Enhancing Thermal Stability of Li3Cs2Ba2-<italic style="font-style: italic">x</italic>Sr<italic style="font-style: italic">x</italic>B3P6O24∶Eu2+ Phosphor <italic style="font-style: italic">via</italic> Cation Substitution

SUO Huixian; SONG Zhi; KANG Xiaojiao; LI Xinming; ZHOU Fei; LYU Wei

doi:10.37188/CJL.20220407

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Enhancing Thermal Stability of Li₃Cs₂Ba_2-_xSr_xB₃P₆O₂₄∶Eu²⁺ Phosphor via Cation Substitution

Synthesis and Properties of Materials | 更新时间：2023-06-15

- Enhancing Thermal Stability of Li₃Cs₂Ba_2-_xSr_xB₃P₆O₂₄∶Eu²⁺ Phosphor via Cation Substitution
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 5, Pages: 837-844(2023)
- 作者机构：
  
  1.东莞理工学院电子工程与智能化学院，广东东莞　523808
  2.华南师范大学信息光电子科技学院，广东省微纳光子功能材料与器件重点实验室，广东广州　510006
- 作者简介：
- 基金信息：
  
  Dongguan Science and Technology of Social Development Program(20221800905152);Dongguan Sci-tech Commissoner Program(20221800500192);Guangdong Provincial Key Laboratory of Intelligent Disaster Prevention and Emergency Technologies for Urban Lifeline Engineering(2022B1212010016)
- DOI：10.37188/CJL.20220407
  CLC： O482.31
- Published：05 May 2023，
  
  Received：08 December 2022，
  
  Revised：16 December 2022，
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索慧娴,宋志,康晓娇等.阳离子替换提升Li₃Cs₂Ba_2-_xSr_xB₃P₆O₂₄∶Eu²⁺荧光粉热稳定性[J].发光学报,2023,44(05):837-844.

SUO Huixian,SONG Zhi,KANG Xiaojiao,et al.Enhancing Thermal Stability of Li₃Cs₂Ba_2-_xSr_xB₃P₆O₂₄∶Eu²⁺ Phosphor via Cation Substitution[J].Chinese Journal of Luminescence,2023,44(05):837-844.
索慧娴,宋志,康晓娇等.阳离子替换提升Li₃Cs₂Ba_2-_xSr_xB₃P₆O₂₄∶Eu²⁺荧光粉热稳定性[J].发光学报,2023,44(05):837-844. DOI： 10.37188/CJL.20220407.

SUO Huixian,SONG Zhi,KANG Xiaojiao,et al.Enhancing Thermal Stability of Li₃Cs₂Ba_2-_xSr_xB₃P₆O₂₄∶Eu²⁺ Phosphor via Cation Substitution[J].Chinese Journal of Luminescence,2023,44(05):837-844. DOI： 10.37188/CJL.20220407.

摘要

热猝灭性能极大程度上限制了发光材料的应用，如何改善发光材料的热稳定性这一课题受到了广泛关注。本文通过高温固相法制备了一系列浓度梯度的Li

∶0.03Eu

荧光粉，并对该系列荧光粉进行了表征，对其XRD、激发发射光谱、荧光寿命、热猝灭性能进行了分析。结果表明，通过阳离子Sr替代Ba的方法不但改善了晶格结构，提升了样品的发光强度，而且使原发光材料的热稳定性能进一步得到了提高。对于Li

∶Eu

样品，在150 ℃下的发光强度已经可以达到常温下的79%，通过Sr替换Ba，该强度能够进一步提高到87%。相关分析及结论可为荧光粉热稳定性的改善提供思路与依据。

Abstract

One of the more critical attributes of inorganic phosphors is the thermal quenching properties. In this study， we attempt to improve the photoluminescence and thermal quenching behavior by cation substitution. The optical， structural property， the thermal stability， and lifetime decay properties of phosphors were investigated. The results indicate that Sr substitution of Ba in Li

∶Eu

system could not only improve the luminous efficiency but also achieve better thermal stability at high temperature. This new series of blue luminescent materials have potential applications in LED applications. More importantly， we demonstrate a strategy to develop highly efficient， thermally stable phosphors.

