Tunable Photoluminescence Properties and Energy Transfer of Ba3YB9O18:Tb3+, Eu3+ Phosphors

Zhi-hua LENG; Zhe TAN; Shu-hong LIU

doi:10.37188/CJL.20200260

您当前的位置：

首页 >

文章列表页 >

Tunable Photoluminescence Properties and Energy Transfer of Ba₃YB₉O₁₈:Tb³⁺, Eu³⁺ Phosphors

Synthesis and Properties of Materials | 更新时间：2021-01-12

- Tunable Photoluminescence Properties and Energy Transfer of Ba₃YB₉O₁₈:Tb³⁺, Eu³⁺ Phosphors
- Chinese Journal of Luminescence Vol. 42, Issue 1, Pages: 83-90(2021)
- 作者机构：
  
  1.西安建筑科技大学化学与化工学院, 陕西西安 710055
  2.吉林大学化学学院, 吉林长春 130012
- 作者简介：
- 基金信息：
  
  the the Natural Science Foundation of Shaanxi Provincial Department of Education
- DOI：10.37188/CJL.20200260
  CLC： O482.31;O611.4
- Received：31 August 2020，
  
  Accepted：20 September 2020，
  
  Published：2021-01
- 稿件说明：
移动端阅览
Zhi-hua LENG, Zhe TAN, Shu-hong LIU. Tunable Photoluminescence Properties and Energy Transfer of Ba₃YB₉O₁₈:Tb³⁺, Eu³⁺ Phosphors[J]. Chinese Journal of Luminescence, 2021, 42(1): 83-90.
DOI：

Zhi-hua LENG, Zhe TAN, Shu-hong LIU. Tunable Photoluminescence Properties and Energy Transfer of Ba₃YB₉O₁₈:Tb³⁺, Eu³⁺ Phosphors[J]. Chinese Journal of Luminescence, 2021, 42(1): 83-90. DOI： 10.37188/CJL.20200260.

摘要

利用高温固相法制备了一系列发光颜色可调的Ba

：Tb

，Eu

荧光粉。采用X射线衍射（XRD）、透射电子显微镜（TEM）研究了所得荧光粉的相纯度和晶体结构。XRD精修结果表明，当Y

被Eu

取代时，Ba

：Tb

，Eu

系列样品的线性结构变化能很好地符合Vegard定律。此外，通过发射光谱和荧光寿命验证了Ba

：Tb

，Eu

荧光粉中Tb

到Eu

的能量传递过程。Tb

到Eu

的能量传递机理为偶极-偶极相互作用。随着Eu

掺杂量的增加，荧光粉的发光颜色可以由绿色逐渐过渡到红色。这些结果表明合成的Ba

：Tb

，Eu

荧光粉在紫外光激发的固态照明领域具有潜在的应用前景。

Abstract

A series of Ba

:Tb

phosphors with tunable photoluminescence were successfully prepared by solid state reaction. X-ray diffraction(XRD) and transmission electron microscopy(TEM) were utilized to investigate the phase purity and crystal structure of the as-obtained phosphors. The XRD refinement results demonstrate that the linear structural evolution of Ba

:Tb

solid-solutions obeys excellent Vegard's rule when Y

were substituted by Eu

ions. Moreover

the energy transfer process from Tb

to Eu

in Ba

:Tb

phosphors was verified by emission spectra and decay curves. The energy transfer mechanism from Tb

to Eu

was proved to be the electric dipole-dipole interaction. Due to the energy transfer process from Tb

to Eu

the color tones can be gradually adjusted from green to red with increasing Eu

doping content. These results manifest that the as-synthesized Ba

:Tb

phosphors may find potential applications for UV excited solid state lighting.

关键词

Keywords

references

LIAO S Z, JI X Y, LIU Y F, et al .. Highly efficient and thermally stable blue-green (Ba 0.8 Eu 0.2 O)(Al 2 O 3 ) 4.575×(1+ x ) phosphor through structural modification[J]. ACS Appl. Mater. Interfaces , 2018, 10(45):39064-39073.

