Constructing Efficient and Stable Perovskite Solar Cells by Adjusting Atomic-layer-deposited SnO<italic style="font-style: italic"><sub>x</sub></italic> Layer <italic style="font-style: italic">via</italic> Oxygen Sources

XIE Yi; WU Shaohang; GAO Yanyan; LIU Yaqing; GUO Rilang; MAI Yaohua

doi:10.37188/CJL.20220325

您当前的位置：

首页 >

文章列表页 >

Constructing Efficient and Stable Perovskite Solar Cells by Adjusting Atomic-layer-deposited SnO_x Layer via Oxygen Sources

Device Fabrication and Physics | 更新时间：2023-03-13

- Constructing Efficient and Stable Perovskite Solar Cells by Adjusting Atomic-layer-deposited SnO_x Layer via Oxygen Sources
  增强出版
- Chinese Journal of Luminescence Vol. 44, Issue 2, Pages: 337-345(2023)
- 作者机构：
  
  暨南大学信息科学技术学院，新能源技术研究院，广东广州　510632
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(62005099);Guangdong Basic and Applied Basic Research Fund （Key project of Guangdong-Foshan Joint Fund）(2021B1515120003)
- DOI：10.37188/CJL.20220325
  CLC： TM914.4
- Received：06 September 2022，
  
  Revised：2022-09-26，
  
  Published：05 February 2023
- 稿件说明：
移动端阅览
谢怿,吴绍航,高彦艳等.通过氧源调控原子层沉积的SnO_x层实现高效稳定的钙钛矿太阳能电池[J].发光学报,2023,44(02):337-345.

XIE Yi,WU Shaohang,GAO Yanyan,et al.Constructing Efficient and Stable Perovskite Solar Cells by Adjusting Atomic-layer-deposited SnO_x Layer via Oxygen Sources[J].Chinese Journal of Luminescence,2023,44(02):337-345.
谢怿,吴绍航,高彦艳等.通过氧源调控原子层沉积的SnO_x层实现高效稳定的钙钛矿太阳能电池[J].发光学报,2023,44(02):337-345. DOI： 10.37188/CJL.20220325.

XIE Yi,WU Shaohang,GAO Yanyan,et al.Constructing Efficient and Stable Perovskite Solar Cells by Adjusting Atomic-layer-deposited SnO_x Layer via Oxygen Sources[J].Chinese Journal of Luminescence,2023,44(02):337-345. DOI： 10.37188/CJL.20220325.

摘要

原子层沉积的SnO

薄膜具有良好的均匀性和致密性，常被用于提升倒置平面结构钙钛矿太阳能电池的稳定性。而SnO

薄膜的特性对器件能量转换效率（Power conversion efficiency，PCE）有着重要影响。本文通过氧源（H

O、O

）调控SnO

薄膜的能级和导电性，提升器件PCE。结果表明，O

作为单一氧源的SnO

薄膜（记为O

‐SnO

）具有较优的能级排列；而只有H

O作氧源的SnO

薄膜（记为H

O‐SnO

）具有较高的电导率。而采用O

和H

O混合氧源制备的SnO

（记为MIX‐SnO

），则兼顾了能级匹配和良好的导电性，有效提升器件的PCE，达到20.9%。不仅如此，得益于SnO

薄膜的致密结构，有效避免了外部水氧的入侵和内部材料的分解流失，从而提升了器件稳定性，在85 ℃（氮气气氛）下老化超过646 h仍能维持初始PCE的86%以上。

Abstract

SnO

deposited by atomic layer deposition exhibits uniform and dense nature， which is commonly used to improve the stability of inverted planar perovskite solar cells. Meanwhile， the characteristics of SnO

films have an essential impact on power conversion efficiency（PCE） of devices. In this paper， the characteristics of atomic-layer-deposited SnO

are adjusted by the oxygen sources（H

O， O

）， including energy level and conductivity， so as to achieve the improvement of PCE of devices. The results show that the SnO

film with O

as a single oxygen source has good energy level alignment. SnO

， which only has water as an oxygen source （denoted H

O-SnO

）， performs higher electrical conductivity. While， taking advantage of mentioned sources， the SnO

（denoted as MIX-SnO

） not only obtains good energy level alignment， but also excellent conductivity， which effectively improves the PCE of the devices， reaching 20.9%. Moreover， thanks to the denseness of SnO

film， it can largely prevent the ingress of moisture into devices， and also inhibit the decomposition of perovskite， dramatically enhancing the stability of perovskite solar cells， which can retain 86% of initial PCE after aging at 85 ℃ （nitrogen atmosphere） for more than 646 h.