关键词

荧光粉Eu2+掺杂温度猝灭阳离子替换

Keywords

phosphorEu2+thermal quenchingcation substitution

references

FANG M H， BAO Z， HUANG W T， et al. Evolutionary generation of phosphor materials and their progress in future applications for light-emitting diodes ［J］. Chem. Rev.， 2022， 122（13）： 11474-11513. doi: 10.1021/acs.chemrev.1c00952http://dx.doi.org/10.1021/acs.chemrev.1c00952

QIAO J W， ZHAO J， LIU Q L， et al. Recent advances in solid-state LED phosphors with thermally stable luminescence ［J］. J. Rare Earths， 2019， 37（6）： 565-572. doi: 10.1016/j.jre.2018.11.001http://dx.doi.org/10.1016/j.jre.2018.11.001

DANG P P， WANG W， LIAN H Z， et al. How to obtain anti-thermal-quenching inorganic luminescent materials for light-emitting diode applications ［J］. Adv. Opt. Mater.， 2022， 10（6）： 2102287-1-18. doi: 10.1002/adom.202102287http://dx.doi.org/10.1002/adom.202102287

张曦月，张乐，孙炳恒，等. 高功率密度激发荧光材料的反常热猝灭效应［J］. 发光学报， 2021， 42（10）： 1458-1481. doi: 10.37188/CJL.20210202http://dx.doi.org/10.37188/CJL.20210202

ZHANG X Y， ZHANG L， SUN B H， et al. Abnormal thermal quenching effect of high power density excited fluorescent materials ［J］. Chin. J. Lumin.， 2021， 42（10）： 1458-1481. （in Chinese）. doi: 10.37188/CJL.20210202http://dx.doi.org/10.37188/CJL.20210202

KIM Y H， ARUNKUMAR P， KIM B Y， et al. A zero-thermal-quenching phosphor ［J］. Nat. Mater.， 2017， 16（5）： 543-550. doi: 10.1038/nmat4843http://dx.doi.org/10.1038/nmat4843

ZHONG J Y， ZHAO W R， DU F， et al. Identifying the emission centers and probing the mechanism for highly efficient and thermally stable luminescence in the La3Si6N11∶Ce3+ phosphor ［J］. J. Phys. Chem. C， 2018， 122（14）： 7849-7858. doi: 10.1021/acs.jpcc.8b00683http://dx.doi.org/10.1021/acs.jpcc.8b00683

WEI Y， CAO L， LV L M， et al. Highly efficient blue emission and superior thermal stability of BaAl12O19∶Eu2+ phosphors based on highly symmetric crystal structure ［J］. Chem. Mater.， 2018， 30（7）： 2389-2399. doi: 10.1021/acs.chemmater.8b00464http://dx.doi.org/10.1021/acs.chemmater.8b00464

HE S， ZHANG L L， WU H， et al. Efficient super broadband NIR Ca2LuZr2Al3O12∶Cr3+，Yb3+ garnet phosphor for pc-LED light source toward NIR spectroscopy applications ［J］. Adv. Opt. Mater.， 2020， 8（6）： 1901684-1-7. doi: 10.1002/adom.201901684http://dx.doi.org/10.1002/adom.201901684

KIM Y H， KIM H J， ONG S P， et al. Cation-size mismatch as a design principle for enhancing the efficiency of garnet phosphors ［J］. Chem. Mater.， 2020， 32（7）： 3097-3108. doi: 10.1021/acs.chemmater.0c00095http://dx.doi.org/10.1021/acs.chemmater.0c00095

LIU H M， LIANG H W， ZHANG W Y， et al. Improving the thermal stability and luminescent efficiency of （Ba， Sr）3SiO5∶Eu2+ phosphors by structure， bandgap engineering and soft chemistry synthesis method ［J］. Chem. Eng. J.， 2021， 410： 128367-1-9. doi: 10.1016/j.cej.2020.128367http://dx.doi.org/10.1016/j.cej.2020.128367

KHAN M A， LI Y Y， LIN H， et al. Syntheses of six and twelve membered borophosphate ring structure with nonlinear optical activity ［J］. J. Solid State Chem.， 2016， 243： 259-266. doi: 10.1016/j.jssc.2016.05.030http://dx.doi.org/10.1016/j.jssc.2016.05.030

王一航，连雪珠，徐华伟，等. 热稳定性优异的单一基质白光Cs2Li3Sr2B3（PO4）6∶Dy3+荧光粉发光性能［J］. 发光学报， 2022， 43（5）： 676-683.