谢会东, 谭玉荣, 苏彬彬, 等. La 2- x-y MgTiO 6 : x Dy 3+ , y Eu 3+ 白色荧光粉的荧光性能及能量传递[J].发光学报, 2019, 40(6):713-718.

XIE H D, TAN Y R, SU B B, et al .. Luminescent properties and energy transfer of La 2- x-y MgTiO 6 : x Dy 3+ , y Eu 3+ white phosphors[J]. Chin. J. Lumin ., 2019, 40(6):713-718. (in Chinese)

谢会东, 郭韬, 苏彬彬, 等. La 2- x-y MgTiO 6 : x Bi 3+ , y Eu 3+ 荧光粉的性能和能量传递[J].硅酸盐学报, 2019, 47(8):1160-1166.

XIE H D, GUO T, SU B B, et al .. Luminescent performance and energy transfer of La 2- x-y MgTiO 6 : x Bi 3+ , y Eu 3+ phosphors[J]. J. Chin. Ceram. Soc ., 2019, 47(8):1160-1166. (in Chinese)

LENG Z H, LI R F, LI L P, et al .. Preferential neighboring substitution-triggered full visible spectrum emission in single-phased Ca 1 0.5- x Mg x (PO 4 ) 7 :Eu 2+ phosphors for high color-rendering white LEDs[J]. ACS Appl. Mater. Interfaces , 2018, 10(39):33322-33334.

赵亚娟, 王晓端, 伍孟林, 等.固相法制备新型红色荧光粉K 6 Ba 4 B 8 O 19 : x %Eu 3+ 的研究[J].光学学报, 2018, 38(5):0516001-1-5.

ZHAO Y J, WANG X D, WU M L, et al .. Study on preparation of novel red fluorescent powder of K 6 Ba 4 B 8 O 19 : x %Eu 3+ by solid phase method[J]. Acta Opt. Sinica , 2018, 38(5):0516001-1-5. (in Chinese)

张寒冰, 李成仁, 李淑凤, 等. Y 2 O 3 :Eu 3+ , Dy 3+ 纳米荧光粉的白光发射性能[J].高等学校化学学报, 2018, 39(2):193-199.

ZHANG H B, LI C R, LI S F, et al .. White light emission performance of Y 2 O 3 :Eu 3+ , Dy 3+ nanophosphors[J]. Chem. J. Chin. Univ ., 2018, 39(2):193-199. (in Chinese)

SONG M J, ZHAO W, RAN W G, et al .. Multicolor tunable luminescence and energy transfer mechanism in a novel single-phase KBaGd(WO 4 ) 3 :Tb 3+ , Eu 3+ phosphor for NUV WLEDs[J]. J. Alloys Compd ., 2019, 803:1063-1074.

DING X, WANG Y H. Commendable Eu 2+ -doped oxide-matrix-based LiBa 12 (BO 3 ) 7 F 4 red broad emission phosphor excited by NUV light:electronic and crystal structures, luminescence properties[J]. ACS Appl. Mater. Interfaces , 2017, 9(28):23983-23994.

WANG C Y, TAKEDA T, KATE O M T, et al .. Ce-doped La 3 Si 6.5 Al 1.5 N 9.5 O 5.5 , a rare highly efficient blue-emitting phosphor at short wavelength toward high color rendering white LED application[J]. ACS Appl. Mater. Interfaces , 2017, 9(27):22665-22675.

ZHANG S A, LI Y, LV Y, et al .. A full-color emitting phosphor Ca 9 Ce(PO 4 ) 7 :Mn 2+ , Tb 3+ :efficient energy transfer, stable thermal stability and high quantum efficiency[J]. Chem. Eng. J ., 2017, 322:314-327.

LI X Z, WANG C, CHEN X L, et al .. Syntheses, thermal stability, and structure determination of the novel isostructural R Ba 3 B 9 O 18 ( R =Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb)[J]. Inorg. Chem ., 2004, 43(26):8555-8560.

CAI G M, CHEN X L, WANG W Y, et al .. A new promising scintillator Ba 3 InB 9 O 18 [J]. J. Solid State Chem ., 2008, 181(3):646-651.

