Calculation and Prediction of Quenching Concentration of Nd<sup>3+</sup>-doped Phosphate Laser Glass

WAN Jie; OUYANG Sha; JI Yao; DUAN Taiyu; WANG Weichao

doi:10.37188/CJL.20230042

您当前的位置：

首页 >

文章列表页 >

Calculation and Prediction of Quenching Concentration of Nd³⁺-doped Phosphate Laser Glass

Theoretical Calculation and Spectral Analysis | 更新时间：2023-10-27

- Calculation and Prediction of Quenching Concentration of Nd³⁺-doped Phosphate Laser Glass
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 6, Pages: 1042-1050(2023)
- 作者机构：
  
  华南理工大学物理与光电学院，发光材料与器件国家重点实验室，广东省光纤激光材料与应用技术重点实验室，广东广州　510640
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation ofChina(52172003)
- DOI：10.37188/CJL.20230042
  CLC： O482.31
- Published：05 June 2023，
  
  Received：20 February 2023，
  
  Revised：09 March 2023，
- 稿件说明：
移动端阅览
万杰,欧阳莎,姬瑶等.Nd³⁺掺杂磷酸盐激光玻璃猝灭浓度的计算与预测[J].发光学报,2023,44(06):1042-1050.

WAN Jie,OUYANG Sha,JI Yao,et al.Calculation and Prediction of Quenching Concentration of Nd³⁺-doped Phosphate Laser Glass[J].Chinese Journal of Luminescence,2023,44(06):1042-1050.
万杰,欧阳莎,姬瑶等.Nd³⁺掺杂磷酸盐激光玻璃猝灭浓度的计算与预测[J].发光学报,2023,44(06):1042-1050. DOI： 10.37188/CJL.20230042.

WAN Jie,OUYANG Sha,JI Yao,et al.Calculation and Prediction of Quenching Concentration of Nd³⁺-doped Phosphate Laser Glass[J].Chinese Journal of Luminescence,2023,44(06):1042-1050. DOI： 10.37188/CJL.20230042.

摘要

通过研究稀土离子在玻璃中激发态布居数与掺杂浓度之间的关系，建立了一种半定量的激光玻璃发光猝灭浓度预测的研究方法。研究发现，在Nd

掺杂磷酸盐玻璃中，无辐射跃迁速率与浓度的线性相关性大于其与浓度的平方相关性，表明OH

对无辐射跃迁几率的影响大于稀土离子之间的能量传递过程。选择低浓度下的荧光寿命代替自发辐射跃迁寿命预测猝灭浓度，有效降低了多声子弛豫以及OH

的影响，预测发光猝灭浓度与实验值的绝对误差从0.82%降低到了0.16%。本文所提出的预测计算方法具有较高的准确性和普适性，这为理论预测激光玻璃的猝灭浓度提供了一定的指导意义，有助于新型激光玻璃的研究和探索。

Abstract

There is a critical value of quenching concentration or optimal doping concentration in the laser glass due to the concentration quenching effect. It is particularly important to quickly and effectively determine the luminescent quenching concentration. In this paper， a semi-quantitative method is established for predicting the quenching concentration of laser glass by studying the relationship between the population of excited states of rare earth ions in glass and the doping concentration. It is found that the linear correlation between the transition rate of spontaneous emission and doping concentration is greater than its squared correlation with a concentration in Nd

-doped phosphate glass. This indicates that OH

affects more to the transition probability of spontaneous emission than the energy transfer process between rare earth ions. The fluorescence lifetime at low concentration is selected instead of the spontaneous radiative lifetime to predict the quenching concentration， which effectively reduced the influence of multi-phonon relaxation and OH

， and the absolute error between the predicted luminescence quenching concentration and the experimental value was reduced from 0.82% to 0.16%. The proposed prediction calculation method has high accuracy and strong universality. This work guides determining the quenching concentration of laser glass and is beneficial to the research and exploration of a new type of laser glass.

