， BATZAVALI D， MAVRONASOU K， et al. Remarkable structural diversity between Zr/Hf and rare-earth MOFs via ligand functionalization and the discovery of unique （4， 8）-c and （4， 12）-connected frameworks ［J］. J. Am. Chem. Soc.， 2020， 142（37）： 15986-15994. doi: 10.1021/jacs.0c07081http://dx.doi.org/10.1021/jacs.0c07081

ARTIUSHENKO O， ÁVILA E P， NAZARKOVSKY M， et al. Reusable hydroxamate immobilized silica adsorbent for dispersive solid phase extraction and separation of rare earth metal ions ［J］. Sep. Purif. Technol.， 2020， 231： 115934-1-10. doi: 10.1016/j.seppur.2019.115934http://dx.doi.org/10.1016/j.seppur.2019.115934

YAO X T， ZHEN H R， ZHANG D F， et al. Microwave-assisted hydrothermal synthesis of broadband Yb3+/Er3+ co-doped BiOI/Bi2O4 photocatalysts with synergistic effects of upconversion and direct Z-scheme heterojunction ［J］. Colloids Surf. A Physicochem. Eng. Aspects， 2022， 648： 129276. doi: 10.1016/j.colsurfa.2022.129276http://dx.doi.org/10.1016/j.colsurfa.2022.129276

LIAO C， ZHAO X R， JIANG X Y， et al. Hydrothermal fabrication of novel three-dimensional graphene oxide-pentaerythritol composites with abundant oxygen-containing groups as efficient adsorbents ［J］. Microchem. J.， 2020， 152： 104288-1-7. doi: 10.1016/j.microc.2019.104288http://dx.doi.org/10.1016/j.microc.2019.104288

SALTON I， IOFFE K， BURSHTEIN T Y， et al. Lanthanoid coordination compounds as diverse self-templating agents towards hierarchically porous Fe-N-C electrocatalysts ［J］. Mater. Adv.， 2022， 3（21）： 7937-7945. doi: 10.1039/d2ma00596dhttp://dx.doi.org/10.1039/d2ma00596d

相国涛，刘小桐，夏清，等. β-NaYF4∶Yb3+ /Er3+@β-NaYF4∶Yb3+的上转换发光特性［J］. 发光学报， 2020， 41（6）： 679-683. doi: 10.3788/fgxb20204106.0679http://dx.doi.org/10.3788/fgxb20204106.0679

XIANG G T， LIU X T， XIA Q， et al. Upconversion luminescence properties of β-NaYF4∶Yb3+ /Er3+ @β-NaYF4∶Yb3+ ［J］. Chin. J. Lumin.， 2020， 41（6）： 679-683. （in Chinese）. doi: 10.3788/fgxb20204106.0679http://dx.doi.org/10.3788/fgxb20204106.0679

ZHANG Y， XU S， LI X， et al. Concentration quenching of blue upconversion luminescence in Tm3+/Yb3+ co-doped Gd2⁃（WO4）3 phosphors under 980 and 808 nm excitation ［J］. J. Alloys Compd.， 2017， 709： 147-157. doi: 10.1016/j.jallcom.2017.03.125http://dx.doi.org/10.1016/j.jallcom.2017.03.125

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Related Institution

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School of Optics and Photonics, Beijing Institute of Technology

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⁰

Back Energy Transfer Enhances Er3+ Upconversion Luminescence

DOI：10.37188/CJL.20230100

摘要

Abstract

关键词

Keywords

references

Back Energy Transfer Enhances Er³⁺ Upconversion Luminescence