关键词

Keywords

references

BOYD C C ， CHEACHAROEN R ， LEIJTENS T ， et al . Understanding degradation mechanisms and improving stability of perovskite photovoltaics ［J］. Chem. Rev. ， 2018 ， 119 （ 5 ）： 3418 - 3451 . doi: 10.1021/acs.chemrev.8b00336 http://dx.doi.org/10.1021/acs.chemrev.8b00336

ZHOU H P ， CHEN Q ， LI G ， et al . Interface engineering of highly efficient perovskite solar cells ［J］. Science ， 2014 ， 345 （ 6196 ）： 542 - 546 . doi: 10.1126/science.1254050 http://dx.doi.org/10.1126/science.1254050

CHEN W ， WU Y Z ， YUE Y F ， et al . Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers ［J］. Science ， 2015 ， 350 （ 6263 ）： 944 - 948 . doi: 10.1126/science.aad1015 http://dx.doi.org/10.1126/science.aad1015

ERDENEBILEG E ， WANG H ， LI J ， et al . Low-temperature atomic layer deposited electron transport layers for co-evaporated perovskite solar cells ［J］. Solar RRL ， 2022 ， 6 （ 1 ）： 2100842 . doi: 10.1002/solr.202100842 http://dx.doi.org/10.1002/solr.202100842

SEO S ， JEONG S ， PARK H ， et al . Atomic layer deposition for efficient and stable perovskite solar cells ［J］. Chem. Commun. ， 2019 ， 55 （ 17 ）： 2403 - 2416 . doi: 10.1039/c8cc09578g http://dx.doi.org/10.1039/c8cc09578g

RAIFORD J A ， OYAKHIRE S T ， BENT S F . Applications of atomic layer deposition and chemical vapor deposition for perovskite solar cells ［J］. Energy Environ. Sci. ， 2020 ， 13 （ 7 ）： 1997 - 2023 . doi: 10.1039/d0ee00385a http://dx.doi.org/10.1039/d0ee00385a

BRINKMANN K O ， ZHAO J ， POURDAVOUD N ， et al . Suppressed decomposition of organometal halide perovskites by impermeable electron-extraction layers in inverted solar cells ［J］. Nat. Commun. ， 2017 ， 8 （ 1 ）： 13938-1-9 . doi: 10.1038/ncomms13938 http://dx.doi.org/10.1038/ncomms13938

SEO S ， JEONG S ， BAE C ， et al . Perovskite solar cells with inorganic electron-and hole-transport layers exhibiting long-term （≈500 h） stability at 85 ℃ under continuous 1 sun illumination in ambient air ［J］. Adv. Mater. ， 2018 ， 30 （ 29 ）： 1801010-1-8 . doi: 10.1002/adma.201801010 http://dx.doi.org/10.1002/adma.201801010

XIAO K ， LIN Y H ， ZHANG M ， et al . Scalable processing for realizing 21.7%-efficient all-perovskite tandem solar modules ［J］. Science ， 2022 ， 376 （ 6594 ）： 762 - 767 . doi: 10.1126/science.abn7696 http://dx.doi.org/10.1126/science.abn7696

REN N Y ， ZHU C J ， LI R J ， et al . 50 ℃ low-temperature ALD SnO 2 driven by H 2 O 2 for efficient perovskite and perovskite/silicon tandem solar cells ［J］. Appl. Phys. Lett. ， 2022 ， 121 （ 3 ）： 033502-1-7 . doi: 10.1063/5.0091311 http://dx.doi.org/10.1063/5.0091311