CAI G M, HE M, CHEN X L, et al .. Crystal structure and luminescence properties of a novel promising phosphor Ba 3 ScB 9 O 18 [J]. Powder Diff ., 2007, 22(4):328-333.

GAO D L, ZHANG X Y, ZHANG J S. The effects of structural characterization on the luminescence of Eu 3+ -doped fluoride nano/microcrystals[J]. CrystEngComm , 2014, 16(48):11115-11121.

LI F, XIE H D, XI H H, et al .. Luminescent properties of sol-gel processed red-emitting phosphor Ca 0.6 Sr 0.4-1.5 x -0.5 y Mo 0.4 -W 0.6 O 4 :Eu x Li y [J]. Luminescence , 2015, 30(5):600-604.

DONG J C, WANG X X, XIONG H L, et al .. Two-step synthetic route towards monodisperse vernier yttrium oxyfluoride with multicolour fluorescence[J]. J. Alloys Compd ., 2018, 739:972-978.

YANG J F, SONG L N, WANG X X, et al .. Facile synthesis and color-tunable properties of monodisperse β -NaYF 4 : Ln 3+ ( Ln =Eu, Tb, Tm, Sm, Ho) microtubes[J]. Dalton Trans ., 2018, 47(4):1294-1302.

LENG Z H, LI L P, CHE X L, et al .. A bridge role of Tb 3+ in broadband excited Sr 3 Y(PO 4 ) 3 :Ce 3+ , Tb 3+ , Sm 3+ phosphors with superior thermal stability[J]. Mater. Des ., 2017, 118:245-255.

ZHANG D, LI G S, YANG W, et al .. Tunable photoluminescence properties and energy transfer of Ca 5 (BO 3 ) 3 F:Tb 3+ /Eu 3+ phosphors for solid state lighting[J]. J. Lumin ., 2019, 208:155-163.

LI F, XIE H D, XI H H, et al .. Sol-gel preparation and luminescent properties of red-emitting phosphor Sr-Ba-Mo-W-O-(Eu 3+ , Sm 3+ )[J]. Luminescence , 2016, 31(1):217-222.

XIE H D, SU B B, TAN Y R, et al .. Effect of Gd 3+ , Bi 3+ , or Sm 3+ on luminescent properties of La 2- x MgTiO 6 : x Eu 3+ phosphors[J]. Luminescence , 2018, 33(8):1450-1455.

LENG Z H, YU G H, LI L L, et al .. Enhanced of Tb 3+ emission in KSr 4 (BO 3 ) 3 :Dy 3+ , Tb 3+ phosphors via energy transfer from Dy 3+ [J]. J. Alloys Compd ., 2015, 651:679-684.

DONG J C, LIU Y L, YANG J F, et al .. Monodisperse Na 0.39 Y 0.61 F 2 .35 : Ln 3+ ( Ln =Dy, Tb, Eu) and NaYF 4 nano-/micromaterials:controllable morphology, porous structure, tunable multicolor and energy transfer[J]. J. Lumin ., 2019, 207:397-407.

Views

292

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Energy Transfer and Photoluminescence Properties of Sr₆GdAl(BO₃)₆:Dy³⁺ Phosphor

Luminescence Properties of Eu³⁺， Dy³⁺， Na⁺ Doped Sr₃AlO₄F

Preparation and Characterization of Zn²⁺-doped MgGa₂O₄∶Ni²⁺ NIR-Ⅱ Phosphors and Their Application in Imaging

Photoluminescence Properties of Sr₆Lu₂Al₄O₁₅∶Tb³⁺ Phosphor

Related Author

Zhihua LENG

Zhe TAN

Shuhong LIU

MIN Rui

SUN Xiaoyuan

LI Min

TAN Qinqin

LI Cheng

Related Institution

Department of Physics， Changchun Normal University

Department of Chemistry， Jilin Normal University

Research Institute of Changchun University of Science and Technology in Chongqing

School of Materials Science and Engineering， Changchun University of Science and Technology

School of Physics， Northeast Normal University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