关键词

磷酸盐玻璃Nd3+猝灭浓度理论计算

Keywords

phosphate glassNd3+quenching concentrationtheoretical calculation

references

张炳涛，陈月娥，赵兹罡，等. 有源光纤的进展与应用［J］. 应用物理， 2018， 8（5）： 256-268. doi: 10.12677/APP.2018.85032http://dx.doi.org/10.12677/APP.2018.85032

ZHANG B T， CHEN Y E， ZHAO Z G， et al. Progress and applications of active optical fibers ［J］. Appl. Phys.， 2018， 8（5）： 256-268. （in Chinese）. doi: 10.12677/APP.2018.85032http://dx.doi.org/10.12677/APP.2018.85032

BALLATO J， DRAGIC P D. Glass： the carrier of light：a brief history of optical fiber ［J］. Int. J. Appl. Glass Sci.， 2016， 7（4）： 413-422. doi: 10.1111/ijag.12239http://dx.doi.org/10.1111/ijag.12239

BALLATO J， DRAGIC P D. Glass： The carrier of light：Part Ⅱ：a brief look into the future of optical fiber ［J］. Int. J. Appl. Glass Sci.， 2021， 12（1）： 3-24. doi: 10.1111/ijag.15844http://dx.doi.org/10.1111/ijag.15844

ZHANG Q Y， HU L L， JIANG Z H. Thermodynamic study on elimination of platinum inclusions in phosphate laser glasses for inertial confinement fusion applications ［J］. Chin. Sci. Bull.， 1999， 44（7）： 664-668. doi: 10.1007/bf03182732http://dx.doi.org/10.1007/bf03182732

JIANG Z H， ZHANG Q Y. The formation of glass： a quantitative perspective ［J］. Sci. China Mater.， 2015， 58（5）： 378-425. doi: 10.1007/s40843-015-0048-zhttp://dx.doi.org/10.1007/s40843-015-0048-z

钱奇，杨中民. Yb3+掺杂磷酸盐玻璃光纤与1.06 μm单频激光器的研制［J］. 光学学报， 2010， 30（7）： 1904-1909. doi: 10.3788/aos20103007.1904http://dx.doi.org/10.3788/aos20103007.1904

QIAN Q， YANG Z M. Yb3+-doped phosphate glass fiber and 1.06 μm single-frequency fiber laser ［J］. Acta Opt. Sinica， 2010， 30（7）： 1904-1909. doi: 10.3788/aos20103007.1904http://dx.doi.org/10.3788/aos20103007.1904

MYSLINSKI P， NGUYEN D， CHROSTOWSKI J. Effects of concentration on the performance of erbium-doped fiber amplifiers ［J］. J. Lightwave Technol.， 1997， 15（1）： 112-120. doi: 10.1109/50.552118http://dx.doi.org/10.1109/50.552118

CAMPBELL J H， SURATWALA T I. Nd-doped phosphate glasses for high-energy/high-peak-power lasers ［J］. J. Non⁃Cryst. Solids， 2000， 263-264： 318-341. doi: 10.1016/s0022-3093(99)00645-6http://dx.doi.org/10.1016/s0022-3093(99)00645-6

HOUDE-WALTER S N， PETERS P M， STEBBINS J F， et al. Hydroxyl-contents and hydroxyl-related concentration quenching in erbium-doped aluminophosphate， aluminosilicate and fluorosilicate glasses ［J］. J. Non⁃Cryst. Solids， 2001， 286（1-2）： 118-131. doi: 10.1016/s0022-3093(00)00445-2http://dx.doi.org/10.1016/s0022-3093(00)00445-2

WANG X， ZHANG R L， REN J J， et al. Mechanism of cluster dissolution of Yb-doped high-silica lanthanum aluminosilicate glass： investigation by spectroscopic and structural characterization ［J］. J. Alloys Compd.， 2017， 695： 2339-2346. doi: 10.1016/j.jallcom.2016.11.104http://dx.doi.org/10.1016/j.jallcom.2016.11.104