WANG Y H， LIAN X Z， XU H W， et al. Single-phase white light-emitting phosphor Cs2Li3Sr2B3（PO4）6∶Dy3+ with excellent thermal stability ［J］. Chin. J. Lumin.， 2022， 43（5）： 676-683. （in Chinese）

ZHANG L J， LI Y Y， LIU P F， et al. Li3Cs2M2B3P6O24 （M=Pb， Sr）： borophosphates with double six-membered ring of ［BP2O8］3- ［J］. Dalton Trans.， 2016， 45（16）： 7124-7130. doi: 10.1039/c6dt00498ahttp://dx.doi.org/10.1039/c6dt00498a

CHEN H， DING J Y， DING X， et al. Synthesis， crystal structure， and luminescence properties of tunable red-emitting nitride solid solutions （Ca1–xSrx）16Si17N34∶Eu2+ for white LEDs ［J］. Inorg. Chem.， 2017， 56（18）： 10904-10913. doi: 10.1021/acs.inorgchem.7b01021http://dx.doi.org/10.1021/acs.inorgchem.7b01021

XIA Z G， ZHUANG J Q， LIAO L B， et al. Synthesis and luminescence properties of Ba2Gd（BO3） 2Cl∶Eu2+ phosphor ［J］. J. Electrochem. Soc.， 2011， 158（11）： J359-J362. doi: 10.1149/2.050111jeshttp://dx.doi.org/10.1149/2.050111jes

WANG X C， ZHAO Z Y， WU Q S， et al. Synthesis， structure， and luminescence properties of SrSiAl2O3N2∶Eu2+ phosphors for light-emitting devices and field emission displays ［J］. Dalton Trans.， 2015， 44（24）： 11057-11066. doi: 10.1039/c5dt00800jhttp://dx.doi.org/10.1039/c5dt00800j

YANG Z Y， ZHAO Y F， ZHOU Y Y， et al. Giant red-shifted emission in （Sr， Ba）Y2O4∶Eu2+ phosphor toward broadband near-infrared luminescence ［J］. Adv. Funct. Mater.， 2022， 32（1）： 2103927-1-12. doi: 10.1002/adfm.202103927http://dx.doi.org/10.1002/adfm.202103927

LIU D J， YUN X H， DANG P P， et al. Yellow/orange-emitting ABZn2Ga2O7∶Bi3+ （A= Ca， Sr； B= Ba， Sr） phosphors： optical temperature sensing and white light-emitting diode applications ［J］. Chem. Mater.， 2020， 32（7）： 3065-3077. doi: 10.1021/acs.chemmater.0c00054http://dx.doi.org/10.1021/acs.chemmater.0c00054

SUN X K， HUANG Z Z， FU X H， et al. Generation of warm white light by doping Sm3+ in Ca3TeO6∶Dy3+ fluorescent powders ［J］. Ceram. Int.， 2020， 46（9）： 14252-14256. doi: 10.1016/j.ceramint.2020.02.058http://dx.doi.org/10.1016/j.ceramint.2020.02.058

LÜ W， HAO Z D， ZHANG X， alet， et al. Eu2+-activated Ca8Zn（SiO4）4Cl2： an intense green emitting phosphor for blue light emitting diodes ［J］. J. Electrochem. Soc.， 2011， 158（2）： H124-H127.

赵旺，平兆艳，郑庆华，等. 白光发光二极管用SrGdLiTeO6∶Eu3+红色荧光粉的浓度猝灭和温度猝灭行为［J］. 物理学报， 2018， 67（24）： 247801-1-10.