YOO J J ， SEO G ， CHUA M R ， et al . Efficient perovskite solar cells via improved carrier management ［J］. Nature ， 2021 ， 590 （ 7847 ）： 587 - 593 . doi: 10.1038/s41586-021-03285-w http://dx.doi.org/10.1038/s41586-021-03285-w

CHENG H E ， TIAN D C ， HUANG K C . Properties of SnO 2 films grown by atomic layer deposition ［J］. Procedia Eng. ， 2012 ， 36 ： 510 - 515 . doi: 10.1016/j.proeng.2012.03.074 http://dx.doi.org/10.1016/j.proeng.2012.03.074

DU X ， DU Y ， GEORGE S M . In situ examination of tin oxide atomic layer deposition using quartz crystal microbalance and Fourier transform infrared techniques ［J］. J. Vac. Sci. Technol. A ， 2005 ， 23 （ 4 ）： 581 - 588 . doi: 10.1116/1.1914810 http://dx.doi.org/10.1116/1.1914810

ELAM J W ， BAKER D A ， HRYN A J ， et al . Atomic layer deposition of tin oxide films using tetrakis （dimethylamino） tin ［J］. J. Vac. Sci. Technol. A ， 2008 ， 26 （ 2 ）： 244 - 252 . doi: 10.1116/1.2835087 http://dx.doi.org/10.1116/1.2835087

HU T ， BECKER T ， POURDAVOUD N ， et al . Indium-free perovskite solar cells enabled by impermeable tin-oxide electron extraction layers ［J］. Adv. Mater. ， 2017 ， 29 （ 27 ）： 1606656-1-9 . doi: 10.1002/adma.201606656 http://dx.doi.org/10.1002/adma.201606656

LEE J H ， YOO M ， KANG D H ， et al . Selective SnO x atomic layer deposition driven by oxygen reactants ［J］. ACS Appl. Mater. Interfaces ， 2018 ， 10 （ 39 ）： 33335 - 33342 . doi: 10.1021/acsami.8b12251 http://dx.doi.org/10.1021/acsami.8b12251

MULLINGS M N ， HÄGGLUND C ， BENT S F . Tin oxide atomic layer deposition from tetrakis （dimethylamino） tin and water ［J］. J. Vac. Sci. Technol. A ， 2013 ， 31 （ 6 ）： 061503-1-8 . doi: 10.1116/1.4812717 http://dx.doi.org/10.1116/1.4812717

MACKUS A J M ， MACISAAC C ， KIM W H ， et al . Incomplete elimination of precursor ligands during atomic layer deposition of zinc-oxide， tin-oxide， and zinc-tin-oxide ［J］. J. Chem. Phys. ， 2017 ， 146 （ 5 ）： 052802-1-11 . doi: 10.1063/1.4961459 http://dx.doi.org/10.1063/1.4961459

CHOI D W ， MAENG W J ， PARK J S . The conducting tin oxide thin films deposited via atomic layer deposition using Tetrakis-dimethylamino tin and peroxide for transparent flexible electronics ［J］. Appl. Surf. Sci. ， 2014 ， 313 ： 585 - 590 . doi: 10.1016/j.apsusc.2014.06.027 http://dx.doi.org/10.1016/j.apsusc.2014.06.027

CHOI D W ， PARK J S . Highly conductive SnO 2 thin films deposited by atomic layer deposition using tetrakis-dimethyl-amine-tin precursor and ozone reactant ［J］. Surf. Coat. Technol. ， 2014 ， 259 ： 238 - 243 . doi: 10.1016/j.surfcoat.2014.02.012 http://dx.doi.org/10.1016/j.surfcoat.2014.02.012

LI F M ， SHEN Z T ， WENG Y J ， et al . Novel electron transport layer material for perovskite solar cells with over 22% efficiency and long-term stability ［J］. Adv. Funct. Mater. ， 2020 ， 30 （ 45 ）： 2004933-1-9 . doi: 10.1002/adfm.202004933 http://dx.doi.org/10.1002/adfm.202004933

LEE M ， KIM D ， LEE Y K ， et al . Indene-C 60 bisadduct electron-transporting material with the high LUMO level enhances open-circuit voltage and efficiency of tin-based perovskite solar cells ［J］. ACS Appl. Energy Mater. ， 2020 ， 3 （ 6 ）： 5581 - 5588 . doi: 10.1021/acsaem.0c00535 http://dx.doi.org/10.1021/acsaem.0c00535