WANG R S， MENG X W， YIN F X， et al. Heavily erbium-doped low-hydroxyl fluorotellurite glasses for 2.7 μm laser applications ［J］. Opt. Mater. Express， 2013， 3（8）： 1127-1136. doi: 10.1364/ome.3.001127http://dx.doi.org/10.1364/ome.3.001127

NOVAIS A L F， DANTAS N O， GUEDES I， et al. Spectroscopic properties of highly Nd-doped lead phosphate glass ［J］. J. Alloys Compd.， 2015， 648： 338-345. doi: 10.1016/j.jallcom.2015.06.148http://dx.doi.org/10.1016/j.jallcom.2015.06.148

VAN UITERT L G. Characterization of energy transfer interactions between rare earth ions ［J］. J. Electrochem. Soc.， 1967， 114（10）： 1048-1053. doi: 10.1149/1.2424184http://dx.doi.org/10.1149/1.2424184

AUZEL F， BONFIGLI F， GAGLIARI S， et al. The interplay of self-trapping and self-quenching for resonant transitions in solids； role of a cavity ［J］. J. Lumin.， 2001， 94-95： 293-297. doi: 10.1016/s0022-2313(01)00308-8http://dx.doi.org/10.1016/s0022-2313(01)00308-8

INOKUTI M， HIRAYAMA F. Influence of energy transfer by the exchange mechanism on donor luminescence ［J］. J. Chem. Phys.， 1965， 43（6）： 1978-1989. doi: 10.1063/1.1697063http://dx.doi.org/10.1063/1.1697063

BURSHTEIN A I. Hopping mechanism of energy transfer ［J］. J. Exp. Theor. Phys.， 1972， 35（5）： 882-885.

黄莉蕾，陈晓竹. 激光晶体YAG中Er3+离子最佳掺杂浓度［J］. 中国计量学院学报， 1996（2）： 15-20.

HUANG L L， CHEN X Z. Optimal concentrations doped https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=49199657&type=https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=49199644&type=https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=49199642&type=4.621000293.440000533.175 ions in YAG laser crystal ［J］. J. China Instit. Univ.， 1996（2）： 15-20. （in Chinese）

李威，陈长水，韦俊雄，等. 激光陶瓷晶体最佳掺杂浓度的理论研究［J］. 物理学报， 2014， 63（8）： 087801-1-7. doi: 10.7498/aps.63.087801http://dx.doi.org/10.7498/aps.63.087801

LI W， CHEN C S， WEI J X， et al. Theoretical study of optimal doping concentration in laser ceramics ［J］. Acta Phys. Sinica， 2014， 63（8）： 087801-1-7. doi: 10.7498/aps.63.087801http://dx.doi.org/10.7498/aps.63.087801

RAVAGLI A， BOETTI N G， CRUZ F A G， et al. Structural and spectral characterisation of Er3+ and Nd3+ doped Ga-La-S-Se glasses ［J］. RSC Adv.， 2018， 8（48）： 27556-27564.

万杰，欧阳莎，姬瑶，等. Er3+掺杂锗酸盐激光玻璃猝灭浓度的计算与预测［J］. 发光学报， 2023， doi： 10.37188/CJL.20230014http://dx.doi.org/10.37188/CJL.20230014.

WAN J， OUYANG S， JI Y， et al. Calculation and prediction of quenching concentration of Er3+-doped germanate glass ［J］. Chin. J. Lumin.， 2023， doi： 10.37188/CJL.20230014.http://dx.doi.org/10.37188/CJL.20230014.（in Chinese）

KESAVULU C R， SREEDHAR V B， JAYASANKAR C K， et al. Structural， thermal and spectroscopic properties of highly Er3+-doped novel oxyfluoride glasses for photonic application ［J］. Mater. Res. Bull.， 2014， 51： 336-344. doi: 10.1016/j.materresbull.2013.12.023http://dx.doi.org/10.1016/j.materresbull.2013.12.023