ZHAO W， PING Z Y， ZHENG Q H， et al. Concentration and thermal quenching of SrGdLiTeO6∶Eu3+ red-emitting phosphor for white light-emitting diode ［J］. Acta Phys. Sinica， 2018， 67（24）： 247801-1-10. （in Chinese）

WANG D， YIN Q R， LI Y X， et al. Concentration quenching of Eu2+ in SrO·Al2O3∶Eu2+ phosphor［J］. J. Lumin.， 2002， 97（1）： 1-6. doi: 10.1016/s0022-2313(01)00413-6http://dx.doi.org/10.1016/s0022-2313(01)00413-6

LONG J Q， CHU F J， WANG Y Z， et al. M8MgSc（PO4）7∶xDy3+ （M= Ca/Sr） single-phase full-color phosphor with high thermal emission stability ［J］. Inorg. Chem.， 2017， 56（17）： 10381-10386. doi: 10.1021/acs.inorgchem.7b01268http://dx.doi.org/10.1021/acs.inorgchem.7b01268

QIN C X， HUANG Y L， SHI L， et al. Thermal stability of luminescence of NaCaPO4∶Eu2+ phosphor for white-light-emitting diodes ［J］. J. Phys. D： Appl. Phys.， 2009， 42（18）： 185105-1-5. doi: 10.1088/0022-3727/42/18/185105http://dx.doi.org/10.1088/0022-3727/42/18/185105

LIN Y C， BETTINELLI M， KARLSSON M， et al. Unraveling the mechanisms of thermal quenching of luminescence in Ce3+-doped garnet phosphors ［J］. Chem. Mater.， 2019， 31（11）： 3851-3862. doi: 10.1021/acs.chemmater.8b05300http://dx.doi.org/10.1021/acs.chemmater.8b05300

ZHANG S Y， HUANG Y L， NAKAI Y， et al. The luminescence characterization and thermal stability of Eu2+ ions-doped NaBaPO4 phosphor ［J］. J. Am. Ceram. Soc.， 2011， 94（9）： 2987-2992. doi: 10.1111/j.1551-2916.2011.04481.xhttp://dx.doi.org/10.1111/j.1551-2916.2011.04481.x

LIN Y C， KARLSSON M， BETTINELLI M， et al. Inorganic phosphor materials for lighting ［J］. Top. Curr. Chem.， 2016， 374（2）： 21-1-47. doi: 10.1007/s41061-016-0023-5http://dx.doi.org/10.1007/s41061-016-0023-5

KHAN W U， KHAN W U， PENG Y， et al. Robust thermal performance of red-emitting phosphor composites for white light-emitting diodes： energy transfer and oxygen-vacancy induced electronic localization ［J］. J. Colloid Interface Sci.， 2021， 600： 219-228. doi: 10.1016/j.jcis.2021.04.139http://dx.doi.org/10.1016/j.jcis.2021.04.139

BLASSE G. Thermal quenching of characteristic fluorescence ［J］. J. Chem. Phys.， 1969， 51（8）： 3529-3530. doi: 10.1063/1.1672543http://dx.doi.org/10.1063/1.1672543

POORT S H M， JANSSEN W， BLASSE G. Optical properties of Eu2+-activated orthosilicates and orthophosphate s［J］. J. Alloys Compd.， 1997， 260（1-2）： 93-97. doi: 10.1016/s0925-8388(97)00140-0http://dx.doi.org/10.1016/s0925-8388(97)00140-0

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Related Institution

School of Electrical Engineering and Intelligentization， Dongguan University of Technology

Guangdong Provincial Key Laboratory of Nanophotonic Functional Materials and Devices， School of Information and Optoelectronic Science and Engineering， South China Normal University

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State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences， Changchun 130033， China

School of Mechanical Engineering， Qinghai University

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⁰

Enhancing Thermal Stability of Li3Cs2Ba2-xSrxB3P6O24∶Eu2+ Phosphor via Cation Substitution

DOI：10.37188/CJL.20220407

摘要

Abstract

关键词

Keywords

references

Enhancing Thermal Stability of Li₃Cs₂Ba_2-_xSr_xB₃P₆O₂₄∶Eu²⁺ Phosphor via Cation Substitution