XU C Q ， ZHANG Y W ， LUO P F ， et al . Comparative study on TiO 2 and C 60 electron transport layers for efficient perovskite solar cells ［J］. ACS Appl. Energy Mater. ， 2021 ， 4 （ 6 ）： 5543 - 5553 . doi: 10.1021/acsaem.1c00226 http://dx.doi.org/10.1021/acsaem.1c00226

MACCO B ， WU Y ， VANHEMEL D ， et al . High mobility In 2 O 3 ∶H transparent conductive oxides prepared by atomic layer deposition and solid phase crystallization ［J］. Phys. Status Solidi （RRL）‐Rapid Res. Lett. ， 2014 ， 8 （ 12 ）： 987 - 990 . doi: 10.1002/pssr.201409426 http://dx.doi.org/10.1002/pssr.201409426

KOIDA T ， SAI H ， KONDO M . In 2 O 3 ∶H transparent conductive oxide films with high mobility and near infrared transparency for optoelectronic applications ［J］. Surf. Eng. ， 2012 ， 28 （ 2 ）： 102 - 107 . doi: 10.1179/1743294411y.0000000053 http://dx.doi.org/10.1179/1743294411y.0000000053

SUCKOW S . 2 / 3 -Diode Fit ［EB/OL］. 2014-12-03 . https：//nanohub.org/resources/14300 https://nanohub.org/resources/14300 .

BERHE T A ， SU W N ， CHEN C H ， et al . Organometal halide perovskite solar cells： degradation and stability ［J］. Energy Environ. Sci. ， 2016 ， 9 （ 2 ）： 323 - 356 . doi: 10.1039/c5ee02733k http://dx.doi.org/10.1039/c5ee02733k

CONINGS B ， DRIJKONINGEN J ， GAUQUELIN N ， et al . Intrinsic thermal instability of methylammonium lead trihalide perovskite ［J］. Adv. Energy Mater. ， 2015 ， 5 （ 15 ）： 1500477-1-8 . doi: 10.1002/aenm.201500477 http://dx.doi.org/10.1002/aenm.201500477

DUNFIELD S P ， BLISS L ， ZHANG F ， et al . From defects to degradation： a mechanistic understanding of degradation in perovskite solar cell devices and modules ［J］. Adv. Energy Mater. ， 2020 ， 10 （ 26 ）： 1904054-1-35 . doi: 10.1002/aenm.201904054 http://dx.doi.org/10.1002/aenm.201904054

Views

618

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Fabrication of Highly Efficient and Stable Perovskite Solar Cells by Vacuum Thermal Evaporation of LiF Passivating Interface

Accelerating Perovskite Solar Cell Development: A Machine Learning-driven Framework with SHAP Explainability

Bimolecularly Passivated Buried Interface for Highly Efficient Perovskite Solar Cells

Solvent Regulation Strategy for Ambient Preparation of Perovskite Solar Cells

Related Author

WU Shao-hang

GAO Yan-yan

LIU Ya-qing

GUO Ri-lang

MAI Yao-hua

WANG Haijun

WANG Jin

LYU Jun

Related Institution

RISEN Energy Co.， Ltd.

Zhejiang Engineering Research Center for Fabrication and Application of Advanced Photovoltaic Materials， Institute for Carbon Neutrality， Ningbo Innovation Centre， Zhejiang University

School of Material Science and Engineering， Zhejiang University

Zhejiang Engineering Research Center for Fabrication and Application of Advanced Photovoltaic Materials， School of Materials Science and Engineering， NingboTech University

School of Materials Science and Engineering， Zhejiang Sci-Tech University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Constructing Efficient and Stable Perovskite Solar Cells by Adjusting Atomic-layer-deposited SnOx Layer via Oxygen Sources

DOI：10.37188/CJL.20220325

摘要

Abstract

关键词

Keywords

references

Constructing Efficient and Stable Perovskite Solar Cells by Adjusting Atomic-layer-deposited SnO_x Layer via Oxygen Sources