ZHAO Y G， SHI D M. Effect of alkali metal oxides R2O（R=Na， K） on 1.53 μm luminescence of Er3+-doped Ga2O3-GeO2 glasses for optical amplification ［J］. J. Rare Earths， 2013， 31（9）： 857-863. doi: 10.1016/s1002-0721(12)60370-6http://dx.doi.org/10.1016/s1002-0721(12)60370-6

LIU J L， XIAO Y B， HUANG S J， et al. The glass-forming region and 2.7 μm emission of Er3+-doped TeO2-Ta2O5-ZnO tellurite glass ［J］. J. Non⁃Cryst. Solids， 2019， 522： 119564-1-8. doi: 10.1016/j.jnoncrysol.2019.119564http://dx.doi.org/10.1016/j.jnoncrysol.2019.119564

钱国权，唐国武，吴敏波，等. Tm3+掺杂玻璃光纤研究进展［J］. 硅酸盐通报， 2021， 40（8）： 2471-2484.

QIAN G Q， TANG G W， WU M B， et al. Research progress of Tm3+-doped glass fibers ［J］. Bull. Chin. Ceramic Soc.， 2021， 40（8）： 2471-2484. （in Chinese）

FENG X， TANABE S， HANADA T. Hydroxyl groups in erbium-doped germanotellurite glasses ［J］. J. Non⁃Cryst.Solids， 2001， 281（1-3）： 48-54. doi: 10.1016/s0022-3093(00)00429-4http://dx.doi.org/10.1016/s0022-3093(00)00429-4

刘永皓，徐权. 不同Er3+离子掺杂浓度下硼铋酸盐玻璃荧光浓度猝灭研究［J］. 齐齐哈尔大学学报， 2010， 26（2）： 41-45. doi: 10.3969/j.issn.1007-984X.2010.02.011http://dx.doi.org/10.3969/j.issn.1007-984X.2010.02.011

LIU Y H， XU Q. The effect of Er3+ concentrations on the fluorescence concentration quenching in bismuth borate glasses ［J］. J. Qiqihar Univ.， 2010， 26（2）： 41-45. （in Chinese）. doi: 10.3969/j.issn.1007-984X.2010.02.011http://dx.doi.org/10.3969/j.issn.1007-984X.2010.02.011

WANG W C， ZHOU B， XU S H， et al. Recent advances in soft optical glass fiber and fiber lasers ［J］. Prog. Mater. Sci.， 2019， 101： 90-171. doi: 10.1016/j.pmatsci.2018.11.003http://dx.doi.org/10.1016/j.pmatsci.2018.11.003

Views

395

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Calculation and Prediction of Quenching Concentration of Er³⁺-doped Germanate Glass

Effect of Yb³⁺/Nd³⁺ Doped on Luminescent Properties of Sr₉Ga(PO₄)₇∶Cr³⁺

YAG:Ce,Yb Nano-phosphor Synthesized by Sol-gel Method and Its Luminescence Properties

Related Author

WAN Jie

OUYANG Sha

JI Yao

DUAN Taiyu

WANG Weichao

WAN Jie

WANG Weichao

XIE Xin

Related Institution

State Key Laboratory of Luminescent Materials and Devices， Guangdong Provincial Key Laboratory ofFiber Laser Materials and Applied Techniques， School of Physics and Optoelectronics， South China University of Technology

School of Materials Science and Engineering， Shaanxi University of Science and Technology

中国科学院大学

中国科学院南京天文光学技术研究所天文光学技术重点实验室

中国科学院国家天文台南京天文光学技术研究所

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Calculation and Prediction of Quenching Concentration of Nd3+-doped Phosphate Laser Glass

DOI：10.37188/CJL.20230042

摘要

Abstract

关键词

Keywords

references

Calculation and Prediction of Quenching Concentration of Nd³⁺-doped Phosphate Laser Glass